Molecular interaction studies of the volumetric behavior of binary liquid mixtures containing alcohols
Studija molekulskih interakcija na bazi volumetrijskih svojstava tečnih binarnih smeša koje sadrže alkohole
Autori
Đorđević, Bojan D.Radović, Ivona
Kijevčanin, Mirjana
Tasić, Aleksandar Ž.
Šerbanović, Slobodan P.
Prikaz (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
An attempt has been made to relate the volumetric effects involved in the binary mixtures of normal and branched alcohols and various components (aromatics, halo and nitroaromatics and haloaliphatics) with the molecular interactions of unlike molecules. This review is a condensation of research activities developed in recent years as results of a better understanding of volumetric behavior and a stronger insight into the complex structure of those mixtures. The influence of important contributions of a physical, chemical and geometrical nature that change excess molar volume, VE (positive, sigmoidal, negative) is considered and explained in detail. It appears that the balance between these contributions is quite sensitive to the behavior of the alcohol molecules in contact with the chosen compounds.
U ovom radu ispitana je veza između volumetrijskih efekata mešanja i molekulskih interakcija različitih molekula u binarnim smešama normalnih ili razgranatih alkohola sa različitim komponentama (aromatima, halo i nitroaromatima, halogenim derivatima ugljovodonika). Ovaj rad sadrži pregled naših istraživanja poslednjih godina, kao i rezultate istraživanja drugih autora u cilju boljeg razumevanja volumetrijskih svojstava i boljeg uvida u složenost struktura ispitivanih smeša. Uzeti su u obzir i detaljno objašnjeni fizički, hemijski i geometrijski uticaji na promenu VE vrednosti (pozitivne, sigmoidne, negativne). Utvrđeno je da na odnos ovih doprinosa veliki uticaj ima ponašanje molekula alkohola u kontaktu sa drugim komponentama.
Ključne reči:
molecular interactions / volumetric properties / excess volume / alcohols / binary liquid mixturesIzvor:
Journal of the Serbian Chemical Society, 2009, 74, 5, 477-491Izdavač:
- Serbian Chemical Society, Belgrade
Finansiranje / projekti:
- Research Fund of Ministry of Science and Environmental Protection, Serbia
- Primena hemijske termodinamike u fenomenima prenosa višefaznih višekomponentnih sistema (RS-MESTD-MPN2006-2010-142064)
Institucija/grupa
Tehnološko-metalurški fakultetTY - JOUR AU - Đorđević, Bojan D. AU - Radović, Ivona AU - Kijevčanin, Mirjana AU - Tasić, Aleksandar Ž. AU - Šerbanović, Slobodan P. PY - 2009 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1383 AB - An attempt has been made to relate the volumetric effects involved in the binary mixtures of normal and branched alcohols and various components (aromatics, halo and nitroaromatics and haloaliphatics) with the molecular interactions of unlike molecules. This review is a condensation of research activities developed in recent years as results of a better understanding of volumetric behavior and a stronger insight into the complex structure of those mixtures. The influence of important contributions of a physical, chemical and geometrical nature that change excess molar volume, VE (positive, sigmoidal, negative) is considered and explained in detail. It appears that the balance between these contributions is quite sensitive to the behavior of the alcohol molecules in contact with the chosen compounds. AB - U ovom radu ispitana je veza između volumetrijskih efekata mešanja i molekulskih interakcija različitih molekula u binarnim smešama normalnih ili razgranatih alkohola sa različitim komponentama (aromatima, halo i nitroaromatima, halogenim derivatima ugljovodonika). Ovaj rad sadrži pregled naših istraživanja poslednjih godina, kao i rezultate istraživanja drugih autora u cilju boljeg razumevanja