Determination of glass temperature of polymers by inverse gas chromatography
Abstract
Inverse gas chromatography (IGC) is an attractive technique for polymer characterization due to possible simultaneous determination of various physicochemical properties of polymer systems merely from retention times of selected sorbates. The technique is especially advantageous to polymers that cannot be characterized by conventional methods. In this review, the utilization of the method for glass transition determination of homopolymers, copolymers and polymer blends is described. Advantages and drawbacks of the IGC method over traditionally used methods for glass transition temperature determination is discussed, along with the most important parameters that influence the precision and accuracy of the glass transition temperature (T-g) measurements.
Keywords:
IGC / retention mechanism / thermal transitions / Z-shaped retention diagram / polymer-solvent interactionsSource:
Journal of Chromatography A, 2008, 1195, 1-2, 1-15Publisher:
- Elsevier, Amsterdam
Funding / projects:
DOI: 10.1016/j.chroma.2008.05.009
ISSN: 0021-9673
PubMed: 18501369
WoS: 000257258800001
Scopus: 2-s2.0-44749087324
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Nastasović, Aleksandra AU - Onjia, Antonije PY - 2008 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1234 AB - Inverse gas chromatography (IGC) is an attractive technique for polymer characterization due to possible simultaneous determination of various physicochemical properties of polymer systems merely from retention times of selected sorbates. The technique is especially advantageous to polymers that cannot be characterized by conventional methods. In this review, the utilization of the method for glass transition determination of homopolymers, copolymers and polymer blends is described. Advantages and drawbacks of the IGC method over traditionally used methods for glass transition temperature determination is discussed, along with the most important parameters that influence the precision and accuracy of the glass transition temperature (T-g) measurements. PB - Elsevier, Amsterdam T2 - Journal of Chromatography A T1 - Determination of glass temperature of polymers by inverse gas chromatography EP - 15 IS - 1-2 SP - 1 VL - 1195 DO - 10.1016/j.chroma.2008.05.009 ER -
@article{ author = "Nastasović, Aleksandra and Onjia, Antonije", year = "2008", abstract = "Inverse gas chromatography (IGC) is an attractive technique for polymer characterization due to possible simultaneous determination of various physicochemical properties of polymer systems merely from retention times of selected sorbates. The technique is especially advantageous to polymers that cannot be characterized by conventional methods. In this review, the utilization of the method for glass transition determination of homopolymers, copolymers and polymer blends is described. Advantages and drawbacks of the IGC method over traditionally used methods for glass transition temperature determination is discussed, along with the most important parameters that influence the precision and accuracy of the glass transition temperature (T-g) measurements.", publisher = "Elsevier, Amsterdam", journal = "Journal of Chromatography A", title = "Determination of glass temperature of polymers by inverse gas chromatography", pages = "15-1", number = "1-2", volume = "1195", doi = "10.1016/j.chroma.2008.05.009" }
Nastasović, A.,& Onjia, A.. (2008). Determination of glass temperature of polymers by inverse gas chromatography. in Journal of Chromatography A Elsevier, Amsterdam., 1195(1-2), 1-15. https://doi.org/10.1016/j.chroma.2008.05.009
Nastasović A, Onjia A. Determination of glass temperature of polymers by inverse gas chromatography. in Journal of Chromatography A. 2008;1195(1-2):1-15. doi:10.1016/j.chroma.2008.05.009 .
Nastasović, Aleksandra, Onjia, Antonije, "Determination of glass temperature of polymers by inverse gas chromatography" in Journal of Chromatography A, 1195, no. 1-2 (2008):1-15, https://doi.org/10.1016/j.chroma.2008.05.009 . .