Hindered, 1,1-disubstituted monomers. Chain transfer to benzene in the radical polymerisation of di-n-butylitaconate
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2008
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Metapodaci
Prikaz svih podataka o dokumentuApstrakt
The transfer constant to benzene in the radical polymerisation of di-n-butyl itaconate, DBI, was measured at 60 degrees C and found to have the value of 2.2 x 10(-3). This value is surprisingly high considering that benzene has no readily extractable hydrogen atoms and is usually considered to be a relatively inert solvent in radical polymerisations. The high values of transfer constants in the radical polymerisation of itaconates must be taken into consideration when planning the tailored polymerisation of these monomers.
Ključne reči:
Polymerisation / Transfer constant / Benzene / Di-n-butyl itaconateIzvor:
European Polymer Journal, 2008, 44, 9, 3028-3031Izdavač:
- Pergamon-Elsevier Science Ltd, Oxford
Finansiranje / projekti:
DOI: 10.1016/j.eurpolymj.2008.06.039
ISSN: 0014-3057
WoS: 000260274400036
Scopus: 2-s2.0-50949116099
Institucija/grupa
Tehnološko-metalurški fakultetTY - JOUR AU - Katsikas, Lynne AU - Milovanović, Miloš AU - Popović, Ivanka PY - 2008 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1232 AB - The transfer constant to benzene in the radical polymerisation of di-n-butyl itaconate, DBI, was measured at 60 degrees C and found to have the value of 2.2 x 10(-3). This value is surprisingly high considering that benzene has no readily extractable hydrogen atoms and is usually considered to be a relatively inert solvent in radical polymerisations. The high values of transfer constants in the radical polymerisation of itaconates must be taken into consideration when planning the tailored polymerisation of these monomers. PB - Pergamon-Elsevier Science Ltd, Oxford T2 - European Polymer Journal T1 - Hindered, 1,1-disubstituted monomers. Chain transfer to benzene in the radical polymerisation of di-n-butylitaconate EP - 3031 IS - 9 SP - 3028 VL - 44 DO - 10.1016/j.eurpolymj.2008.06.039 ER -
@article{ author = "Katsikas, Lynne and Milovanović, Miloš and Popović, Ivanka", year = "2008", abstract = "The transfer constant to benzene in the radical polymerisation of di-n-butyl itaconate, DBI, was measured at 60 degrees C and found to have the value of 2.2 x 10(-3). This value is surprisingly high considering that benzene has no readily extractable hydrogen atoms and is usually considered to be a relatively inert solvent in radical polymerisations. The high values of transfer constants in the radical polymerisation of itaconates must be taken into consideration when planning the tailored polymerisation of these monomers.", publisher = "Pergamon-Elsevier Science Ltd, Oxford", journal = "European Polymer Journal", title = "Hindered, 1,1-disubstituted monomers. Chain transfer to benzene in the radical polymerisation of di-n-butylitaconate", pages = "3031-3028", number = "9", volume = "44", doi = "10.1016/j.eurpolymj.2008.06.039" }
Katsikas, L., Milovanović, M.,& Popović, I.. (2008). Hindered, 1,1-disubstituted monomers. Chain transfer to benzene in the radical polymerisation of di-n-butylitaconate. in European Polymer Journal Pergamon-Elsevier Science Ltd, Oxford., 44(9), 3028-3031. https://doi.org/10.1016/j.eurpolymj.2008.06.039
Katsikas L, Milovanović M, Popović I. Hindered, 1,1-disubstituted monomers. Chain transfer to benzene in the radical polymerisation of di-n-butylitaconate. in European Polymer Journal. 2008;44(9):3028-3031. doi:10.1016/j.eurpolymj.2008.06.039 .
Katsikas, Lynne, Milovanović, Miloš, Popović, Ivanka, "Hindered, 1,1-disubstituted monomers. Chain transfer to benzene in the radical polymerisation of di-n-butylitaconate" in European Polymer Journal, 44, no. 9 (2008):3028-3031, https://doi.org/10.1016/j.eurpolymj.2008.06.039 . .