Kinetic analysis of hydrogen evolution at Ni-Mo alloy electrodes
Само за регистроване кориснике
2000
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The hydrogen evolution reaction (HER) on Ni, Mo and MoNi intermetallic compound was investigated with ac impedance and dc polarization measurements in 1.0 mol dm-3 NaOH solution at 25 °C. The rate constants of the forward and backward reactions of Volmer, Heyrovsky and Tafel steps were estimated by a nonlinear fitting method. MoNi alloy electrode provides a much lower overpotential for the HER than Ni and Mo electrodes, sometimes which exhibit similar catalytic activity. The main pathway for the HER at above mentioned electrode materials is Volmer-Heyrovsky with Heyrovsky as the rate determining step.
Извор:
Electrochimica Acta, 2000, 45, 25-26, 4151-4158Издавач:
- Elsevier Science Ltd
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Jakšić, J.M. AU - Vojnović, M.V. AU - Krstajić, Nedeljko V. PY - 2000 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5312 AB - The hydrogen evolution reaction (HER) on Ni, Mo and MoNi intermetallic compound was investigated with ac impedance and dc polarization measurements in 1.0 mol dm-3 NaOH solution at 25 °C. The rate constants of the forward and backward reactions of Volmer, Heyrovsky and Tafel steps were estimated by a nonlinear fitting method. MoNi alloy electrode provides a much lower overpotential for the HER than Ni and Mo electrodes, sometimes which exhibit similar catalytic activity. The main pathway for the HER at above mentioned electrode materials is Volmer-Heyrovsky with Heyrovsky as the rate determining step. PB - Elsevier Science Ltd T2 - Electrochimica Acta T1 - Kinetic analysis of hydrogen evolution at Ni-Mo alloy electrodes EP - 4158 IS - 25-26 SP - 4151 VL - 45 DO - 10.1016/S0013-4686(00)00549-1 ER -
@article{ author = "Jakšić, J.M. and Vojnović, M.V. and Krstajić, Nedeljko V.", year = "2000", abstract = "The hydrogen evolution reaction (HER) on Ni, Mo and MoNi intermetallic compound was investigated with ac impedance and dc polarization measurements in 1.0 mol dm-3 NaOH solution at 25 °C. The rate constants of the forward and backward reactions of Volmer, Heyrovsky and Tafel steps were estimated by a nonlinear fitting method. MoNi alloy electrode provides a much lower overpotential for the HER than Ni and Mo electrodes, sometimes which exhibit similar catalytic activity. The main pathway for the HER at above mentioned electrode materials is Volmer-Heyrovsky with Heyrovsky as the rate determining step.", publisher = "Elsevier Science Ltd", journal = "Electrochimica Acta", title = "Kinetic analysis of hydrogen evolution at Ni-Mo alloy electrodes", pages = "4158-4151", number = "25-26", volume = "45", doi = "10.1016/S0013-4686(00)00549-1" }
Jakšić, J.M., Vojnović, M.V.,& Krstajić, N. V.. (2000). Kinetic analysis of hydrogen evolution at Ni-Mo alloy electrodes. in Electrochimica Acta Elsevier Science Ltd., 45(25-26), 4151-4158. https://doi.org/10.1016/S0013-4686(00)00549-1
Jakšić J, Vojnović M, Krstajić NV. Kinetic analysis of hydrogen evolution at Ni-Mo alloy electrodes. in Electrochimica Acta. 2000;45(25-26):4151-4158. doi:10.1016/S0013-4686(00)00549-1 .
Jakšić, J.M., Vojnović, M.V., Krstajić, Nedeljko V., "Kinetic analysis of hydrogen evolution at Ni-Mo alloy electrodes" in Electrochimica Acta, 45, no. 25-26 (2000):4151-4158, https://doi.org/10.1016/S0013-4686(00)00549-1 . .