A two-step optimized laboratory synthetic method of zinc dialkyldithiocarbamates is presented. In the course of the first phase, a sodium salt of dialkyldithiocarbamic acid has been synthesized from the dialkylamines, carbon disulfide and sodium hydroxide. The synthesis of zinc dialkyldithiocarbamates was achieved by the precipitation from sodium dialkyldithiocarbamic acid by zinc sulfate under the optimized conditions. The synthesized products have been characterized by FTIR, 1H and 13C NMR, AAS spectroscopic methods, as well as by elemental analysis and melting points. Kinetic studies of the motor oil oxidation inhibited by synthesized compounds have been tested using a standard method.
TY - JOUR
AU - Marinković, Aleksandar
AU - Milosavljević, Milutin
AU - Milenković, Dragan D.
AU - Ivanović, Goran
PY - 2008
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1323
AB - A two-step optimized laboratory synthetic method of zinc dialkyldithiocarbamates is presented. In the course of the first phase, a sodium salt of dialkyldithiocarbamic acid has been synthesized from the dialkylamines, carbon disulfide and sodium hydroxide. The synthesis of zinc dialkyldithiocarbamates was achieved by the precipitation from sodium dialkyldithiocarbamic acid by zinc sulfate under the optimized conditions. The synthesized products have been characterized by FTIR, 1H and 13C NMR, AAS spectroscopic methods, as well as by elemental analysis and melting points. Kinetic studies of the motor oil oxidation inhibited by synthesized compounds have been tested using a standard method.
PB - Association of the Chemical Engineers of Serbia
T2 - Chemical Industry & Chemical Engineering Quarterly
T1 - The optimization of zinc dialkyldithiocarbamates synthesis and determination of their antioxidant activity
EP - 255
IS - 4
SP - 251
VL - 14
DO - 10.2298/CICEQ0804251M
ER -
@article{
author = "Marinković, Aleksandar and Milosavljević, Milutin and Milenković, Dragan D. and Ivanović, Goran",
year = "2008",
abstract = "A two-step optimized laboratory synthetic method of zinc dialkyldithiocarbamates is presented. In the course of the first phase, a sodium salt of dialkyldithiocarbamic acid has been synthesized from the dialkylamines, carbon disulfide and sodium hydroxide. The synthesis of zinc dialkyldithiocarbamates was achieved by the precipitation from sodium dialkyldithiocarbamic acid by zinc sulfate under the optimized conditions. The synthesized products have been characterized by FTIR, 1H and 13C NMR, AAS spectroscopic methods, as well as by elemental analysis and melting points. Kinetic studies of the motor oil oxidation inhibited by synthesized compounds have been tested using a standard method.",
publisher = "Association of the Chemical Engineers of Serbia",
journal = "Chemical Industry & Chemical Engineering Quarterly",
title = "The optimization of zinc dialkyldithiocarbamates synthesis and determination of their antioxidant activity",
pages = "255-251",
number = "4",
volume = "14",
doi = "10.2298/CICEQ0804251M"
}
Marinković, A., Milosavljević, M., Milenković, D. D.,& Ivanović, G.. (2008). The optimization of zinc dialkyldithiocarbamates synthesis and determination of their antioxidant activity. in Chemical Industry & Chemical Engineering Quarterly
Association of the Chemical Engineers of Serbia., 14(4), 251-255.
https://doi.org/10.2298/CICEQ0804251M
Marinković A, Milosavljević M, Milenković DD, Ivanović G. The optimization of zinc dialkyldithiocarbamates synthesis and determination of their antioxidant activity. in Chemical Industry & Chemical Engineering Quarterly. 2008;14(4):251-255.
doi:10.2298/CICEQ0804251M .
Marinković, Aleksandar, Milosavljević, Milutin, Milenković, Dragan D., Ivanović, Goran, "The optimization of zinc dialkyldithiocarbamates synthesis and determination of their antioxidant activity" in Chemical Industry & Chemical Engineering Quarterly, 14, no. 4 (2008):251-255,
https://doi.org/10.2298/CICEQ0804251M . .
