Novel electrolyte for zinc-polyaniline batteries
Samo za registrovane korisnike
2006
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
Electrochemical behavior of zinc and polyaniline (PANI) electrode polymerized from 0.1 M HCl and 0.1 M aniline on graphite electrode, in 0.2 M ZnCl2 and 0.50 M NH4Cl (chloride electrolyte) and with addition of 0.33 M Na-citrate (chloride/citrate electrolyte) were investigated. In the chloride/citrate comparing with chloride containing electrolyte for the zinc electrode negative shift of the open circuit potential of 150 mV, decreases of exchange current density for more than order of magnitude and increase of cathodic Tafel slope, due to the zinc ions complexation, were observed. In citrate/chloride electrolyte zinc dendrite fonnation were completely suppressed. PANI electrodes show better discharge characteristic in chloride/citrate electrolyte with determined maximum discharge capacity of 164 mAh g(-1).
Ključne reči:
polyaniline / zinc / batteries / chloride / citrates / dendritesIzvor:
Journal of Power Sources, 2006, 160, 2, 1447-1450Izdavač:
- Elsevier Science Bv, Amsterdam
DOI: 10.1016/j.jpowsour.2006.02.096
ISSN: 0378-7753
WoS: 000241411600093
Scopus: 2-s2.0-33748964677
Institucija/grupa
Tehnološko-metalurški fakultetTY - JOUR AU - Jugović, Branimir AU - Trišović, Tomislav AU - Stevanović, Jasmina AU - Maksimović, M. AU - Grgur, Branimir PY - 2006 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/919 AB - Electrochemical behavior of zinc and polyaniline (PANI) electrode polymerized from 0.1 M HCl and 0.1 M aniline on graphite electrode, in 0.2 M ZnCl2 and 0.50 M NH4Cl (chloride electrolyte) and with addition of 0.33 M Na-citrate (chloride/citrate electrolyte) were investigated. In the chloride/citrate comparing with chloride containing electrolyte for the zinc electrode negative shift of the open circuit potential of 150 mV, decreases of exchange current density for more than order of magnitude and increase of cathodic Tafel slope, due to the zinc ions complexation, were observed. In citrate/chloride electrolyte zinc dendrite fonnation were completely suppressed. PANI electrodes show better discharge characteristic in chloride/citrate electrolyte with determined maximum discharge capacity of 164 mAh g(-1). PB - Elsevier Science Bv, Amsterdam T2 - Journal of Power Sources T1 - Novel electrolyte for zinc-polyaniline batteries EP - 1450 IS - 2 SP - 1447 VL - 160 DO - 10.1016/j.jpowsour.2006.02.096 ER -
@article{ author = "Jugović, Branimir and Trišović, Tomislav and Stevanović, Jasmina and Maksimović, M. and Grgur, Branimir", year = "2006", abstract = "Electrochemical behavior of zinc and polyaniline (PANI) electrode polymerized from 0.1 M HCl and 0.1 M aniline on graphite electrode, in 0.2 M ZnCl2 and 0.50 M NH4Cl (chloride electrolyte) and with addition of 0.33 M Na-citrate (chloride/citrate electrolyte) were investigated. In the chloride/citrate comparing with chloride containing electrolyte for the zinc electrode negative shift of the open circuit potential of 150 mV, decreases of exchange current density for more than order of magnitude and increase of cathodic Tafel slope, due to the zinc ions complexation, were observed. In citrate/chloride electrolyte zinc dendrite fonnation were completely suppressed. PANI electrodes show better discharge characteristic in chloride/citrate electrolyte with determined maximum discharge capacity of 164 mAh g(-1).", publisher = "Elsevier Science Bv, Amsterdam", journal = "Journal of Power Sources", title = "Novel electrolyte for zinc-polyaniline batteries", pages = "1450-1447", number = "2", volume = "160", doi = "10.1016/j.jpowsour.2006.02.096" }
Jugović, B., Trišović, T., Stevanović, J., Maksimović, M.,& Grgur, B.. (2006). Novel electrolyte for zinc-polyaniline batteries. in Journal of Power Sources Elsevier Science Bv, Amsterdam., 160(2), 1447-1450. https://doi.org/10.1016/j.jpowsour.2006.02.096
Jugović B, Trišović T, Stevanović J, Maksimović M, Grgur B. Novel electrolyte for zinc-polyaniline batteries. in Journal of Power Sources. 2006;160(2):1447-1450. doi:10.1016/j.jpowsour.2006.02.096 .
Jugović, Branimir, Trišović, Tomislav, Stevanović, Jasmina, Maksimović, M., Grgur, Branimir, "Novel electrolyte for zinc-polyaniline batteries" in Journal of Power Sources, 160, no. 2 (2006):1447-1450, https://doi.org/10.1016/j.jpowsour.2006.02.096 . .