Cordierite gel was synthesized by non-hydrolytic sol-gel route, starting from aluminum chloride, TEOS and magnesium chloride dissolved in absolute ethanol. Crystallization of p.-cordierite from gel at temperatures between 900 and 1000 degrees C was confirmed by differential thermal analyses, X-ray and FTIR spectroscopy. Higher calcination temperature resulted in the transformation of mu- to alpha-cordierite. The value of Avrami parameter n = 2.23 for the mu-cordierite crystallization indicates contribution of different simultaneous mechanisms: homogeneous nucleation and three-dimensional crystallite growth due to homogeneity of gel and surface crystallization due to submicron particles of the gel.
TY - JOUR
AU - Janković-Častvan, Ivona
AU - Lazarević, Slavica
AU - Tanasković, Dušanka
AU - Orlović, Aleksandar
AU - Petrović, Rada
AU - Janaćković, Đorđe
PY - 2007
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1172
AB - Cordierite gel was synthesized by non-hydrolytic sol-gel route, starting from aluminum chloride, TEOS and magnesium chloride dissolved in absolute ethanol. Crystallization of p.-cordierite from gel at temperatures between 900 and 1000 degrees C was confirmed by differential thermal analyses, X-ray and FTIR spectroscopy. Higher calcination temperature resulted in the transformation of mu- to alpha-cordierite. The value of Avrami parameter n = 2.23 for the mu-cordierite crystallization indicates contribution of different simultaneous mechanisms: homogeneous nucleation and three-dimensional crystallite growth due to homogeneity of gel and surface crystallization due to submicron particles of the gel.
PB - Elsevier Sci Ltd, Oxford
T2 - Ceramics International
T1 - Phase transformation in cordierite gel synthesized by non-hydrolytic sol-gel route
EP - 1268
IS - 7
SP - 1263
VL - 33
DO - 10.1016/j.ceramint.2006.05.003
ER -
@article{
author = "Janković-Častvan, Ivona and Lazarević, Slavica and Tanasković, Dušanka and Orlović, Aleksandar and Petrović, Rada and Janaćković, Đorđe",
year = "2007",
abstract = "Cordierite gel was synthesized by non-hydrolytic sol-gel route, starting from aluminum chloride, TEOS and magnesium chloride dissolved in absolute ethanol. Crystallization of p.-cordierite from gel at temperatures between 900 and 1000 degrees C was confirmed by differential thermal analyses, X-ray and FTIR spectroscopy. Higher calcination temperature resulted in the transformation of mu- to alpha-cordierite. The value of Avrami parameter n = 2.23 for the mu-cordierite crystallization indicates contribution of different simultaneous mechanisms: homogeneous nucleation and three-dimensional crystallite growth due to homogeneity of gel and surface crystallization due to submicron particles of the gel.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Ceramics International",
title = "Phase transformation in cordierite gel synthesized by non-hydrolytic sol-gel route",
pages = "1268-1263",
number = "7",
volume = "33",
doi = "10.1016/j.ceramint.2006.05.003"
}
Janković-Častvan, I., Lazarević, S., Tanasković, D., Orlović, A., Petrović, R.,& Janaćković, Đ.. (2007). Phase transformation in cordierite gel synthesized by non-hydrolytic sol-gel route. in Ceramics International
Elsevier Sci Ltd, Oxford., 33(7), 1263-1268.
https://doi.org/10.1016/j.ceramint.2006.05.003
Janković-Častvan I, Lazarević S, Tanasković D, Orlović A, Petrović R, Janaćković Đ. Phase transformation in cordierite gel synthesized by non-hydrolytic sol-gel route. in Ceramics International. 2007;33(7):1263-1268.
doi:10.1016/j.ceramint.2006.05.003 .
Janković-Častvan, Ivona, Lazarević, Slavica, Tanasković, Dušanka, Orlović, Aleksandar, Petrović, Rada, Janaćković, Đorđe, "Phase transformation in cordierite gel synthesized by non-hydrolytic sol-gel route" in Ceramics International, 33, no. 7 (2007):1263-1268,
https://doi.org/10.1016/j.ceramint.2006.05.003 . .
