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Now showing items 11-20 of 43
An electrochemical illustration of the mathematical modelling of chlorine impact and acidification in electrochemical tumour treatment and its application on an agar-agar gel system
(Elsevier, 2003)
Electrochemical treatment (EchT) of tumours, which is also known as electrochemical therapy, implies that tumour tissue is treated with a direct current through the use of electrodes. This was shown earlier when the major ...
On the deactivation mechanism of RuO2-TiO2/Ti anodes prepared by the sol-gel procedure
(Elsevier Science Sa, Lausanne, 2005)
The deactivation process that leads to the end of titanium supported RuO2-TiO2 coating service life, for anodes prepared from RuO2 and TiO2 sols, as well as by the conventional thermal decomposition of RuCl3 and TiCl3, was ...
The potentiostatic current transients and the role of local diffusion fields in formation of the 2D lead dendrites from the concentrated electrolyte
(Elsevier, 2015)
Electrodeposition of lead from the concentrated nitrate electrolyte in the potentiostatic regime of electrolysis has been investigated by the analysis of the potentiostatic current transients and scanning electron microscope ...
Oxygen reduction reaction on Pt(111): effects of bromide
(Elsevier Science Sa, Lausanne, 1999)
Using the rotating ring-disk technique (RRDE) the oxygen reduction reaction (orr) was studied on the Pt(111) surface in the presence of Br- anions. We found that the orr at the Pt(111) \ Br-ad interface is always accompanied ...
Oscillatory behavior in the electrochemical oxidation of formic acid on Pt(100): rotation and temperature effects
(Elsevier Science Sa, Lausanne, 2001)
We investigated the oscillatory behavior in the kinetics of formic acid electrooxidation on Pt(100) in 1 mM HClO4 solution. We studied the effect of different experimental parameters on the oscillatory behavior, viz. defined ...
Rate expression for electrochemical oxidation of methanol on a direct methanol fuel cell anode
(Elsevier, 2005)
The kinetics of methanol oxidation at PtRu catalyst was investigated on a membrane electrode assembly (MEA) in a cyclone flow cell. Catalyst characterisation was done by means of cyclic voltammetry and CO stripping. The ...
On the kinetics of the hydrogen evolution reaction on nickel in alkaline solution - Part II. Effect of temperature
(Elsevier S.A., 2001)
The effect of temperature on the kinetics of the hydrogen evolution reaction (her) on nickel in 1.0 mol dm (-3) NaOH solution was studied. In this article, four sets of experiments were done in a non-isothermal cell. In ...
A comparative study of the electrochemical properties of carbon nanotubes and carbon black
(Elsevier Science Sa, Lausanne, 2009)
Two samples of commercial multi-walled carbon nanotubes (Sigma-Aldrich and Sun Nanotech) and a sample of carbon black (Vulcan XC-72R) were investigated in raw state and after the activation in nitric and sulfuric acid by ...
Electrochemical instability of Pt nanoparticles probed by formic acid oxidation
(Elsevier Science Sa, Lausanne, 2012)
A detrimental effect of CO on the stability of Pt nanoparticles, which is important for fuel cells technology, is demonstrated by the change in HCOOH kinetics on Pt nanoparticles caused by the presence of CO in the ...
Electrochemical determination of sildenafil citrate as standard, in tablets and spiked with human serum at gold and cystein modified gold electrode
(Elsevier Science Sa, Lausanne, 2016)
Nonmedical use of sildenafil citrate (SC) requires new methods for drug determination in human serum and in tablets. SC as standard and in Sildena (R) tablets is determined by square wave voltammetry (SWV) in 0.1 M H2SO4 ...