Volumetric and Transport Properties of Isoamyl Acetate Based Binary Systems-Experimental Determination and Modeling
Samo za registrovane korisnike
2022
Autori
Grozdanić, Nikola D.Majstorović, Divna M.
Jovanović, Jovan D.
Kijevčanin, Mirjana Lj.
Živković, Emila M.
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
Three binary mixtures consisting of isoamyl acetate and 1-butanol or isobutanol or isopentanol were experimentally investigated in terms of their density, viscosity refractive index, and ultrasonic speed of sound, in the temperature range from 288.15 to 323.15 K and at atmospheric pressure. The choice of mixtures was based on their potential for practical application. From experimental data, excess molar volume, viscosity deviation, excess molar Gibbs free energy of activation of viscous flow, deviation in refractive index, and deviation in isentropic compressibility are calculated, correlated with the Redlich-Kister equation and used for better understanding of molecular interactions between the mixture components. Also, partial molar volumes, excess partial molar volumes, and partial molar volumes at infinite dilutions were calculated to elucidate the nonideal behavior of the investigated mixtures. Since the mixtures were investigated both from the theoretical point of view and with ...the aspect for practical application, the modeling of two key properties, viscosity and excess molar volume, was performed with different models and approaches, and the results are compared with experimental values.
Izvor:
Journal of Chemical and Engineering Data, 2022, 67, 9, 2257-2273Izdavač:
- American Chemical Society
Finansiranje / projekti:
- Ministarstvo nauke, tehnološkog razvoja i inovacija Republike Srbije, institucionalno finansiranje - 200135 (Univerzitet u Beogradu, Tehnološko-metalurški fakultet) (RS-MESTD-inst-2020-200135)
DOI: 10.1021/acs.jced.2c00241
ISSN: 0021-9568
WoS: 00082781950000
Scopus: 2-s2.0-85138469285
Institucija/grupa
Tehnološko-metalurški fakultetTY - JOUR AU - Grozdanić, Nikola D. AU - Majstorović, Divna M. AU - Jovanović, Jovan D. AU - Kijevčanin, Mirjana Lj. AU - Živković, Emila M. PY - 2022 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5223 AB - Three binary mixtures consisting of isoamyl acetate and 1-butanol or isobutanol or isopentanol were experimentally investigated in terms of their density, viscosity refractive index, and ultrasonic speed of sound, in the temperature range from 288.15 to 323.15 K and at atmospheric pressure. The choice of mixtures was based on their potential for practical application. From experimental data, excess molar volume, viscosity deviation, excess molar Gibbs free energy of activation of viscous flow, deviation in refractive index, and deviation in isentropic compressibility are calculated, correlated with the Redlich-Kister equation and used for better understanding of molecular interactions between the mixture components. Also, partial molar volumes, excess partial molar volumes, and partial molar volumes at infinite dilutions were calculated to elucidate the nonideal behavior of the investigated mixtures. Since the mixtures were investigated both from the theoretical point of view and with the aspect for practical application, the modeling of two key properties, viscosity and excess molar volume, was performed with different models and approaches, and the results are compared with experimental values. PB - American Chemical Society T2 - Journal of Chemical and Engineering Data T1 - Volumetric and Transport Properties of Isoamyl Acetate Based Binary Systems-Experimental Determination and Modeling EP - 2273 IS - 9 SP - 2257 VL - 67 DO - 10.1021/acs.jced.2c00241 ER -
@article{ author = "Grozdanić, Nikola D. and Majstorović, Divna M. and Jovanović, Jovan D. and Kijevčanin, Mirjana Lj. and Živković, Emila M.", year = "2022", abstract = "Three binary mixtures consisting of isoamyl acetate and 1-butanol or isobutanol or isopentanol were experimentally investigated in terms of their density, viscosity refractive index, and ultrasonic speed of sound, in the temperature range from 288.15 to 323.15 K and at atmospheric pressure. The choice of mixtures was based on their potential for practical application. From experimental data, excess molar volume, viscosity deviation, excess molar Gibbs free energy of activation of viscous flow, deviation in refractive index, and deviation in isentropic compressibility are calculated, correlated with the Redlich-Kister equation and used for better understanding of molecular interactions between the mixture components. Also, partial molar volumes, excess partial molar volumes, and partial molar volumes at infinite dilutions were calculated to elucidate the nonideal behavior of the investigated mixtures. Since the mixtures were investigated both from the theoretical point of view and with the aspect for practical application, the modeling of two key properties, viscosity and excess molar volume, was performed with different models and approaches, and the results are compared with experimental values.", publisher = "American Chemical Society", journal = "Journal of Chemical and Engineering Data", title = "Volumetric and Transport Properties of Isoamyl Acetate Based Binary Systems-Experimental Determination and Modeling", pages = "2273-2257", number = "9", volume = "67", doi = "10.1021/acs.jced.2c00241" }
Grozdanić, N. D., Majstorović, D. M., Jovanović, J. D., Kijevčanin, M. Lj.,& Živković, E. M.. (2022). Volumetric and Transport Properties of Isoamyl Acetate Based Binary Systems-Experimental Determination and Modeling. in Journal of Chemical and Engineering Data American Chemical Society., 67(9), 2257-2273. https://doi.org/10.1021/acs.jced.2c00241
Grozdanić ND, Majstorović DM, Jovanović JD, Kijevčanin ML, Živković EM. Volumetric and Transport Properties of Isoamyl Acetate Based Binary Systems-Experimental Determination and Modeling. in Journal of Chemical and Engineering Data. 2022;67(9):2257-2273. doi:10.1021/acs.jced.2c00241 .
Grozdanić, Nikola D., Majstorović, Divna M., Jovanović, Jovan D., Kijevčanin, Mirjana Lj., Živković, Emila M., "Volumetric and Transport Properties of Isoamyl Acetate Based Binary Systems-Experimental Determination and Modeling" in Journal of Chemical and Engineering Data, 67, no. 9 (2022):2257-2273, https://doi.org/10.1021/acs.jced.2c00241 . .