The structure directing role of 1,3-diaminopropane in the hydrothermal synthesis of iron(III) phosphate
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
13-Diaminopropane (DAP) was used as a structure-directing agent for the hydrothermal synthesis of an organically templated iron phosphate. During crystallization at 180 degreesC, iron phosphate (FePO-DAP) with a layered structure was formed after one day. Longer crystallization yielded a mixture of FePO-DAP and leucophosphite, raising the question whether a transformation of FePO-DAP to leucophosphite occurs. or wheter DAP decomposes under hydrothermal conditions resulting in leucophosphite formation. Lattice energy, and free energy calculations strongly support the supposition that a decomposition of DAP occurs prior to the formation of leueophosphite.
Ključne reči:
FePO / iron phosphate / hydrothermal synthesis / GULP / open-frameworkIzvor:
Journal of the Serbian Chemical Society, 2004, 69, 3, 179-185Izdavač:
- Srpsko hemijsko društvo, Beograd
DOI: 10.2298/JSC0403179R
ISSN: 0352-5139
WoS: 000220461000002
Scopus: 2-s2.0-2142708163
Institucija/grupa
Tehnološko-metalurški fakultetTY - JOUR AU - Rajić, Nevenka AU - Stojaković, D. AU - Hanžel, Darko AU - Kaučič, Venčeslav PY - 2004 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/680 AB - 13-Diaminopropane (DAP) was used as a structure-directing agent for the hydrothermal synthesis of an organically templated iron phosphate. During crystallization at 180 degreesC, iron phosphate (FePO-DAP) with a layered structure was formed after one day. Longer crystallization yielded a mixture of FePO-DAP and leucophosphite, raising the question whether a transformation of FePO-DAP to leucophosphite occurs. or wheter DAP decomposes under hydrothermal conditions resulting in leucophosphite formation. Lattice energy, and free energy calculations strongly support the supposition that a decomposition of DAP occurs prior to the formation of leueophosphite. PB - Srpsko hemijsko društvo, Beograd T2 - Journal of the Serbian Chemical Society T1 - The structure directing role of 1,3-diaminopropane in the hydrothermal synthesis of iron(III) phosphate EP - 185 IS - 3 SP - 179 VL - 69 DO - 10.2298/JSC0403179R ER -
@article{ author = "Rajić, Nevenka and Stojaković, D. and Hanžel, Darko and Kaučič, Venčeslav", year = "2004", abstract = "13-Diaminopropane (DAP) was used as a structure-directing agent for the hydrothermal synthesis of an organically templated iron phosphate. During crystallization at 180 degreesC, iron phosphate (FePO-DAP) with a layered structure was formed after one day. Longer crystallization yielded a mixture of FePO-DAP and leucophosphite, raising the question whether a transformation of FePO-DAP to leucophosphite occurs. or wheter DAP decomposes under hydrothermal conditions resulting in leucophosphite formation. Lattice energy, and free energy calculations strongly support the supposition that a decomposition of DAP occurs prior to the formation of leueophosphite.", publisher = "Srpsko hemijsko društvo, Beograd", journal = "Journal of the Serbian Chemical Society", title = "The structure directing role of 1,3-diaminopropane in the hydrothermal synthesis of iron(III) phosphate", pages = "185-179", number = "3", volume = "69", doi = "10.2298/JSC0403179R" }
Rajić, N., Stojaković, D., Hanžel, D.,& Kaučič, V.. (2004). The structure directing role of 1,3-diaminopropane in the hydrothermal synthesis of iron(III) phosphate. in Journal of the Serbian Chemical Society Srpsko hemijsko društvo, Beograd., 69(3), 179-185. https://doi.org/10.2298/JSC0403179R
Rajić N, Stojaković D, Hanžel D, Kaučič V. The structure directing role of 1,3-diaminopropane in the hydrothermal synthesis of iron(III) phosphate. in Journal of the Serbian Chemical Society. 2004;69(3):179-185. doi:10.2298/JSC0403179R .
Rajić, Nevenka, Stojaković, D., Hanžel, Darko, Kaučič, Venčeslav, "The structure directing role of 1,3-diaminopropane in the hydrothermal synthesis of iron(III) phosphate" in Journal of the Serbian Chemical Society, 69, no. 3 (2004):179-185, https://doi.org/10.2298/JSC0403179R . .