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Kinetic Modeling of Sunflower Oil Methanolysis Catalyzed by Calcium-Based Catalysts
(Wiley-VCH Verlag, 2015)
The kinetic model originally developed for quicklime-catalyzed methanolysis of sunflower oil was tested for another three calcium-based catalysts, namely, neat CaO, Ca(OH)2, and CaO·ZnO. This model includes the changing ...
Structure sensitivity of dimethylamine deep oxidation over Pt/Al2O3 catalysts
(Elsevier, 2009)
The deep oxidation of dimethylamine (DMA) was studied over Pt/Al2O3 catalysts with small (1 nm) and large (7.8-15.5 nm) Pt crystallite sizes. The turnover frequency (TOF) was higher for the large than for the small Pt ...
The effect of agitation intensity on alkali-catalyzed methanolysis of sunflower oil
(Elsevier, 2007)
The sunflower oil methanolysis was studied in a stirred reactor at different agitation speeds. The measurements of drop size, drop size distribution and the conversion degree demonstrate the effects of the agitation speed ...
Thermal characterization and kinetic analysis of non-isothermal decomposition process of Bauxite red mud. Estimation of density distribution function of the apparent activation energy
(Elsevier, 2013)
Thermal characterization and kinetic analysis of non-isothermal decomposition process of Bauxite red mud were carried out using thermogravimetry (TG), derivative thermogravimetry (DTG), differential scanning calorimetry ...
Decrease of free fatty acid content in vegetable oil using silica supported ferric sulfate catalyst
(Elsevier Sci Ltd, Oxford, 2012)
A difficulty of biodiesel synthesis based on alkaline catalysts obviously exists if free fatty acids (FFAs) content in vegetable oil is above 0.5 wt.%. In this study, the ferric sulfate supported on silica (Fe-2(SO4)(3)/SiO2) ...
Batch and semicontinuous production of L-ascorbyl oleate catalyzed by CALB immobilized onto Purolite (R) MN102
(Elsevier, Amsterdam, 2017)
L-Ascorbyl oleate is recognized as efficient liposoluble antioxidant and biosurfactant which can be synthesized by using immobilized lipases as catalysts in organic media. However, development of economical production ...
Kinetics of sunflower oil methanolysis at low temperatures
(Elsevier Ltd, 2008)
The kinetics of the sunflower oil methanolysis process was studied at lower temperatures (10-30 °C). The sigmoidal kinetics of the process was explained by the mass transfer controlled region in the initial heterogenous ...
On the thermal degradation of 3-methylaminopropylamine captured inside the aluminum phosphate analog of ULM-3
(Springer, Dordrecht, 2010)
An open-framework aluminophosphate analog of the fluorogallophosphate structure-type ULM-3 was obtained by hydrothermal crystallization of an aqueous aluminum phosphate suspension in the presence of 3-methylpropylamine ...
Kinetics of the hydrogen evolution reaction on Ni-(Ebonex-supported Ru) composite coatings in alkaline solution
(Pergamon-Elsevier Science Ltd, Oxford, 2013)
The hydrogen evolution reaction (HER) was studied on Ni, Ni-Ebonex and Ni-(Ebonex-Ru) coatings in 1 mol dm(-3) NaOH solution at 25 degrees C. The composite coatings were electro-deposited from a nickel Watts-type bath ...
Modeling the kinetics of calcium hydroxide catalyzed methanolysis of sunflower oil
(Elsevier, 2010)
The kinetics of Ca(OH)2-catalyzed methanolysis of sunflower oil was studied at a moderate temperature (60 °C), a methanol-to-oil molar ratio (6:1) and different catalyst amounts (from 1% to 10% based on oil weight). The ...