volumetrijskih svojstava i boljeg uvida u složenost struktura ispitivanih smeša. Uzeti su u obzir i detaljno objašnjeni fizički, hemijski i geometrijski uticaji na promenu VE vrednosti (pozitivne, sigmoidne, negativne). Utvrđeno je da na odnos ovih doprinosa veliki uticaj ima ponašanje molekula alkohola u kontaktu sa drugim komponentama. PB - Serbian Chemical Society, Belgrade T2 - Journal of the Serbian Chemical Society T1 - Molecular interaction studies of the volumetric behavior of binary liquid mixtures containing alcohols T1 - Studija molekulskih interakcija na bazi volumetrijskih svojstava tečnih binarnih smeša koje sadrže alkohole EP - 491 IS - 5 SP - 477 VL - 74 UR - https://hdl.handle.net/21.15107/rcub_technorep_1383 ER -
@article{ author = "Đorđević, Bojan D. and Radović, Ivona and Kijevčanin, Mirjana and Tasić, Aleksandar Ž. and Šerbanović, Slobodan P.", year = "2009", abstract = "An attempt has been made to relate the volumetric effects involved in the binary mixtures of normal and branched alcohols and various components (aromatics, halo and nitroaromatics and haloaliphatics) with the molecular interactions of unlike molecules. This review is a condensation of research activities developed in recent years as results of a better understanding of volumetric behavior and a stronger insight into the complex structure of those mixtures. The influence of important contributions of a physical, chemical and geometrical nature that change excess molar volume, VE (positive, sigmoidal, negative) is considered and explained in detail. It appears that the balance between these contributions is quite sensitive to the behavior of the alcohol molecules in contact with the chosen compounds., U ovom radu ispitana je veza između volumetrijskih efekata mešanja i molekulskih interakcija različitih molekula u binarnim smešama normalnih ili razgranatih alkohola sa različitim komponentama (aromatima, halo i nitroaromatima, halogenim derivatima ugljovodonika). Ovaj rad sadrži pregled naših istraživanja poslednjih godina, kao i rezultate istraživanja drugih autora u cilju boljeg razumevanja volumetrijskih svojstava i boljeg uvida u složenost struktura ispitivanih smeša. Uzeti su u obzir i detaljno objašnjeni fizički, hemijski i geometrijski uticaji na promenu VE vrednosti (pozitivne, sigmoidne, negativne). Utvrđeno je da na odnos ovih doprinosa veliki uticaj ima ponašanje molekula alkohola u kontaktu sa drugim komponentama.", publisher = "Serbian Chemical Society, Belgrade", journal = "Journal of the Serbian Chemical Society", title = "Molecular interaction studies of the volumetric behavior of binary liquid mixtures containing alcohols, Studija molekulskih interakcija na bazi volumetrijskih svojstava tečnih binarnih smeša koje sadrže alkohole", pages = "491-477", number = "5", volume = "74", url = "https://hdl.handle.net/21.15107/rcub_technorep_1383" }
Đorđević, B. D., Radović, I., Kijevčanin, M., Tasić, A. Ž.,& Šerbanović, S. P.. (2009). Molecular interaction studies of the volumetric behavior of binary liquid mixtures containing alcohols. in Journal of the Serbian Chemical Society Serbian Chemical Society, Belgrade., 74(5), 477-491. https://hdl.handle.net/21.15107/rcub_technorep_1383
Đorđević BD, Radović I, Kijevčanin M, Tasić AŽ, Šerbanović SP. Molecular interaction studies of the volumetric behavior of binary liquid mixtures containing alcohols. in Journal of the Serbian Chemical Society. 2009;74(5):477-491. https://hdl.handle.net/21.15107/rcub_technorep_1383 .
Đorđević, Bojan D., Radović, Ivona, Kijevčanin, Mirjana, Tasić, Aleksandar Ž., Šerbanović, Slobodan P., "Molecular interaction studies of the volumetric behavior of binary liquid mixtures containing alcohols" in Journal of the Serbian Chemical Society, 74, no. 5 (2009):477-491, https://hdl.handle.net/21.15107/rcub_technorep_1383 .