Boron and phosphorus doped glassy carbon: I. Surface properties
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1997
Authors
Đurkić, Tatjana
Perić, Aleksandra

Laušević, Mila
Dekanski, Aleksandar

Nešković, Olivera M.
Veljković, Miomir V.
Laušević, Zoran

Article (Published version)

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The effects of boron and phosphorus incorporation in phenolic resin precursor on the surface properties of glassy carbon (GC) have been studied. Characterization of the surface properties using X-ray photoelectron spectroscopy and mass spectrometry analysis of desorption products showed that boron and phosphorus doped GC contained more carbon-oxygen complexes on the surface than undoped GC. The thermal decomposition of the surface oxide species, resulting in desorption of CO and CO2 as major gas products, showed that the presence of heteroatoms affects the nature of the surface oxide species and contributes to their increased stability. The presence of stable surface oxide species promotes the increased oxidation resistance of doped GC samples.
Keywords:
glass-like carbon / bulk doping / photoelectron spectroscopy / surface propertiesSource:
Carbon, 1997, 35, 10-11, 1567-1572Publisher:
- Pergamon-Elsevier Science Ltd, Oxford
DOI: 10.1016/S0008-6223(97)00113-9
ISSN: 0008-6223
WoS: 000071081300014
Scopus: 2-s2.0-0031383031
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Đurkić, Tatjana AU - Perić, Aleksandra AU - Laušević, Mila AU - Dekanski, Aleksandar AU - Nešković, Olivera M. AU - Veljković, Miomir V. AU - Laušević, Zoran PY - 1997 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/153 AB - The effects of boron and phosphorus incorporation in phenolic resin precursor on the surface properties of glassy carbon (GC) have been studied. Characterization of the surface properties using X-ray photoelectron spectroscopy and mass spectrometry analysis of desorption products showed that boron and phosphorus doped GC contained more carbon-oxygen complexes on the surface than undoped GC. The thermal decomposition of the surface oxide species, resulting in desorption of CO and CO2 as major gas products, showed that the presence of heteroatoms affects the nature of the surface oxide species and contributes to their increased stability. The presence of stable surface oxide species promotes the increased oxidation resistance of doped GC samples. PB - Pergamon-Elsevier Science Ltd, Oxford T2 - Carbon T1 - Boron and phosphorus doped glassy carbon: I. Surface properties EP - 1572 IS - 10-11 SP - 1567 VL - 35 DO - 10.1016/S0008-6223(97)00113-9 ER -
@article{ author = "Đurkić, Tatjana and Perić, Aleksandra and Laušević, Mila and Dekanski, Aleksandar and Nešković, Olivera M. and Veljković, Miomir V. and Laušević, Zoran", year = "1997", abstract = "The effects of boron and phosphorus incorporation in phenolic resin precursor on the surface properties of glassy carbon (GC) have been studied. Characterization of the surface properties using X-ray photoelectron spectroscopy and mass spectrometry analysis of desorption products showed that boron and phosphorus doped GC contained more carbon-oxygen complexes on the surface than undoped GC. The thermal decomposition of the surface oxide species, resulting in desorption of CO and CO2 as major gas products, showed that the presence of heteroatoms affects the nature of the surface oxide species and contributes to their increased stability. The presence of stable surface oxide species promotes the increased oxidation resistance of doped GC samples.", publisher = "Pergamon-Elsevier Science Ltd, Oxford", journal = "Carbon", title = "Boron and phosphorus doped glassy carbon: I. Surface properties", pages = "1572-1567", number = "10-11", volume = "35", doi = "10.1016/S0008-6223(97)00113-9" }
Đurkić, T., Perić, A., Laušević, M., Dekanski, A., Nešković, O. M., Veljković, M. V.,& Laušević, Z.. (1997). Boron and phosphorus doped glassy carbon: I. Surface properties. in Carbon Pergamon-Elsevier Science Ltd, Oxford., 35(10-11), 1567-1572. https://doi.org/10.1016/S0008-6223(97)00113-9
Đurkić T, Perić A, Laušević M, Dekanski A, Nešković OM, Veljković MV, Laušević Z. Boron and phosphorus doped glassy carbon: I. Surface properties. in Carbon. 1997;35(10-11):1567-1572. doi:10.1016/S0008-6223(97)00113-9 .
Đurkić, Tatjana, Perić, Aleksandra, Laušević, Mila, Dekanski, Aleksandar, Nešković, Olivera M., Veljković, Miomir V., Laušević, Zoran, "Boron and phosphorus doped glassy carbon: I. Surface properties" in Carbon, 35, no. 10-11 (1997):1567-1572, https://doi.org/10.1016/S0008-6223(97)00113-9 . .