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Experimental determination and modelling of densities and excess molar volumes of ternary system (1-butanol + cyclohexylamine plus n-heptane) and corresponding binaries from 288.15 to 323.15 K

Authorized Users Only
2009
Authors
Kijevčanin, Mirjana
Radović, Ivona
Šerbanović, Slobodan P.
Tasić, Aleksandar Ž.
Đorđević, Bojan D.
Article (Published version)
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Abstract
Experimental densities rho and excess molar volumes V-E of one ternary and three binary systems containing 1-butanol, cyclohexylamine and n-heptane at temperatures from 283.15 to 323.15 K are reported. Density measurements were performed by ail Anton Paar DMA 5000 vibrating tube densimeter. The obtained V-E of binary systems were fitted to the Redlich-Kister equation, and to the Nagata-Tamura equation for the ternary system. For the correlation of V-E data of binary systems van der Waals (vdW1) and Twu-Coon-Bluck-Tilton (TCBT) mixing rules coupled with the Peng-Robinson-Stryjek-Vera (PRSV) equation of state were applied. The same models were applied for the prediction and correlation of V-E data of the ternary system. In addition, several empirical relationships were applied for the prediction of V-E data of the ternary system from the corresponding binary data. The obtained results have been analysed in terms of specific molecular interactions present in the investigated mixtures taki...ng into considerations the effect of temperature increasing on present interactions.

Keywords:
Excess molar volume / Ternary system / 1-Butanol / Cyclohexylamine / Modelling
Source:
Thermochimica Acta, 2009, 496, 1-2, 71-86
Publisher:
  • Elsevier Science Bv, Amsterdam
Funding / projects:
  • Ministry of Science and Environmental Protection, Serbia
  • Primena hemijske termodinamike u fenomenima prenosa višefaznih višekomponentnih sistema (RS-142064)

DOI: 10.1016/j.tca.2009.07.002

ISSN: 0040-6031

WoS: 000272853700012

Scopus: 2-s2.0-70649112277
[ Google Scholar ]
30
30
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1462
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Kijevčanin, Mirjana
AU  - Radović, Ivona
AU  - Šerbanović, Slobodan P.
AU  - Tasić, Aleksandar Ž.
AU  - Đorđević, Bojan D.
PY  - 2009
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1462
AB  - Experimental densities rho and excess molar volumes V-E of one ternary and three binary systems containing 1-butanol, cyclohexylamine and n-heptane at temperatures from 283.15 to 323.15 K are reported. Density measurements were performed by ail Anton Paar DMA 5000 vibrating tube densimeter. The obtained V-E of binary systems were fitted to the Redlich-Kister equation, and to the Nagata-Tamura equation for the ternary system. For the correlation of V-E data of binary systems van der Waals (vdW1) and Twu-Coon-Bluck-Tilton (TCBT) mixing rules coupled with the Peng-Robinson-Stryjek-Vera (PRSV) equation of state were applied. The same models were applied for the prediction and correlation of V-E data of the ternary system. In addition, several empirical relationships were applied for the prediction of V-E data of the ternary system from the corresponding binary data. The obtained results have been analysed in terms of specific molecular interactions present in the investigated mixtures taking into considerations the effect of temperature increasing on present interactions.
PB  - Elsevier Science Bv, Amsterdam
T2  - Thermochimica Acta
T1  - Experimental determination and modelling of densities and excess molar volumes of ternary system (1-butanol + cyclohexylamine plus n-heptane) and corresponding binaries from 288.15 to 323.15 K
EP  - 86
IS  - 1-2
SP  - 71
VL  - 496
DO  - 10.1016/j.tca.2009.07.002
ER  - 
@article{
author = "Kijevčanin, Mirjana and Radović, Ivona and Šerbanović, Slobodan P. and Tasić, Aleksandar Ž. and Đorđević, Bojan D.",
year = "2009",
abstract = "Experimental densities rho and excess molar volumes V-E of one ternary and three binary systems containing 1-butanol, cyclohexylamine and n-heptane at temperatures from 283.15 to 323.15 K are reported. Density measurements were performed by ail Anton Paar DMA 5000 vibrating tube densimeter. The obtained V-E of binary systems were fitted to the Redlich-Kister equation, and to the Nagata-Tamura equation for the ternary system. For the correlation of V-E data of binary systems van der Waals (vdW1) and Twu-Coon-Bluck-Tilton (TCBT) mixing rules coupled with the Peng-Robinson-Stryjek-Vera (PRSV) equation of state were applied. The same models were applied for the prediction and correlation of V-E data of the ternary system. In addition, several empirical relationships were applied for the prediction of V-E data of the ternary system from the corresponding binary data. The obtained results have been analysed in terms of specific molecular interactions present in the investigated mixtures taking into considerations the effect of temperature increasing on present interactions.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Thermochimica Acta",
title = "Experimental determination and modelling of densities and excess molar volumes of ternary system (1-butanol + cyclohexylamine plus n-heptane) and corresponding binaries from 288.15 to 323.15 K",
pages = "86-71",
number = "1-2",
volume = "496",
doi = "10.1016/j.tca.2009.07.002"
}
Kijevčanin, M., Radović, I., Šerbanović, S. P., Tasić, A. Ž.,& Đorđević, B. D.. (2009). Experimental determination and modelling of densities and excess molar volumes of ternary system (1-butanol + cyclohexylamine plus n-heptane) and corresponding binaries from 288.15 to 323.15 K. in Thermochimica Acta
Elsevier Science Bv, Amsterdam., 496(1-2), 71-86.
https://doi.org/10.1016/j.tca.2009.07.002
Kijevčanin M, Radović I, Šerbanović SP, Tasić AŽ, Đorđević BD. Experimental determination and modelling of densities and excess molar volumes of ternary system (1-butanol + cyclohexylamine plus n-heptane) and corresponding binaries from 288.15 to 323.15 K. in Thermochimica Acta. 2009;496(1-2):71-86.
doi:10.1016/j.tca.2009.07.002 .
Kijevčanin, Mirjana, Radović, Ivona, Šerbanović, Slobodan P., Tasić, Aleksandar Ž., Đorđević, Bojan D., "Experimental determination and modelling of densities and excess molar volumes of ternary system (1-butanol + cyclohexylamine plus n-heptane) and corresponding binaries from 288.15 to 323.15 K" in Thermochimica Acta, 496, no. 1-2 (2009):71-86,
https://doi.org/10.1016/j.tca.2009.07.002 . .

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