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Volumetric properties of the ternary system ethanol plus chloroform plus benzene at temperature range (288.15-313.15) K: Experimental data, correlation and prediction by cubic EOS

Authorized Users Only
2007
Authors
Kijevčanin, Mirjana
Šerbanović, Slobodan P.
Radović, Ivona
Đorđević, Bojan D.
Tasić, Aleksandar Ž.
Article (Published version)
Metadata
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Abstract
Densities p of the ternary system (ethanol + chloroform + benzene) and binaries (ethanol + chloroform) and (chloroform + benzene), have been measured at six temperatures (288.15, 293.15, 298.15, 303.15, 308.15, 313.15) K and pressure 101.33 kPa with an Anton Paar DMA 5000 digital vibrating tube densimeter. Excess molar volumes V-E were calculated from these densities data and fitted by the polynomial Redlich-Kister (for binary data) and Nagata and Tamura (for ternary data) equations. Radojkovic et al. equation was used for the prediction of the V-E of ternary data. The obtained results have been explained in terms of different effects between molecules of present species, taking into consideration influence of temperature on them. For the correlation of binary and prediction of ternary V-E with cubic equation of state (CEOS), the Peng-Robinson-Stryjek-Vera equation of state (PRSV CEOS) coupled with two different types of independent and temperature dependent mixing rules: (i) the compo...sition dependent (vdW1) and (ii) CEOS with G(E) equation (CEOS/G(E)) Twu and co-workers (TCBT) model were used. For the correlation of ternary V data only Twu and co-workers (TCBT) mixing rules were used. Rho

Keywords:
experimental / ternary system / densities / excess molar volumes / cubic FOS
Source:
Fluid Phase Equilibria, 2007, 251, 2, 78-92
Publisher:
  • Elsevier Science Bv, Amsterdam

DOI: 10.1016/j.fluid.2006.11.005

ISSN: 0378-3812

WoS: 000243798600002

Scopus: 2-s2.0-33846160163
[ Google Scholar ]
33
30
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1122
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Kijevčanin, Mirjana
AU  - Šerbanović, Slobodan P.
AU  - Radović, Ivona
AU  - Đorđević, Bojan D.
AU  - Tasić, Aleksandar Ž.
PY  - 2007
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1122
AB  - Densities p of the ternary system (ethanol + chloroform + benzene) and binaries (ethanol + chloroform) and (chloroform + benzene), have been measured at six temperatures (288.15, 293.15, 298.15, 303.15, 308.15, 313.15) K and pressure 101.33 kPa with an Anton Paar DMA 5000 digital vibrating tube densimeter. Excess molar volumes V-E were calculated from these densities data and fitted by the polynomial Redlich-Kister (for binary data) and Nagata and Tamura (for ternary data) equations. Radojkovic et al. equation was used for the prediction of the V-E of ternary data. The obtained results have been explained in terms of different effects between molecules of present species, taking into consideration influence of temperature on them. For the correlation of binary and prediction of ternary V-E with cubic equation of state (CEOS), the Peng-Robinson-Stryjek-Vera equation of state (PRSV CEOS) coupled with two different types of independent and temperature dependent mixing rules: (i) the composition dependent (vdW1) and (ii) CEOS with G(E) equation (CEOS/G(E)) Twu and co-workers (TCBT) model were used. For the correlation of ternary V data only Twu and co-workers (TCBT) mixing rules were used. Rho
PB  - Elsevier Science Bv, Amsterdam
T2  - Fluid Phase Equilibria
T1  - Volumetric properties of the ternary system ethanol plus chloroform plus benzene at temperature range (288.15-313.15) K: Experimental data, correlation and prediction by cubic EOS
EP  - 92
IS  - 2
SP  - 78
VL  - 251
DO  - 10.1016/j.fluid.2006.11.005
ER  - 
@article{
author = "Kijevčanin, Mirjana and Šerbanović, Slobodan P. and Radović, Ivona and Đorđević, Bojan D. and Tasić, Aleksandar Ž.",
year = "2007",
abstract = "Densities p of the ternary system (ethanol + chloroform + benzene) and binaries (ethanol + chloroform) and (chloroform + benzene), have been measured at six temperatures (288.15, 293.15, 298.15, 303.15, 308.15, 313.15) K and pressure 101.33 kPa with an Anton Paar DMA 5000 digital vibrating tube densimeter. Excess molar volumes V-E were calculated from these densities data and fitted by the polynomial Redlich-Kister (for binary data) and Nagata and Tamura (for ternary data) equations. Radojkovic et al. equation was used for the prediction of the V-E of ternary data. The obtained results have been explained in terms of different effects between molecules of present species, taking into consideration influence of temperature on them. For the correlation of binary and prediction of ternary V-E with cubic equation of state (CEOS), the Peng-Robinson-Stryjek-Vera equation of state (PRSV CEOS) coupled with two different types of independent and temperature dependent mixing rules: (i) the composition dependent (vdW1) and (ii) CEOS with G(E) equation (CEOS/G(E)) Twu and co-workers (TCBT) model were used. For the correlation of ternary V data only Twu and co-workers (TCBT) mixing rules were used. Rho",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Fluid Phase Equilibria",
title = "Volumetric properties of the ternary system ethanol plus chloroform plus benzene at temperature range (288.15-313.15) K: Experimental data, correlation and prediction by cubic EOS",
pages = "92-78",
number = "2",
volume = "251",
doi = "10.1016/j.fluid.2006.11.005"
}
Kijevčanin, M., Šerbanović, S. P., Radović, I., Đorđević, B. D.,& Tasić, A. Ž.. (2007). Volumetric properties of the ternary system ethanol plus chloroform plus benzene at temperature range (288.15-313.15) K: Experimental data, correlation and prediction by cubic EOS. in Fluid Phase Equilibria
Elsevier Science Bv, Amsterdam., 251(2), 78-92.
https://doi.org/10.1016/j.fluid.2006.11.005
Kijevčanin M, Šerbanović SP, Radović I, Đorđević BD, Tasić AŽ. Volumetric properties of the ternary system ethanol plus chloroform plus benzene at temperature range (288.15-313.15) K: Experimental data, correlation and prediction by cubic EOS. in Fluid Phase Equilibria. 2007;251(2):78-92.
doi:10.1016/j.fluid.2006.11.005 .
Kijevčanin, Mirjana, Šerbanović, Slobodan P., Radović, Ivona, Đorđević, Bojan D., Tasić, Aleksandar Ž., "Volumetric properties of the ternary system ethanol plus chloroform plus benzene at temperature range (288.15-313.15) K: Experimental data, correlation and prediction by cubic EOS" in Fluid Phase Equilibria, 251, no. 2 (2007):78-92,
https://doi.org/10.1016/j.fluid.2006.11.005 . .

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