The transfer constant to benzene in the radical polymerisation of di-n-butyl itaconate, DBI, was measured at 60 degrees C and found to have the value of 2.2 x 10(-3). This value is surprisingly high considering that benzene has no readily extractable hydrogen atoms and is usually considered to be a relatively inert solvent in radical polymerisations. The high values of transfer constants in the radical polymerisation of itaconates must be taken into consideration when planning the tailored polymerisation of these monomers.
Keywords:
Polymerisation / Transfer constant / Benzene / Di-n-butyl itaconate
TY - JOUR
AU - Katsikas, Lynne
AU - Milovanović, Miloš
AU - Popović, Ivanka
PY - 2008
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1232
AB - The transfer constant to benzene in the radical polymerisation of di-n-butyl itaconate, DBI, was measured at 60 degrees C and found to have the value of 2.2 x 10(-3). This value is surprisingly high considering that benzene has no readily extractable hydrogen atoms and is usually considered to be a relatively inert solvent in radical polymerisations. The high values of transfer constants in the radical polymerisation of itaconates must be taken into consideration when planning the tailored polymerisation of these monomers.
PB - Pergamon-Elsevier Science Ltd, Oxford
T2 - European Polymer Journal
T1 - Hindered, 1,1-disubstituted monomers. Chain transfer to benzene in the radical polymerisation of di-n-butylitaconate
EP - 3031
IS - 9
SP - 3028
VL - 44
DO - 10.1016/j.eurpolymj.2008.06.039
ER -
@article{
author = "Katsikas, Lynne and Milovanović, Miloš and Popović, Ivanka",
year = "2008",
abstract = "The transfer constant to benzene in the radical polymerisation of di-n-butyl itaconate, DBI, was measured at 60 degrees C and found to have the value of 2.2 x 10(-3). This value is surprisingly high considering that benzene has no readily extractable hydrogen atoms and is usually considered to be a relatively inert solvent in radical polymerisations. The high values of transfer constants in the radical polymerisation of itaconates must be taken into consideration when planning the tailored polymerisation of these monomers.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "European Polymer Journal",
title = "Hindered, 1,1-disubstituted monomers. Chain transfer to benzene in the radical polymerisation of di-n-butylitaconate",
pages = "3031-3028",
number = "9",
volume = "44",
doi = "10.1016/j.eurpolymj.2008.06.039"
}
Katsikas, L., Milovanović, M.,& Popović, I.. (2008). Hindered, 1,1-disubstituted monomers. Chain transfer to benzene in the radical polymerisation of di-n-butylitaconate. in European Polymer Journal
Pergamon-Elsevier Science Ltd, Oxford., 44(9), 3028-3031.
https://doi.org/10.1016/j.eurpolymj.2008.06.039
Katsikas L, Milovanović M, Popović I. Hindered, 1,1-disubstituted monomers. Chain transfer to benzene in the radical polymerisation of di-n-butylitaconate. in European Polymer Journal. 2008;44(9):3028-3031.
doi:10.1016/j.eurpolymj.2008.06.039 .
Katsikas, Lynne, Milovanović, Miloš, Popović, Ivanka, "Hindered, 1,1-disubstituted monomers. Chain transfer to benzene in the radical polymerisation of di-n-butylitaconate" in European Polymer Journal, 44, no. 9 (2008):3028-3031,
https://doi.org/10.1016/j.eurpolymj.2008.06.039 . .
