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Hindered, 1,1-disubstituted monomers. Chain transfer to benzene in the radical polymerisation of di-n-butylitaconate

Samo za registrovane korisnike
2008
Autori
Katsikas, Lynne
Milovanović, Miloš
Popović, Ivanka
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentu
Apstrakt
The transfer constant to benzene in the radical polymerisation of di-n-butyl itaconate, DBI, was measured at 60 degrees C and found to have the value of 2.2 x 10(-3). This value is surprisingly high considering that benzene has no readily extractable hydrogen atoms and is usually considered to be a relatively inert solvent in radical polymerisations. The high values of transfer constants in the radical polymerisation of itaconates must be taken into consideration when planning the tailored polymerisation of these monomers.
Ključne reči:
Polymerisation / Transfer constant / Benzene / Di-n-butyl itaconate
Izvor:
European Polymer Journal, 2008, 44, 9, 3028-3031
Izdavač:
  • Pergamon-Elsevier Science Ltd, Oxford
Finansiranje / projekti:
  • Sinteza i karakterizacija polimera i polimernih (nano)kompozita definisane molekulske i nadmolekulske strukture (RS-142023)

DOI: 10.1016/j.eurpolymj.2008.06.039

ISSN: 0014-3057

WoS: 000260274400036

Scopus: 2-s2.0-50949116099
[ Google Scholar ]
4
4
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1232
Kolekcije
  • Radovi istraživača / Researchers’ publications (TMF)
Institucija/grupa
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Katsikas, Lynne
AU  - Milovanović, Miloš
AU  - Popović, Ivanka
PY  - 2008
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1232
AB  - The transfer constant to benzene in the radical polymerisation of di-n-butyl itaconate, DBI, was measured at 60 degrees C and found to have the value of 2.2 x 10(-3). This value is surprisingly high considering that benzene has no readily extractable hydrogen atoms and is usually considered to be a relatively inert solvent in radical polymerisations. The high values of transfer constants in the radical polymerisation of itaconates must be taken into consideration when planning the tailored polymerisation of these monomers.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - European Polymer Journal
T1  - Hindered, 1,1-disubstituted monomers. Chain transfer to benzene in the radical polymerisation of di-n-butylitaconate
EP  - 3031
IS  - 9
SP  - 3028
VL  - 44
DO  - 10.1016/j.eurpolymj.2008.06.039
ER  - 
@article{
author = "Katsikas, Lynne and Milovanović, Miloš and Popović, Ivanka",
year = "2008",
abstract = "The transfer constant to benzene in the radical polymerisation of di-n-butyl itaconate, DBI, was measured at 60 degrees C and found to have the value of 2.2 x 10(-3). This value is surprisingly high considering that benzene has no readily extractable hydrogen atoms and is usually considered to be a relatively inert solvent in radical polymerisations. The high values of transfer constants in the radical polymerisation of itaconates must be taken into consideration when planning the tailored polymerisation of these monomers.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "European Polymer Journal",
title = "Hindered, 1,1-disubstituted monomers. Chain transfer to benzene in the radical polymerisation of di-n-butylitaconate",
pages = "3031-3028",
number = "9",
volume = "44",
doi = "10.1016/j.eurpolymj.2008.06.039"
}
Katsikas, L., Milovanović, M.,& Popović, I.. (2008). Hindered, 1,1-disubstituted monomers. Chain transfer to benzene in the radical polymerisation of di-n-butylitaconate. in European Polymer Journal
Pergamon-Elsevier Science Ltd, Oxford., 44(9), 3028-3031.
https://doi.org/10.1016/j.eurpolymj.2008.06.039
Katsikas L, Milovanović M, Popović I. Hindered, 1,1-disubstituted monomers. Chain transfer to benzene in the radical polymerisation of di-n-butylitaconate. in European Polymer Journal. 2008;44(9):3028-3031.
doi:10.1016/j.eurpolymj.2008.06.039 .
Katsikas, Lynne, Milovanović, Miloš, Popović, Ivanka, "Hindered, 1,1-disubstituted monomers. Chain transfer to benzene in the radical polymerisation of di-n-butylitaconate" in European Polymer Journal, 44, no. 9 (2008):3028-3031,
https://doi.org/10.1016/j.eurpolymj.2008.06.039 . .

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