Uticaj parametara neselektivne oksidacije na sadržaj funkcionalnih grupa u celuloznim vlaknima
Influence of the nonselective oxidation conditions onto functional groups content in cellulose fibers
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In this paper, the influence of oxidation with hydrogen peroxide onto functional groups content in natural cellulose fibers was studied. Changes in fibers obtained at various modification conditions were evaluated by determination of carbonyl and carboxyl group content in samples before and after modification. Oxidation with H2O2 leads to a significant increase in carbonyl group content already at shorter times and milder treatment conditions. Small change in carboxyl group content occurs at higher pH values (pH 11) and 6 vol % solution concentration. Taking into account nonselective nature of hydrogen peroxide as an oxidizing agent, the optimization of process in accordance with ultimate application of modified cellulose material can be performed by careful selection of oxidation conditions.
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Knjiga radova / 50. jubilarno savetovanje Srpskog hemijskog društva, Beograd, 14-15. juni 2012, 2012, 270-274Publisher:
- Beograd : Srpsko hemijsko društvo
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- Functionalization, characterization and application of cellulose and cellulose derivatives (RS-MESTD-Basic Research (BR or ON)-172029)
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Tehnološko-metalurški fakultetTY - CONF AU - Kramar, Ana D. AU - Korica, Matea AU - Milanović, Jovana Ž. AU - Kostić, Mirjana M. PY - 2012 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6846 AB - In this paper, the influence of oxidation with hydrogen peroxide onto functional groups content in natural cellulose fibers was studied. Changes in fibers obtained at various modification conditions were evaluated by determination of carbonyl and carboxyl group content in samples before and after modification. Oxidation with H2O2 leads to a significant increase in carbonyl group content already at shorter times and milder treatment conditions. Small change in carboxyl group content occurs at higher pH values (pH 11) and 6 vol % solution concentration. Taking into account nonselective nature of hydrogen peroxide as an oxidizing agent, the optimization of process in accordance with ultimate application of modified cellulose material can be performed by careful selection of oxidation conditions. PB - Beograd : Srpsko hemijsko društvo C3 - Knjiga radova / 50. jubilarno savetovanje Srpskog hemijskog društva, Beograd, 14-15. juni 2012 T1 - Uticaj parametara neselektivne oksidacije na sadržaj funkcionalnih grupa u celuloznim vlaknima T1 - Influence of the nonselective oxidation conditions onto functional groups content in cellulose fibers EP - 274 SP - 270 UR - https://hdl.handle.net/21.15107/rcub_technorep_6846 ER -
@conference{ author = "Kramar, Ana D. and Korica, Matea and Milanović, Jovana Ž. and Kostić, Mirjana M.", year = "2012", abstract = "In this paper, the influence of oxidation with hydrogen peroxide onto functional groups content in natural cellulose fibers was studied. Changes in fibers obtained at various modification conditions were evaluated by determination of carbonyl and carboxyl group content in samples before and after modification. Oxidation with H2O2 leads to a significant increase in carbonyl group content already at shorter times and milder treatment conditions. Small change in carboxyl group content occurs at higher pH values (pH 11) and 6 vol % solution concentration. Taking into account nonselective nature of hydrogen peroxide as an oxidizing agent, the optimization of process in accordance with ultimate application of modified cellulose material can be performed by careful selection of oxidation conditions.", publisher = "Beograd : Srpsko hemijsko društvo", journal = "Knjiga radova / 50. jubilarno savetovanje Srpskog hemijskog društva, Beograd, 14-15. juni 2012", title = "Uticaj parametara neselektivne oksidacije na sadržaj funkcionalnih grupa u celuloznim vlaknima, Influence of the nonselective oxidation conditions onto functional groups content in cellulose fibers", pages = "274-270", url = "https://hdl.handle.net/21.15107/rcub_technorep_6846" }
Kramar, A. D., Korica, M., Milanović, J. Ž.,& Kostić, M. M.. (2012). Uticaj parametara neselektivne oksidacije na sadržaj funkcionalnih grupa u celuloznim vlaknima. in Knjiga radova / 50. jubilarno savetovanje Srpskog hemijskog društva, Beograd, 14-15. juni 2012 Beograd : Srpsko hemijsko društvo., 270-274. https://hdl.handle.net/21.15107/rcub_technorep_6846
Kramar AD, Korica M, Milanović JŽ, Kostić MM. Uticaj parametara neselektivne oksidacije na sadržaj funkcionalnih grupa u celuloznim vlaknima. in Knjiga radova / 50. jubilarno savetovanje Srpskog hemijskog društva, Beograd, 14-15. juni 2012. 2012;:270-274. https://hdl.handle.net/21.15107/rcub_technorep_6846 .
Kramar, Ana D., Korica, Matea, Milanović, Jovana Ž., Kostić, Mirjana M., "Uticaj parametara neselektivne oksidacije na sadržaj funkcionalnih grupa u celuloznim vlaknima" in Knjiga radova / 50. jubilarno savetovanje Srpskog hemijskog društva, Beograd, 14-15. juni 2012 (2012):270-274, https://hdl.handle.net/21.15107/rcub_technorep_6846 .