Приказ основних података о документу

dc.creatorRajić, Nevenka
dc.creatorStojaković, Đorđe
dc.creatorRecnik, Aleksander
dc.date.accessioned2021-03-10T11:07:57Z
dc.date.available2021-03-10T11:07:57Z
dc.date.issued2009
dc.identifier.issn0020-1693
dc.identifier.urihttp://TechnoRep.tmf.bg.ac.rs/handle/123456789/1470
dc.description.abstractThermogravimetrical analysis has been used to study the kinetics of thermal deamination of bis(ethylenediamine) nickel(II)-containing aluminophosphate (Ni-CHA) which is a precursor of nickel(II)-containing chabazite-like AlPO4-34. The deamination occurs as a single-step kinetic process which is best described by the contracting cylinder model. The obtained activation energy of 200 kJ/mol is mainly a reflection of the strong Ni-N coordination bond. The thermal decomposition of Ni-CHA results in the deposition of crystalline NiO particles homogeneously dispersed in the AlPO4-34 lattice. Average particle size was found to be about 5 nm. The study confirms that the thermal decomposition of amine complexes of Ni(II) encapsulated inside the microporous aluminophosphate host can be a suitable method for obtaining fine nano-oxide particles.en
dc.publisherElsevier Science Sa, Lausanne
dc.relationinfo:eu-repo/grantAgreement/MESTD/MPN2006-2010/142055/RS//
dc.rightsrestrictedAccess
dc.sourceInorganica Chimica Acta
dc.subjectAlPO4-34en
dc.subjectChabazite-likeen
dc.subjectNano-oxideen
dc.subjectDecomposition kineticsen
dc.subjectTEMen
dc.titleThermal deamination kinetics of the nickel-containing chabazite-like aluminophosphate, Ni(NH2-CH2-CH2-NH2)(2)(AlPO4)(6)(OH)(2), deposition of nanocrystalline NiO particlesen
dc.typearticle
dc.rights.licenseARR
dc.citation.epage5143
dc.citation.issue15
dc.citation.other362(15): 5139-5143
dc.citation.rankM22
dc.citation.spage5139
dc.citation.volume362
dc.identifier.doi10.1016/j.ica.2009.09.007
dc.identifier.scopus2-s2.0-71949094372
dc.identifier.wos000271779000003
dc.type.versionpublishedVersion


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Приказ основних података о документу