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Temperature dependent oxygen electrochemistry on platinum low index single crystal surfaces in acid solutions
(Natl Research Council Canada, Ottawa, 1997)
Using the rotating ring-disk technique (RRDPt(hkl)E), the oxygen-reduction reaction (ORR) was studied in sulfuric acid solution over the temperature range 298-333 K. At the same temperature, the exchange current density ...
Temperature-dependent hydrogen electrochemistry on platinum low-index single-crystal surfaces in acid solutions
(Amer Chemical Soc, Washington, 1997)
The hydrogen evolution (HER) and the hydrogen oxidation reaction (HOR) were studied on platinum single crystals in a sulfuric acid solution over the temperature range 274-333 K. We found, for the first rime, that at a fixed ...
Thermogravimetric characterisation of poly(methyl methacrylate) photopolymerised by colloidal cadmium sulphide
(Springer, Dordrecht, 1997)
The thermal stability of poly(methyl methacrylate) (PMMA) photopolymerised using colloidal cadmium sulphide as the photoinitiator was studied by thermogravimetry (TG) and differential TG (DTG). The thermal stability of the ...
Electrooxidation of H-2/CO mixtures on a well-characterized Pt75Mo25 alloy surface
(Amer Chemical Soc, Washington, 1997)
The electrochemical oxidation of hydrogen in the presence of carbon monoxide (0.05-2%) on a well-characterized Pt75Mo25 alloy surface was examined using the rotating disk electrode technique in 0.5 M H2SO4 at 333 K. The ...
Relationship between fracture resistance and critical temperature difference in ceramic materials
(Plenum Publ Corp, New York, 1997)
The resistance of ceramics to thermal shock can be characterized using either a parameter of their resistance to fracture R or the critical temperature difference Delta T-c = Delta T-c (Bi). It is demonstrated that a ...
Size distribution of ultrafine spherical ceramic powders obtained by ultrasonic spray pyrolysis
(Trans Tech Publications Ltd., 1997)
Comparative analysis of experimentally determined particle size distribution and theoretically calculated aerosole drop size distribution (obtained on the basis of 3D model of spherical / elliptical waves generated by the ...
Recent advances in homogeneous and heterogeneous asymmetric catalysis with nitrogen-containing ligands
(Baltzer Sci Publ Bv, Bussum, 1997)
Nitrogen-containing chiral ligands are being used more and more in asymmetric catalysis. This article is an overview of results published in 1993-1996 in this field and tries to open new perspectives for this type of ligand, ...
Polymeric and immobilized crown compounds, material for ion separation
(Pergamon-Elsevier Science Ltd, Oxford, 1997)
We describe the synthesis of ionoselective polymers bearing different pendant crown ethers. The synthesis was applied to various macrocycles. We discuss the influence of macrocyclic cavity Size and rigidity of the polymers ...
Preparation of thermoplastic starch
(Serbian Chemical Society, Belgrade, 1997)
Native starch and WX-starch, i.e., native starch enriched with amylopectin, were mixed with plasticizers and thermomechanically treated in a twin screw mixer in order to obtain thermoplastic starch. Ethylene glycol, propane ...
The thermal degradation of polymethacrylonitrile with different end groups
(Springer, Dordrecht, 1997)
Polymethacrylonitrile (PMAN) was prepared by bulk, solution and precipitation polymerization. The thermal stability of the polymer, which is affected by the structure of the chain end groups, was studied by non-isothermal ...