Supplementary material for the article: Simić, Z. V.; Radović, I. R.; Kijevčanin, M. Lj. Measurement and Correlation of Liquid–Liquid Equilibrium Data for Ternary Systems Water + C1–C3 Alcohols + Diethyl Adipate at 298.15 K and Atmospheric Pressure. Journal of Chemical and Engineering Data 2024. https://doi.org/10.1021/acs.jced.3c00708
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This paper investigates the feasibility of using diethyl adipate (DEA), a green organic solvent, as a separation agent for extracting various alcohols from aqueous solutions. In order to achieve this, liquid-liquid equilibria (LLE) experiments were carried out for four ternary systems: {water + methanol + DEA}, {water + ethanol + DEA}, {water + 1-propanol + DEA}, and {water + 2-propanol + DEA} at 298.15 K and atmospheric pressure. LLE experiments involve determination of certain thermodynamic data such as binodal curves and cloud-point data. Binodal curve data were determined by the cloud-point method using the titration technique, while the tie-line data were determined by optimizing the parameters based on the experimental measurements of the refractive index. Additionally, the distribution coefficients and the separation factors were calculated within the immiscibility region. Hand and Othmer-Tobias correlations were used to examine the reliability of the tie-line data. Also, the ex...perimental ternary LLE data were correlated using the UNIversal QUAsiChemical (UNIQUAC) activity coefficient models. The results confirm that that DEA is a suitable choice for extracting methanol, ethanol, 1-propanol, and 2-propanol from water. The potential of DEA as a separation agent followed the sequence methanol < ethanol < 2-propanol < 1-propanol. UNIQUAC model proved to be effective in correlating the LLE data.
Izvor:
Journal of Chemical and Engineering Data, 2024Izdavač:
- American Chemical Society
Finansiranje / projekti:
- Ministarstvo nauke, tehnološkog razvoja i inovacija Republike Srbije, institucionalno finansiranje - 200135 (Univerzitet u Beogradu, Tehnološko-metalurški fakultet) (RS-MESTD-inst-2020-200135)
- Ministarstvo nauke, tehnološkog razvoja i inovacija Republike Srbije, institucionalno finansiranje - 200287 (Inovacioni centar Tehnološko-metalurškog fakulteta u Beogradu doo) (RS-MESTD-inst-2020-200287)
Napomena:
- Related to: https://technorep.tmf.bg.ac.rs/handle/123456789/7342
- Supplementary material for: https://doi.org/10.1021/acs.jced.3c00708
Povezane informacije:
Institucija/grupa
Tehnološko-metalurški fakultetTY - DATA AU - Simić, Zoran V. AU - Radović, Ivona R. AU - Kijevčanin, Mirjana Lj. PY - 2024 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7343 AB - This paper investigates the feasibility of using diethyl adipate (DEA), a green organic solvent, as a separation agent for extracting various alcohols from aqueous solutions. In order to achieve this, liquid-liquid equilibria (LLE) experiments were carried out for four ternary systems: {water + methanol + DEA}, {water + ethanol + DEA}, {water + 1-propanol + DEA}, and {water + 2-propanol + DEA} at 298.15 K and atmospheric pressure. LLE experiments involve determination of certain thermodynamic data such as binodal curves and cloud-point data. Binodal curve data were determined by the cloud-point method using the titration technique, while the tie-line data were determined by optimizing the parameters based on the experimental measurements of the refractive index. Additionally, the distribution coefficients and the separation factors were calculated within the immiscibility region. Hand and Othmer-Tobias correlations were used to examine the reliability of the tie-line data. Also, the experimental ternary LLE data were correlated using the UNIversal QUAsiChemical (UNIQUAC) activity coefficient models. The results confirm that that DEA is a suitable choice for extracting methanol, ethanol, 1-propanol, and 2-propanol from water. The potential of DEA as a separation agent followed the sequence methanol < ethanol < 2-propanol < 1-propanol. UNIQUAC model proved to be effective in correlating the LLE data. PB - American Chemical Society T2 - Journal of Chemical and Engineering Data T1 - Supplementary material for the article: Simić, Z. V.; Radović, I. R.; Kijevčanin, M. Lj. Measurement and Correlation of Liquid–Liquid Equilibrium Data for Ternary Systems Water + C1–C3 Alcohols + Diethyl Adipate at 298.15 K and Atmospheric Pressure. Journal of Chemical and Engineering Data 2024. https://doi.org/10.1021/acs.jced.3c00708 UR - https://hdl.handle.net/21.15107/rcub_technorep_7343 ER -
