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Photolysis of insecticide methomyl in various solvents: An experimental and theoretical study
dc.creator | Tomašević, Anđelka | |
dc.creator | Mijin, Dušan | |
dc.creator | Radišić, Marina | |
dc.creator | Prlainović, Nevena | |
dc.creator | Cvijetić, Ilija | |
dc.creator | Kovačević, Danijela | |
dc.creator | Marinković, Aleksandar | |
dc.date.accessioned | 2021-03-10T14:21:33Z | |
dc.date.available | 2021-03-10T14:21:33Z | |
dc.date.issued | 2020 | |
dc.identifier.issn | 1010-6030 | |
dc.identifier.uri | http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4480 | |
dc.description.abstract | This study describes photolysis of 1 x 10(-4) M methomyl solution in deionized water and in eleven organic solvents, both polar and nonpolar: methanol, ethanol, n-propanol, isopropanol, sec-butanol, tert-butanol, isobutanol, isopentanol, n-hexane, acetonitrile, and dichloromethane. Photolysis of methomyl at 254 nm was performed using Osram mercury lamp (6 x 8 W) by exposing to irradiation for five hours. All photolytic methomyl reactions were studied by UV/Vis spectroscopy within a wavelength range of 190 - 300 nm (Spectrum Mode), and at 233.4 nm (Quantitative Mode), while the rate of photodecomposition of methomyl was measured using UV spectroscopy and HPLC. In order to get better insight in the photolysis of methomyl, a liquid chromatography-mass spectrometry (LC-MSn) was used. The rate of methomyl photolysis was solvent-specific and the following reaction rate order was established: deionized water gt tert-butanol gt n-hexane gt sec-butanol gt ethanol gt isopentanol gt isobutanol gt isopropanol gt methanol gt acetonitrile gt dichloromethane gt n-propanol. Both nonspecific and specific solvent-solute interactions contribute mutually to the differences in the obtained quantum yields. Results of quantum chemical calculations, using CBS-QB3 method, provided insights into the solvent effects on both ground and excited state. The LC/MSn analysis showed the formation of several photolytic products. | en |
dc.publisher | Elsevier Science Sa, Lausanne | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/46008/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172013/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172035/RS// | |
dc.rights | restrictedAccess | |
dc.source | Journal of Photochemistry and Photobiology A-Chemistry | |
dc.subject | Solvent effect | en |
dc.subject | Quantum yields | en |
dc.subject | Dielectric constant | en |
dc.subject | Acceptor and donor numbers | en |
dc.subject | LFER | en |
dc.subject | CBS-QB3 method | en |
dc.title | Photolysis of insecticide methomyl in various solvents: An experimental and theoretical study | en |
dc.type | article | |
dc.rights.license | ARR | |
dc.citation.other | 391: - | |
dc.citation.rank | M22 | |
dc.citation.volume | 391 | |
dc.identifier.doi | 10.1016/j.jphotochem.2020.112366 | |
dc.identifier.scopus | 2-s2.0-85077930720 | |
dc.identifier.wos | 000514008000021 | |
dc.type.version | publishedVersion |