Synthesis and Characterization of Some Nitro-Substituted Phthalocyanines of Nickel(II), Cobalt(II) and Copper(II)
Apstrakt
Synthesis of the peripherally substituted (phthalocyaninato)metal derivatives (NO2)4PcM (M α Ni, Co, Cu; NO2 groups are in 1,8,15,22- or 2,9,16,23-positions) is described, and their X-ray powder diffraction patterns, solubilities, electronic and infrared spectra, and thermal stability are reported. The complexes exhibit isomorphism and polymorphism, and they are more soluble than the corresponding MPcs. Their thermal stability increases in the series Co < Ni < Cu, being at the same time greater for the 2,9,16,23-tetranitro- than for the 1,8,15,22-tetranitro derivatives
Ključne reči:
Nitrophtalocyanines / copper(II) / nickel(II) / synthesis / propertiesIzvor:
Journal of Coordination Chemistry, 1989, 19, 4, 295-301Izdavač:
- Taylor&Francis
Institucija/grupa
Tehnološko-metalurški fakultetTY - JOUR AU - Rajić, Nevenka AU - Stojaković, Djordje PY - 1989 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6392 AB - Synthesis of the peripherally substituted (phthalocyaninato)metal derivatives (NO2)4PcM (M α Ni, Co, Cu; NO2 groups are in 1,8,15,22- or 2,9,16,23-positions) is described, and their X-ray powder diffraction patterns, solubilities, electronic and infrared spectra, and thermal stability are reported. The complexes exhibit isomorphism and polymorphism, and they are more soluble than the corresponding MPcs. Their thermal stability increases in the series Co < Ni < Cu, being at the same time greater for the 2,9,16,23-tetranitro- than for the 1,8,15,22-tetranitro derivatives PB - Taylor&Francis T2 - Journal of Coordination Chemistry T1 - Synthesis and Characterization of Some Nitro-Substituted Phthalocyanines of Nickel(II), Cobalt(II) and Copper(II) EP - 301 IS - 4 SP - 295 VL - 19 DO - 10.1080/00958978909408832 ER -
@article{ author = "Rajić, Nevenka and Stojaković, Djordje", year = "1989", abstract = "Synthesis of the peripherally substituted (phthalocyaninato)metal derivatives (NO2)4PcM (M α Ni, Co, Cu; NO2 groups are in 1,8,15,22- or 2,9,16,23-positions) is described, and their X-ray powder diffraction patterns, solubilities, electronic and infrared spectra, and thermal stability are reported. The complexes exhibit isomorphism and polymorphism, and they are more soluble than the corresponding MPcs. Their thermal stability increases in the series Co < Ni < Cu, being at the same time greater for the 2,9,16,23-tetranitro- than for the 1,8,15,22-tetranitro derivatives", publisher = "Taylor&Francis", journal = "Journal of Coordination Chemistry", title = "Synthesis and Characterization of Some Nitro-Substituted Phthalocyanines of Nickel(II), Cobalt(II) and Copper(II)", pages = "301-295", number = "4", volume = "19", doi = "10.1080/00958978909408832" }
Rajić, N.,& Stojaković, D.. (1989). Synthesis and Characterization of Some Nitro-Substituted Phthalocyanines of Nickel(II), Cobalt(II) and Copper(II). in Journal of Coordination Chemistry Taylor&Francis., 19(4), 295-301. https://doi.org/10.1080/00958978909408832
Rajić N, Stojaković D. Synthesis and Characterization of Some Nitro-Substituted Phthalocyanines of Nickel(II), Cobalt(II) and Copper(II). in Journal of Coordination Chemistry. 1989;19(4):295-301. doi:10.1080/00958978909408832 .
Rajić, Nevenka, Stojaković, Djordje, "Synthesis and Characterization of Some Nitro-Substituted Phthalocyanines of Nickel(II), Cobalt(II) and Copper(II)" in Journal of Coordination Chemistry, 19, no. 4 (1989):295-301, https://doi.org/10.1080/00958978909408832 . .