Kinetics of the thermal decomposition of 3-methylaminopropylamine which was used as a structure-directing agent in the synthesis of AlPO4-21 has been studied under isothermal and non-isothermal conditions. The decomposition is a single-step reaction occurring in the 573-663 K range. It is a phase-boundary-controlled process, described by the 'F2/3, R3' kinetic model. The activation energy values obtained under the non-isothermal and isothermal conditions lie in the 173-151 kJ mol(-1) range.
TY - JOUR
AU - Stojaković, D.
AU - Rajić, Nevenka
AU - Sajić, Sanja
AU - Zabukovec-Logar, Nataša
AU - Kaučič, Venčeslav
PY - 2007
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1115
AB - Kinetics of the thermal decomposition of 3-methylaminopropylamine which was used as a structure-directing agent in the synthesis of AlPO4-21 has been studied under isothermal and non-isothermal conditions. The decomposition is a single-step reaction occurring in the 573-663 K range. It is a phase-boundary-controlled process, described by the 'F2/3, R3' kinetic model. The activation energy values obtained under the non-isothermal and isothermal conditions lie in the 173-151 kJ mol(-1) range.
PB - Springer, Dordrecht
T2 - Journal of Thermal Analysis and Calorimetry
T1 - A kinetic study of the thermal degradation of 3-methylaminopropylamine inside AlPO4-21
EP - 341
IS - 2
SP - 337
VL - 87
DO - 10.1007/s10973-005-7382-4
ER -
@article{
author = "Stojaković, D. and Rajić, Nevenka and Sajić, Sanja and Zabukovec-Logar, Nataša and Kaučič, Venčeslav",
year = "2007",
abstract = "Kinetics of the thermal decomposition of 3-methylaminopropylamine which was used as a structure-directing agent in the synthesis of AlPO4-21 has been studied under isothermal and non-isothermal conditions. The decomposition is a single-step reaction occurring in the 573-663 K range. It is a phase-boundary-controlled process, described by the 'F2/3, R3' kinetic model. The activation energy values obtained under the non-isothermal and isothermal conditions lie in the 173-151 kJ mol(-1) range.",
publisher = "Springer, Dordrecht",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "A kinetic study of the thermal degradation of 3-methylaminopropylamine inside AlPO4-21",
pages = "341-337",
number = "2",
volume = "87",
doi = "10.1007/s10973-005-7382-4"
}
Stojaković, D., Rajić, N., Sajić, S., Zabukovec-Logar, N.,& Kaučič, V.. (2007). A kinetic study of the thermal degradation of 3-methylaminopropylamine inside AlPO4-21. in Journal of Thermal Analysis and Calorimetry
Springer, Dordrecht., 87(2), 337-341.
https://doi.org/10.1007/s10973-005-7382-4
Stojaković D, Rajić N, Sajić S, Zabukovec-Logar N, Kaučič V. A kinetic study of the thermal degradation of 3-methylaminopropylamine inside AlPO4-21. in Journal of Thermal Analysis and Calorimetry. 2007;87(2):337-341.
doi:10.1007/s10973-005-7382-4 .
Stojaković, D., Rajić, Nevenka, Sajić, Sanja, Zabukovec-Logar, Nataša, Kaučič, Venčeslav, "A kinetic study of the thermal degradation of 3-methylaminopropylamine inside AlPO4-21" in Journal of Thermal Analysis and Calorimetry, 87, no. 2 (2007):337-341,
https://doi.org/10.1007/s10973-005-7382-4 . .
