TechnoRep - Faculty of Technology and Metallurgy Repository
University of Belgrade - Faculty of Technology and Metallurgy
    • English
    • Српски
    • Српски (Serbia)
  • English 
    • English
    • Serbian (Cyrillic)
    • Serbian (Latin)
  • Login
View Item 
  •   TechnoRep
  • Tehnološko-metalurški fakultet
  • Radovi istraživača / Researchers’ publications (TMF)
  • View Item
  •   TechnoRep
  • Tehnološko-metalurški fakultet
  • Radovi istraživača / Researchers’ publications (TMF)
  • View Item
JavaScript is disabled for your browser. Some features of this site may not work without it.

The optimization of zinc dialkyldithiocarbamates synthesis and determination of their antioxidant activity

Thumbnail
2008
1451-93720804251M.pdf (366.2Kb)
Authors
Marinković, Aleksandar
Milosavljević, Milutin
Milenković, Dragan D.
Ivanović, Goran
Article (Published version)
Metadata
Show full item record
Abstract
A two-step optimized laboratory synthetic method of zinc dialkyldithiocarbamates is presented. In the course of the first phase, a sodium salt of dialkyldithiocarbamic acid has been synthesized from the dialkylamines, carbon disulfide and sodium hydroxide. The synthesis of zinc dialkyldithiocarbamates was achieved by the precipitation from sodium dialkyldithiocarbamic acid by zinc sulfate under the optimized conditions. The synthesized products have been characterized by FTIR, 1H and 13C NMR, AAS spectroscopic methods, as well as by elemental analysis and melting points. Kinetic studies of the motor oil oxidation inhibited by synthesized compounds have been tested using a standard method.
Keywords:
zinc dialkyldithicarbamates / optimization / inhibition rate constant
Source:
Chemical Industry & Chemical Engineering Quarterly, 2008, 14, 4, 251-255
Publisher:
  • Association of the Chemical Engineers of Serbia

DOI: 10.2298/CICEQ0804251M

ISSN: 1451-9372

WoS: 000262278100010

Scopus: 2-s2.0-74049109775
[ Google Scholar ]
3
3
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1323
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Marinković, Aleksandar
AU  - Milosavljević, Milutin
AU  - Milenković, Dragan D.
AU  - Ivanović, Goran
PY  - 2008
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1323
AB  - A two-step optimized laboratory synthetic method of zinc dialkyldithiocarbamates is presented. In the course of the first phase, a sodium salt of dialkyldithiocarbamic acid has been synthesized from the dialkylamines, carbon disulfide and sodium hydroxide. The synthesis of zinc dialkyldithiocarbamates was achieved by the precipitation from sodium dialkyldithiocarbamic acid by zinc sulfate under the optimized conditions. The synthesized products have been characterized by FTIR, 1H and 13C NMR, AAS spectroscopic methods, as well as by elemental analysis and melting points. Kinetic studies of the motor oil oxidation inhibited by synthesized compounds have been tested using a standard method.
PB  - Association of the Chemical Engineers of Serbia
T2  - Chemical Industry & Chemical Engineering Quarterly
T1  - The optimization of zinc dialkyldithiocarbamates synthesis and determination of their antioxidant activity
EP  - 255
IS  - 4
SP  - 251
VL  - 14
DO  - 10.2298/CICEQ0804251M
ER  - 
@article{
author = "Marinković, Aleksandar and Milosavljević, Milutin and Milenković, Dragan D. and Ivanović, Goran",
year = "2008",
abstract = "A two-step optimized laboratory synthetic method of zinc dialkyldithiocarbamates is presented. In the course of the first phase, a sodium salt of dialkyldithiocarbamic acid has been synthesized from the dialkylamines, carbon disulfide and sodium hydroxide. The synthesis of zinc dialkyldithiocarbamates was achieved by the precipitation from sodium dialkyldithiocarbamic acid by zinc sulfate under the optimized conditions. The synthesized products have been characterized by FTIR, 1H and 13C NMR, AAS spectroscopic methods, as well as by elemental analysis and melting points. Kinetic studies of the motor oil oxidation inhibited by synthesized compounds have been tested using a standard method.",
publisher = "Association of the Chemical Engineers of Serbia",
journal = "Chemical Industry & Chemical Engineering Quarterly",
title = "The optimization of zinc dialkyldithiocarbamates synthesis and determination of their antioxidant activity",
pages = "255-251",
number = "4",
volume = "14",
doi = "10.2298/CICEQ0804251M"
}
Marinković, A., Milosavljević, M., Milenković, D. D.,& Ivanović, G.. (2008). The optimization of zinc dialkyldithiocarbamates synthesis and determination of their antioxidant activity. in Chemical Industry & Chemical Engineering Quarterly
Association of the Chemical Engineers of Serbia., 14(4), 251-255.
https://doi.org/10.2298/CICEQ0804251M
Marinković A, Milosavljević M, Milenković DD, Ivanović G. The optimization of zinc dialkyldithiocarbamates synthesis and determination of their antioxidant activity. in Chemical Industry & Chemical Engineering Quarterly. 2008;14(4):251-255.
doi:10.2298/CICEQ0804251M .
Marinković, Aleksandar, Milosavljević, Milutin, Milenković, Dragan D., Ivanović, Goran, "The optimization of zinc dialkyldithiocarbamates synthesis and determination of their antioxidant activity" in Chemical Industry & Chemical Engineering Quarterly, 14, no. 4 (2008):251-255,
https://doi.org/10.2298/CICEQ0804251M . .

DSpace software copyright © 2002-2015  DuraSpace
About TechnoRep | Send Feedback

OpenAIRERCUB
 

 

All of DSpaceInstitutions/communitiesAuthorsTitlesSubjectsThis institutionAuthorsTitlesSubjects

Statistics

View Usage Statistics

DSpace software copyright © 2002-2015  DuraSpace
About TechnoRep | Send Feedback

OpenAIRERCUB