Characterisation of the nanotubular oxide layer formed on the ultrafine-grained titanium
Apstrakt
Commercially pure titanium (cpTi) and titanium alloys are metallic implant materials usually used in dentistry and orthopaedics. In order to improve implant properties, Ti-based materials may be surface modified by different procedures. One of the most attractive methods is electrochemical anodization, as a method for obtaining nanotubular oxide layer on the material surface, aiming at improving mechanical, biological and corrosion properties of the metallic biomaterials. In the present study, ultrafine-grained titanium (UFG cpTi) was obtained by high pressure torsion (HPT) under a pressure of 4.1 GPa with a rotational speed of 0.2 rpm, up to 5 rotations at room temperature. In order to form homogeneous nanotubular oxide layer on the UFG cpTi, the electrochemical anodization was performed in phosphoric acid containing 0 5 wt. % of NaF electrolyte during anodizing times of 30, 60 and 90 minutes. The characterisation of thus formed nanotubes was performed using the scanning electron micr...oscopy (SEM), while the surface topography was analysed using the atomic force microscopy (AFM). The results show that the electrochemical anodization process leads to an enhanced roughness of the surface. The mechanical behaviour of the UFG cpTi after the electrochemical anodization process is estimated using the nanoindentation technique. Obtained results show that anodized material has lower value of nanohardness than nonanodized material. Moreover, anodized UFG cpTi has lower modulus of elasticity than non-anodized UFG cpTi and the value is close to those observed in bones.
Ključne reči:
electrochemical anodization / high pressure torsion / nanotubular oxide layer / ultrafine-grained titaniumIzvor:
Metallurgical & Materials Engineering, 2018, 24, 4, 261-270Izdavač:
- Savez inženjera metalurgije Srbije, Beograd
Finansiranje / projekti:
- Mikromehanički kriterijumi oštećenja i loma (RS-MESTD-Basic Research (BR or ON)-174004)
- Sinteza, razvoj tehnologija dobijanja i primena nanostrukturnih multifunkcionalnih materijala definisanih svojstava (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45019)
Kolekcije
Institucija/grupa
Tehnološko-metalurški fakultetTY - JOUR AU - Barjaktarević, Dragana AU - Rakin, Marko AU - Đokić, Veljko PY - 2018 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3917 AB - Commercially pure titanium (cpTi) and titanium alloys are metallic implant materials usually used in dentistry and orthopaedics. In order to improve implant properties, Ti-based materials may be surface modified by different procedures. One of the most attractive methods is electrochemical anodization, as a method for obtaining nanotubular oxide layer on the material surface, aiming at improving mechanical, biological and corrosion properties of the metallic biomaterials. In the present study, ultrafine-grained titanium (UFG cpTi) was obtained by high pressure torsion (HPT) under a pressure of 4.1 GPa with a rotational speed of 0.2 rpm, up to 5 rotations at room temperature. In order to form homogeneous nanotubular oxide layer on the UFG cpTi, the electrochemical anodization was performed in phosphoric acid containing 0 5 wt. % of NaF electrolyte during anodizing times of 30, 60 and 90 minutes. The characterisation of thus formed nanotubes was performed using the scanning electron microscopy (SEM), while the surface topography was analysed using the atomic force microscopy (AFM). The results show that the electrochemical anodization process leads to an enhanced roughness of the surface. The mechanical behaviour of the UFG cpTi after the electrochemical anodization process is estimated using the nanoindentation technique. Obtained results show that anodized material has lower value of nanohardness than nonanodized material. Moreover, anodized UFG cpTi has lower modulus of elasticity than non-anodized UFG cpTi and the value is close to those observed in bones. PB - Savez inženjera metalurgije Srbije, Beograd T2 - Metallurgical & Materials Engineering T1 - Characterisation of the nanotubular oxide layer formed on the ultrafine-grained titanium EP - 270 IS - 4 SP - 261 VL - 24 DO - 10.30544/402 ER -
@article{ author = "Barjaktarević, Dragana and Rakin, Marko and Đokić, Veljko", year = "2018", abstract = "Commercially pure titanium (cpTi) and titanium alloys are metallic implant materials usually used in dentistry and orthopaedics. In order to improve implant properties, Ti-based materials may be surface modified by different procedures. One of the most attractive methods is electrochemical anodization, as a method for obtaining nanotubular oxide layer on the material surface, aiming at improving mechanical, biological and corrosion properties of the metallic biomaterials. In the present study, ultrafine-grained titanium (UFG cpTi) was obtained by high pressure torsion (HPT) under a pressure of 4.1 GPa with a rotational speed of 0.2 rpm, up to 5 rotations at room temperature. In order to form homogeneous nanotubular oxide layer on the UFG cpTi, the electrochemical anodization was performed in phosphoric acid containing 0 5 wt. % of NaF electrolyte during anodizing times of 30, 60 and 90 minutes. The characterisation of thus formed nanotubes was performed using the scanning electron microscopy (SEM), while the surface topography was analysed using the atomic force microscopy (AFM). The results show that the electrochemical anodization process leads to an enhanced roughness of the surface. The mechanical behaviour of the UFG cpTi after the electrochemical anodization process is estimated using the nanoindentation technique. Obtained results show that anodized material has lower value of nanohardness than nonanodized material. Moreover, anodized UFG cpTi has lower modulus of elasticity than non-anodized UFG cpTi and the value is close to those observed in bones.", publisher = "Savez inženjera metalurgije Srbije, Beograd", journal = "Metallurgical & Materials Engineering", title = "Characterisation of the nanotubular oxide layer formed on the ultrafine-grained titanium", pages = "270-261", number = "4", volume = "24", doi = "10.30544/402" }
Barjaktarević, D., Rakin, M.,& Đokić, V.. (2018). Characterisation of the nanotubular oxide layer formed on the ultrafine-grained titanium. in Metallurgical & Materials Engineering Savez inženjera metalurgije Srbije, Beograd., 24(4), 261-270. https://doi.org/10.30544/402
Barjaktarević D, Rakin M, Đokić V. Characterisation of the nanotubular oxide layer formed on the ultrafine-grained titanium. in Metallurgical & Materials Engineering. 2018;24(4):261-270. doi:10.30544/402 .
Barjaktarević, Dragana, Rakin, Marko, Đokić, Veljko, "Characterisation of the nanotubular oxide layer formed on the ultrafine-grained titanium" in Metallurgical & Materials Engineering, 24, no. 4 (2018):261-270, https://doi.org/10.30544/402 . .