Influence of 1,2,3,4-butanetetracarboxylic acid concentration on in situ synthesis of cuo/cu2o nanoparticles on cotton and viscose rayon fabrics
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2019
Authors
Marković, DarkaJokić, Bojan
Radovanović, Željko
Ašanin, Jelena
Radoičić, Marija B.
Mitrić, Miodrag
Mišić, Dušan
Radetić, Maja
Article (Published version)
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This study discusses the possibility of in situ synthesis of Cu-based nanoparticles (NPs) on cotton and viscose rayon fabrics previously modified with 1,2,3,4-butanetetracarboxylic acid (BTCA) of different concentrations, with the aim to obtain antibacterial protection. The changes in the chemical structure of the fibers caused by the modification with BTCA were assessed by FTIR spectroscopy. The higher the concentration of the applied BTCA, the larger the amounts of free carboxyl groups in both fabrics. AAS analysis showed that the samples modified with higher concentration of BTCA provided larger Cu2+-ions uptake and consequently, higher content of Cu after Cu2+-ions reduction. The presence of Cu-based NPs on the fabrics was confirmed by FESEM and EDS analyses. XRD analysis revealed that NPs appeared as a mixture of CuO and Cu2O. Synthesized NPs imparted excellent antibacterial activity to both fabrics against E. coli and S. aureus, including methicillin-resistant S. aureus.
Keywords:
cotton / viscose / Cu-based nanoparticles / BTCA / antimicrobial activity / controlled releaseSource:
Cellulose Chemistry and Technology, 2019, 53, 7-8, 805-813Publisher:
- Editura Acad Romane, Bucuresti
Funding / projects:
- COST ActionEuropean Cooperation in Science and Technology (COST) [CA17107]
- Size-, shape- and structure- dependent properties of nanoparticles and nanocomposites (RS-MESTD-Basic Research (BR or ON)-172056)
- Materials of Reduced Dimensions for Efficient Light Harvesting and Energy conversion (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45020)
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Tehnološko-metalurški fakultetTY - JOUR AU - Marković, Darka AU - Jokić, Bojan AU - Radovanović, Željko AU - Ašanin, Jelena AU - Radoičić, Marija B. AU - Mitrić, Miodrag AU - Mišić, Dušan AU - Radetić, Maja PY - 2019 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4193 AB - This study discusses the possibility of in situ synthesis of Cu-based nanoparticles (NPs) on cotton and viscose rayon fabrics previously modified with 1,2,3,4-butanetetracarboxylic acid (BTCA) of different concentrations, with the aim to obtain antibacterial protection. The changes in the chemical structure of the fibers caused by the modification with BTCA were assessed by FTIR spectroscopy. The higher the concentration of the applied BTCA, the larger the amounts of free carboxyl groups in both fabrics. AAS analysis showed that the samples modified with higher concentration of BTCA provided larger Cu2+-ions uptake and consequently, higher content of Cu after Cu2+-ions reduction. The presence of Cu-based NPs on the fabrics was confirmed by FESEM and EDS analyses. XRD analysis revealed that NPs appeared as a mixture of CuO and Cu2O. Synthesized NPs imparted excellent antibacterial activity to both fabrics against E. coli and S. aureus, including methicillin-resistant S. aureus. PB - Editura Acad Romane, Bucuresti T2 - Cellulose Chemistry and Technology T1 - Influence of 1,2,3,4-butanetetracarboxylic acid concentration on in situ synthesis of cuo/cu2o nanoparticles on cotton and viscose rayon fabrics EP - 813 IS - 7-8 SP - 805 VL - 53 UR - https://hdl.handle.net/21.15107/rcub_technorep_4193 ER -
@article{ author = "Marković, Darka and Jokić, Bojan and Radovanović, Željko and Ašanin, Jelena and Radoičić, Marija B. and Mitrić, Miodrag and Mišić, Dušan and Radetić, Maja", year = "2019", abstract = "This study discusses the possibility of in situ synthesis of Cu-based nanoparticles (NPs) on cotton and viscose rayon fabrics previously modified with 1,2,3,4-butanetetracarboxylic acid (BTCA) of different concentrations, with the aim to obtain antibacterial protection. The changes in the chemical structure of the fibers caused by the modification with BTCA were assessed by FTIR spectroscopy. The higher the concentration of the applied BTCA, the larger the amounts of free carboxyl groups in both fabrics. AAS analysis showed that the samples modified with higher concentration of BTCA provided larger Cu2+-ions uptake and consequently, higher content of Cu after Cu2+-ions reduction. The presence of Cu-based NPs on the fabrics was confirmed by FESEM and EDS analyses. XRD analysis revealed that NPs appeared as a mixture of CuO and Cu2O. Synthesized NPs imparted excellent antibacterial activity to both fabrics against E. coli and S. aureus, including methicillin-resistant S. aureus.", publisher = "Editura Acad Romane, Bucuresti", journal = "Cellulose Chemistry and Technology", title = "Influence of 1,2,3,4-butanetetracarboxylic acid concentration on in situ synthesis of cuo/cu2o nanoparticles on cotton and viscose rayon fabrics", pages = "813-805", number = "7-8", volume = "53", url = "https://hdl.handle.net/21.15107/rcub_technorep_4193" }
Marković, D., Jokić, B., Radovanović, Ž., Ašanin, J., Radoičić, M. B., Mitrić, M., Mišić, D.,& Radetić, M.. (2019). Influence of 1,2,3,4-butanetetracarboxylic acid concentration on in situ synthesis of cuo/cu2o nanoparticles on cotton and viscose rayon fabrics. in Cellulose Chemistry and Technology Editura Acad Romane, Bucuresti., 53(7-8), 805-813. https://hdl.handle.net/21.15107/rcub_technorep_4193
Marković D, Jokić B, Radovanović Ž, Ašanin J, Radoičić MB, Mitrić M, Mišić D, Radetić M. Influence of 1,2,3,4-butanetetracarboxylic acid concentration on in situ synthesis of cuo/cu2o nanoparticles on cotton and viscose rayon fabrics. in Cellulose Chemistry and Technology. 2019;53(7-8):805-813. https://hdl.handle.net/21.15107/rcub_technorep_4193 .
Marković, Darka, Jokić, Bojan, Radovanović, Željko, Ašanin, Jelena, Radoičić, Marija B., Mitrić, Miodrag, Mišić, Dušan, Radetić, Maja, "Influence of 1,2,3,4-butanetetracarboxylic acid concentration on in situ synthesis of cuo/cu2o nanoparticles on cotton and viscose rayon fabrics" in Cellulose Chemistry and Technology, 53, no. 7-8 (2019):805-813, https://hdl.handle.net/21.15107/rcub_technorep_4193 .