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A new ecologically friendly process for the synthesis of selective flotation reagents

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2009
1451-93720904257M.pdf (257.0Kb)
Authors
Milosavljević, Milutin M.
Marinković, Aleksandar
Petrović, Slobodan
Sovrlić, Milica
Article (Published version)
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Abstract
A new ecologically friendly synthesis of N-alkyl-O-ethylthioncarbamates from ethyl dixanthogenates, waste material from the xanthate production plant, and monoalkylamines has been performed in this work. Structure determination of the synthesized compounds and also corresponding intermediates has been performed by IR, 1H-NMR and MS spectrometric methods. Residual dixanthogenates and thioncarbamates in waste water have been done by the gas chromatographic method and corresponding standard curve. It was confirmed that the reaction product was not present in water, while the concentration of dixanthogenates has been determined to be under the maximum contamination limit.
Keywords:
thioncarbamate / xantogenate / GC spectroscopy / ethyl dixanthogenate
Source:
Chemical Industry & Chemical Engineering Quarterly, 2009, 15, 4, 257-262
Publisher:
  • Association of the Chemical Engineers of Serbia
Funding / projects:
  • Proučavanje sinteze, strukture i aktivnosti organskih jedinjenja prirodnog i sintetskog porekla (RS-142063)

DOI: 10.2298/CICEQ0904257M

ISSN: 1451-9372

WoS: 000275477600008

Scopus: 2-s2.0-77149156672
[ Google Scholar ]
3
3
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1448
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Milosavljević, Milutin M.
AU  - Marinković, Aleksandar
AU  - Petrović, Slobodan
AU  - Sovrlić, Milica
PY  - 2009
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1448
AB  - A new ecologically friendly synthesis of N-alkyl-O-ethylthioncarbamates from ethyl dixanthogenates, waste material from the xanthate production plant, and monoalkylamines has been performed in this work. Structure determination of the synthesized compounds and also corresponding intermediates has been performed by IR, 1H-NMR and MS spectrometric methods. Residual dixanthogenates and thioncarbamates in waste water have been done by the gas chromatographic method and corresponding standard curve. It was confirmed that the reaction product was not present in water, while the concentration of dixanthogenates has been determined to be under the maximum contamination limit.
PB  - Association of the Chemical Engineers of Serbia
T2  - Chemical Industry & Chemical Engineering Quarterly
T1  - A new ecologically friendly process for the synthesis of selective flotation reagents
EP  - 262
IS  - 4
SP  - 257
VL  - 15
DO  - 10.2298/CICEQ0904257M
ER  - 
@article{
author = "Milosavljević, Milutin M. and Marinković, Aleksandar and Petrović, Slobodan and Sovrlić, Milica",
year = "2009",
abstract = "A new ecologically friendly synthesis of N-alkyl-O-ethylthioncarbamates from ethyl dixanthogenates, waste material from the xanthate production plant, and monoalkylamines has been performed in this work. Structure determination of the synthesized compounds and also corresponding intermediates has been performed by IR, 1H-NMR and MS spectrometric methods. Residual dixanthogenates and thioncarbamates in waste water have been done by the gas chromatographic method and corresponding standard curve. It was confirmed that the reaction product was not present in water, while the concentration of dixanthogenates has been determined to be under the maximum contamination limit.",
publisher = "Association of the Chemical Engineers of Serbia",
journal = "Chemical Industry & Chemical Engineering Quarterly",
title = "A new ecologically friendly process for the synthesis of selective flotation reagents",
pages = "262-257",
number = "4",
volume = "15",
doi = "10.2298/CICEQ0904257M"
}
Milosavljević, M. M., Marinković, A., Petrović, S.,& Sovrlić, M.. (2009). A new ecologically friendly process for the synthesis of selective flotation reagents. in Chemical Industry & Chemical Engineering Quarterly
Association of the Chemical Engineers of Serbia., 15(4), 257-262.
https://doi.org/10.2298/CICEQ0904257M
Milosavljević MM, Marinković A, Petrović S, Sovrlić M. A new ecologically friendly process for the synthesis of selective flotation reagents. in Chemical Industry & Chemical Engineering Quarterly. 2009;15(4):257-262.
doi:10.2298/CICEQ0904257M .
Milosavljević, Milutin M., Marinković, Aleksandar, Petrović, Slobodan, Sovrlić, Milica, "A new ecologically friendly process for the synthesis of selective flotation reagents" in Chemical Industry & Chemical Engineering Quarterly, 15, no. 4 (2009):257-262,
https://doi.org/10.2298/CICEQ0904257M . .

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