Characterization of glycidyl methacrylate based magnetic nanocomposites
2019
Authors
Marković, Bojana M.Spasojević, Vojislav
Dapčević, Aleksandra
Vuković, Zorica M.
Pavlović, Vladimir B.
Ranđelović, Danijela
Nastasović, Aleksandra
Article (Published version)
Metadata
Show full item recordAbstract
Magnetic and non-magnetic macroporous crosslinked copolymers of glycidyl methacrylate and trimethylolpropane trimethacrylate were prepared by suspension copolymerization and functionalized with diethylenetriamine. The samples were characterized by mercury porosimetry, scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), Fourier transform infrared spectroscopy analysis (FTIR-ATR), thermogravimetric analysis (TGA), X-ray diffractometry (XRD), atomic force microscopy (AFM), transmission electron microscopy (TEM) and SQUID magnetometry. The FTIR-ATR analysis of synthesized magnetic nanocomposites confirmed the presence of magnetite and successful aminofunctionalization. Non-functionalized and amino-functionalized nanocomposites exhibited superparamagnetic behavior at 300 K, with a saturation magnetization of 5.0 emu/g and 2.9 emu/g, respectively. TEM analysis of the magnetic nanocomposite has shown that magnetic nanoparticles were homogeneously dispersed in the... polymer matrix. It was demonstrated that incorporation of magnetic nanoparticles enhanced the thermal stability of the magnetic nanocomposite in comparison to the initial non-magnetic macroporous copolymer.
Keywords:
glycidyl methacrylate / trimethylolpropane trimethacrylate / magnetic nanocomposite / diethylenetriamineSource:
Hemijska industrija, 2019, 73, 1, 25-35Publisher:
- Savez hemijskih inženjera, Beograd
Funding / projects:
- Advanced technologies for monitoring and environmental protection from chemical pollutants and radiation burden (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-43009)
- Micro- Nanosystems and Sensors for Electric Power and Process Industry and Environmental Protection (RS-MESTD-Technological Development (TD or TR)-32008)
- Nanostructured Functional and Composite Materials in Catalytic and Sorption Processes (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45001)
- Zero- to Three-Dimensional Nanostructures for Application in Electronics and Renewable Energy Sources: Synthesis, Characterization and Processing (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45007)
- Magnetic and radionuclide labeled nanostructured materials for medical applications (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45015)
DOI: 10.2298/HEMIND181113006M
ISSN: 0367-598X
WoS: 000460129400003
Scopus: 2-s2.0-85064212602
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Marković, Bojana M. AU - Spasojević, Vojislav AU - Dapčević, Aleksandra AU - Vuković, Zorica M. AU - Pavlović, Vladimir B. AU - Ranđelović, Danijela AU - Nastasović, Aleksandra PY - 2019 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4179 AB - Magnetic and non-magnetic macroporous crosslinked copolymers of glycidyl methacrylate and trimethylolpropane trimethacrylate were prepared by suspension copolymerization and functionalized with diethylenetriamine. The samples were characterized by mercury porosimetry, scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), Fourier transform infrared spectroscopy analysis (FTIR-ATR), thermogravimetric analysis (TGA), X-ray diffractometry (XRD), atomic force microscopy (AFM), transmission electron microscopy (TEM) and SQUID magnetometry. The FTIR-ATR analysis of synthesized magnetic nanocomposites confirmed the presence of magnetite and successful aminofunctionalization. Non-functionalized and amino-functionalized nanocomposites exhibited superparamagnetic behavior at 300 K, with a saturation magnetization of 5.0 emu/g and 2.9 emu/g, respectively. TEM analysis of the magnetic nanocomposite has shown that magnetic nanoparticles were homogeneously dispersed in the polymer matrix. It was demonstrated that incorporation of magnetic nanoparticles enhanced the thermal stability of the magnetic nanocomposite in comparison to the initial non-magnetic macroporous copolymer. PB - Savez hemijskih inženjera, Beograd T2 - Hemijska industrija T1 - Characterization of glycidyl methacrylate based magnetic nanocomposites EP - 35 IS - 1 SP - 25 VL - 73 DO - 10.2298/HEMIND181113006M ER -
@article{ author = "Marković, Bojana M. and Spasojević, Vojislav and Dapčević, Aleksandra and Vuković, Zorica M. and Pavlović, Vladimir B. and Ranđelović, Danijela and Nastasović, Aleksandra", year = "2019", abstract = "Magnetic and non-magnetic macroporous crosslinked copolymers of glycidyl methacrylate and trimethylolpropane trimethacrylate were prepared by suspension copolymerization and functionalized with diethylenetriamine. The samples were characterized by mercury porosimetry, scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), Fourier transform infrared spectroscopy analysis (FTIR-ATR), thermogravimetric analysis (TGA), X-ray diffractometry (XRD), atomic force microscopy (AFM), transmission electron microscopy (TEM) and SQUID magnetometry. The FTIR-ATR analysis of synthesized magnetic nanocomposites confirmed the presence of magnetite and successful aminofunctionalization. Non-functionalized and amino-functionalized nanocomposites exhibited superparamagnetic behavior at 300 K, with a saturation magnetization of 5.0 emu/g and 2.9 emu/g, respectively. TEM analysis of the magnetic nanocomposite has shown that magnetic nanoparticles were homogeneously dispersed in the polymer matrix. It was demonstrated that incorporation of magnetic nanoparticles enhanced the thermal stability of the magnetic nanocomposite in comparison to the initial non-magnetic macroporous copolymer.", publisher = "Savez hemijskih inženjera, Beograd", journal = "Hemijska industrija", title = "Characterization of glycidyl methacrylate based magnetic nanocomposites", pages = "35-25", number = "1", volume = "73", doi = "10.2298/HEMIND181113006M" }
Marković, B. M., Spasojević, V., Dapčević, A., Vuković, Z. M., Pavlović, V. B., Ranđelović, D.,& Nastasović, A.. (2019). Characterization of glycidyl methacrylate based magnetic nanocomposites. in Hemijska industrija Savez hemijskih inženjera, Beograd., 73(1), 25-35. https://doi.org/10.2298/HEMIND181113006M
Marković BM, Spasojević V, Dapčević A, Vuković ZM, Pavlović VB, Ranđelović D, Nastasović A. Characterization of glycidyl methacrylate based magnetic nanocomposites. in Hemijska industrija. 2019;73(1):25-35. doi:10.2298/HEMIND181113006M .
Marković, Bojana M., Spasojević, Vojislav, Dapčević, Aleksandra, Vuković, Zorica M., Pavlović, Vladimir B., Ranđelović, Danijela, Nastasović, Aleksandra, "Characterization of glycidyl methacrylate based magnetic nanocomposites" in Hemijska industrija, 73, no. 1 (2019):25-35, https://doi.org/10.2298/HEMIND181113006M . .