Thermal and rheological properties of unsaturated polyester resins-based composites
Samo za registrovane korisnike
2019
Poglavlje u monografiji (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
Unsaturated polyester resins (UPR) are among the most commercially important thermosetting matrix materials for composites. This chapter summarizes the importance of the thermal and rheological properties of UPR. The kinetics and mechanisms of thermal degradation (for both inert and reactive atmospheres) are presented. A little information about the toxicity of the major thermal degradation products is given. The main parameters affecting thermal stability (prepolymer structure, styrene content, cure regime, fillers, and reinforcements) are summarized. A comprehensive study of the methods of improving thermal stability and flame retardancy with a special emphasis on nonhalogenated flame retardants is presented. Bearing in mind that the rheological characteristics of UPR govern and limit their usage potential, a comprehensive study of the parameters affecting the viscosity of UPR composites (thickening and thixotropic agents, low profile additives, fillers, and reinforcements) is presen...ted. Also, briefly introduced and described are the main processing techniques with special emphasis on the rheological requirements for each technique. Finally, some rheological concerns and challenges for the development of fully bio-based UPRs are described.
Ključne reči:
Degradation products / Flame retardancy / Processing techniques / Structure-property relationship / Thermal stability / Unsaturated polyester resin / Viscosity control / Viscosity requirementsIzvor:
Unsaturated Polyester Resins: Fundamentals, Design, Fabrication, and Applications, 2019, 367-406
DOI: 10.1016/B978-0-12-816129-6.00015-6
ISBN: 978-012816129-6
PubMed:
Scopus: 2-s2.0-85082618198
Institucija/grupa
Inovacioni centarTY - CHAP AU - Spasojević, Pavle PY - 2019 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4199 AB - Unsaturated polyester resins (UPR) are among the most commercially important thermosetting matrix materials for composites. This chapter summarizes the importance of the thermal and rheological properties of UPR. The kinetics and mechanisms of thermal degradation (for both inert and reactive atmospheres) are presented. A little information about the toxicity of the major thermal degradation products is given. The main parameters affecting thermal stability (prepolymer structure, styrene content, cure regime, fillers, and reinforcements) are summarized. A comprehensive study of the methods of improving thermal stability and flame retardancy with a special emphasis on nonhalogenated flame retardants is presented. Bearing in mind that the rheological characteristics of UPR govern and limit their usage potential, a comprehensive study of the parameters affecting the viscosity of UPR composites (thickening and thixotropic agents, low profile additives, fillers, and reinforcements) is presented. Also, briefly introduced and described are the main processing techniques with special emphasis on the rheological requirements for each technique. Finally, some rheological concerns and challenges for the development of fully bio-based UPRs are described. T2 - Unsaturated Polyester Resins: Fundamentals, Design, Fabrication, and Applications T1 - Thermal and rheological properties of unsaturated polyester resins-based composites EP - 406 SP - 367 DO - 10.1016/B978-0-12-816129-6.00015-6 ER -
@inbook{ author = "Spasojević, Pavle", year = "2019", abstract = "Unsaturated polyester resins (UPR) are among the most commercially important thermosetting matrix materials for composites. This chapter summarizes the importance of the thermal and rheological properties of UPR. The kinetics and mechanisms of thermal degradation (for both inert and reactive atmospheres) are presented. A little information about the toxicity of the major thermal degradation products is given. The main parameters affecting thermal stability (prepolymer structure, styrene content, cure regime, fillers, and reinforcements) are summarized. A comprehensive study of the methods of improving thermal stability and flame retardancy with a special emphasis on nonhalogenated flame retardants is presented. Bearing in mind that the rheological characteristics of UPR govern and limit their usage potential, a comprehensive study of the parameters affecting the viscosity of UPR composites (thickening and thixotropic agents, low profile additives, fillers, and reinforcements) is presented. Also, briefly introduced and described are the main processing techniques with special emphasis on the rheological requirements for each technique. Finally, some rheological concerns and challenges for the development of fully bio-based UPRs are described.", journal = "Unsaturated Polyester Resins: Fundamentals, Design, Fabrication, and Applications", booktitle = "Thermal and rheological properties of unsaturated polyester resins-based composites", pages = "406-367", doi = "10.1016/B978-0-12-816129-6.00015-6" }
Spasojević, P.. (2019). Thermal and rheological properties of unsaturated polyester resins-based composites. in Unsaturated Polyester Resins: Fundamentals, Design, Fabrication, and Applications, 367-406. https://doi.org/10.1016/B978-0-12-816129-6.00015-6
Spasojević P. Thermal and rheological properties of unsaturated polyester resins-based composites. in Unsaturated Polyester Resins: Fundamentals, Design, Fabrication, and Applications. 2019;:367-406. doi:10.1016/B978-0-12-816129-6.00015-6 .
Spasojević, Pavle, "Thermal and rheological properties of unsaturated polyester resins-based composites" in Unsaturated Polyester Resins: Fundamentals, Design, Fabrication, and Applications (2019):367-406, https://doi.org/10.1016/B978-0-12-816129-6.00015-6 . .