@misc{ author = "Simić, Zoran V. and Radović, Ivona R. and Kijevčanin, Mirjana Lj.", year = "2024", abstract = "This paper investigates the feasibility of using diethyl adipate (DEA), a green organic solvent, as a separation agent for extracting various alcohols from aqueous solutions. In order to achieve this, liquid-liquid equilibria (LLE) experiments were carried out for four ternary systems: {water + methanol + DEA}, {water + ethanol + DEA}, {water + 1-propanol + DEA}, and {water + 2-propanol + DEA} at 298.15 K and atmospheric pressure. LLE experiments involve determination of certain thermodynamic data such as binodal curves and cloud-point data. Binodal curve data were determined by the cloud-point method using the titration technique, while the tie-line data were determined by optimizing the parameters based on the experimental measurements of the refractive index. Additionally, the distribution coefficients and the separation factors were calculated within the immiscibility region. Hand and Othmer-Tobias correlations were used to examine the reliability of the tie-line data. Also, the experimental ternary LLE data were correlated using the UNIversal QUAsiChemical (UNIQUAC) activity coefficient models. The results confirm that that DEA is a suitable choice for extracting methanol, ethanol, 1-propanol, and 2-propanol from water. The potential of DEA as a separation agent followed the sequence methanol < ethanol < 2-propanol < 1-propanol. UNIQUAC model proved to be effective in correlating the LLE data.", publisher = "American Chemical Society", journal = "Journal of Chemical and Engineering Data", title = "Supplementary material for the article: Simić, Z. V.; Radović, I. R.; Kijevčanin, M. Lj. Measurement and Correlation of Liquid–Liquid Equilibrium Data for Ternary Systems Water + C1–C3 Alcohols + Diethyl Adipate at 298.15 K and Atmospheric Pressure. Journal of Chemical and Engineering Data 2024. https://doi.org/10.1021/acs.jced.3c00708", url = "https://hdl.handle.net/21.15107/rcub_technorep_7343" }
Simić, Z. V., Radović, I. R.,& Kijevčanin, M. Lj.. (2024). Supplementary material for the article: Simić, Z. V.; Radović, I. R.; Kijevčanin, M. Lj. Measurement and Correlation of Liquid–Liquid Equilibrium Data for Ternary Systems Water + C1–C3 Alcohols + Diethyl Adipate at 298.15 K and Atmospheric Pressure. Journal of Chemical and Engineering Data 2024. https://doi.org/10.1021/acs.jced.3c00708. in Journal of Chemical and Engineering Data American Chemical Society.. https://hdl.handle.net/21.15107/rcub_technorep_7343
Simić ZV, Radović IR, Kijevčanin ML. Supplementary material for the article: Simić, Z. V.; Radović, I. R.; Kijevčanin, M. Lj. Measurement and Correlation of Liquid–Liquid Equilibrium Data for Ternary Systems Water + C1–C3 Alcohols + Diethyl Adipate at 298.15 K and Atmospheric Pressure. Journal of Chemical and Engineering Data 2024. https://doi.org/10.1021/acs.jced.3c00708. in Journal of Chemical and Engineering Data. 2024;. https://hdl.handle.net/21.15107/rcub_technorep_7343 .
Simić, Zoran V., Radović, Ivona R., Kijevčanin, Mirjana Lj., "Supplementary material for the article: Simić, Z. V.; Radović, I. R.; Kijevčanin, M. Lj. Measurement and Correlation of Liquid–Liquid Equilibrium Data for Ternary Systems Water + C1–C3 Alcohols + Diethyl Adipate at 298.15 K and Atmospheric Pressure. Journal of Chemical and Engineering Data 2024. https://doi.org/10.1021/acs.jced.3c00708" in Journal of Chemical and Engineering Data (2024), https://hdl.handle.net/21.15107/rcub_technorep_7343 .