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Determination of glass temperature of polymers by inverse gas chromatography

Authorized Users Only
2008
Authors
Nastasović, Aleksandra
Onjia, Antonije
Article (Published version)
Metadata
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Abstract
Inverse gas chromatography (IGC) is an attractive technique for polymer characterization due to possible simultaneous determination of various physicochemical properties of polymer systems merely from retention times of selected sorbates. The technique is especially advantageous to polymers that cannot be characterized by conventional methods. In this review, the utilization of the method for glass transition determination of homopolymers, copolymers and polymer blends is described. Advantages and drawbacks of the IGC method over traditionally used methods for glass transition temperature determination is discussed, along with the most important parameters that influence the precision and accuracy of the glass transition temperature (T-g) measurements.
Keywords:
IGC / retention mechanism / thermal transitions / Z-shaped retention diagram / polymer-solvent interactions
Source:
Journal of Chromatography A, 2008, 1195, 1-2, 1-15
Publisher:
  • Elsevier, Amsterdam
Funding / projects:
  • Nove metode i tehnike za separaciju i specijaciju hemijskih elemenata u tragovima, organskih supstanci i radionuklida i identifikaciju njihovih izvora (RS-142039)

DOI: 10.1016/j.chroma.2008.05.009

ISSN: 0021-9673

PubMed: 18501369

WoS: 000257258800001

Scopus: 2-s2.0-44749087324
[ Google Scholar ]
42
39
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1234
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Nastasović, Aleksandra
AU  - Onjia, Antonije
PY  - 2008
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1234
AB  - Inverse gas chromatography (IGC) is an attractive technique for polymer characterization due to possible simultaneous determination of various physicochemical properties of polymer systems merely from retention times of selected sorbates. The technique is especially advantageous to polymers that cannot be characterized by conventional methods. In this review, the utilization of the method for glass transition determination of homopolymers, copolymers and polymer blends is described. Advantages and drawbacks of the IGC method over traditionally used methods for glass transition temperature determination is discussed, along with the most important parameters that influence the precision and accuracy of the glass transition temperature (T-g) measurements.
PB  - Elsevier, Amsterdam
T2  - Journal of Chromatography A
T1  - Determination of glass temperature of polymers by inverse gas chromatography
EP  - 15
IS  - 1-2
SP  - 1
VL  - 1195
DO  - 10.1016/j.chroma.2008.05.009
ER  - 
@article{
author = "Nastasović, Aleksandra and Onjia, Antonije",
year = "2008",
abstract = "Inverse gas chromatography (IGC) is an attractive technique for polymer characterization due to possible simultaneous determination of various physicochemical properties of polymer systems merely from retention times of selected sorbates. The technique is especially advantageous to polymers that cannot be characterized by conventional methods. In this review, the utilization of the method for glass transition determination of homopolymers, copolymers and polymer blends is described. Advantages and drawbacks of the IGC method over traditionally used methods for glass transition temperature determination is discussed, along with the most important parameters that influence the precision and accuracy of the glass transition temperature (T-g) measurements.",
publisher = "Elsevier, Amsterdam",
journal = "Journal of Chromatography A",
title = "Determination of glass temperature of polymers by inverse gas chromatography",
pages = "15-1",
number = "1-2",
volume = "1195",
doi = "10.1016/j.chroma.2008.05.009"
}
Nastasović, A.,& Onjia, A.. (2008). Determination of glass temperature of polymers by inverse gas chromatography. in Journal of Chromatography A
Elsevier, Amsterdam., 1195(1-2), 1-15.
https://doi.org/10.1016/j.chroma.2008.05.009
Nastasović A, Onjia A. Determination of glass temperature of polymers by inverse gas chromatography. in Journal of Chromatography A. 2008;1195(1-2):1-15.
doi:10.1016/j.chroma.2008.05.009 .
Nastasović, Aleksandra, Onjia, Antonije, "Determination of glass temperature of polymers by inverse gas chromatography" in Journal of Chromatography A, 1195, no. 1-2 (2008):1-15,
https://doi.org/10.1016/j.chroma.2008.05.009 . .

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