Electrochemical characterization of electrochemically polymerized polyaniline in citrate containing electrolyte

2010
Authors
Jugović, Branimir
Gvozdenović, Milica

Stevanović, Jasmina

Trišović, Tomislav

Grgur, Branimir

Conference object (Published version)
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Polyaniline electrode, was obtained by electrochemical polymerization at constant current density of 2.0 mA cm-2 from aqueous solution of 1.0 mol dm-3 HCl containing 0.25 mol dm-3 aniline. Electrochemical characterization of the polyaniline electrode in chloride and chloride/citrate electrolyte, for different anodic potential limits, was performed using cyclic voltammetry and galvanostatic measurements. It was observed that for anodic potential 0.32 V, higher electrode capacity in chloride/citrate was obtained. For anodic potential limit of 0.50 V, faster decrease of the electrode capacity in chloride/citrate electrolyte was also observed. It was suggested that influence of both chloride and citrate anions has to be taken into account.
Keywords:
electrochemistry / polymers / power sourcesSource:
The 61st Annual Meeting of the International Society of Electrochemistry: Electrochemistry from Biol, 2010, s05-P-054-Publisher:
- Nice : International Society of Electrochemistry
Funding / projects:
- Modifikacija metalnih i nemetalnih materijala elektroprovodnim polimerima za primenu u novim tehnologijama (RS-142044)
Institution/Community
Tehnološko-metalurški fakultetTY - CONF AU - Jugović, Branimir AU - Gvozdenović, Milica AU - Stevanović, Jasmina AU - Trišović, Tomislav AU - Grgur, Branimir PY - 2010 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1570 AB - Polyaniline electrode, was obtained by electrochemical polymerization at constant current density of 2.0 mA cm-2 from aqueous solution of 1.0 mol dm-3 HCl containing 0.25 mol dm-3 aniline. Electrochemical characterization of the polyaniline electrode in chloride and chloride/citrate electrolyte, for different anodic potential limits, was performed using cyclic voltammetry and galvanostatic measurements. It was observed that for anodic potential 0.32 V, higher electrode capacity in chloride/citrate was obtained. For anodic potential limit of 0.50 V, faster decrease of the electrode capacity in chloride/citrate electrolyte was also observed. It was suggested that influence of both chloride and citrate anions has to be taken into account. PB - Nice : International Society of Electrochemistry C3 - The 61st Annual Meeting of the International Society of Electrochemistry: Electrochemistry from Biol T1 - Electrochemical characterization of electrochemically polymerized polyaniline in citrate containing electrolyte SP - s05-P-054 UR - https://hdl.handle.net/21.15107/rcub_technorep_1570 ER -
@conference{ author = "Jugović, Branimir and Gvozdenović, Milica and Stevanović, Jasmina and Trišović, Tomislav and Grgur, Branimir", year = "2010", abstract = "Polyaniline electrode, was obtained by electrochemical polymerization at constant current density of 2.0 mA cm-2 from aqueous solution of 1.0 mol dm-3 HCl containing 0.25 mol dm-3 aniline. Electrochemical characterization of the polyaniline electrode in chloride and chloride/citrate electrolyte, for different anodic potential limits, was performed using cyclic voltammetry and galvanostatic measurements. It was observed that for anodic potential 0.32 V, higher electrode capacity in chloride/citrate was obtained. For anodic potential limit of 0.50 V, faster decrease of the electrode capacity in chloride/citrate electrolyte was also observed. It was suggested that influence of both chloride and citrate anions has to be taken into account.", publisher = "Nice : International Society of Electrochemistry", journal = "The 61st Annual Meeting of the International Society of Electrochemistry: Electrochemistry from Biol", title = "Electrochemical characterization of electrochemically polymerized polyaniline in citrate containing electrolyte", pages = "s05-P-054", url = "https://hdl.handle.net/21.15107/rcub_technorep_1570" }
Jugović, B., Gvozdenović, M., Stevanović, J., Trišović, T.,& Grgur, B.. (2010). Electrochemical characterization of electrochemically polymerized polyaniline in citrate containing electrolyte. in The 61st Annual Meeting of the International Society of Electrochemistry: Electrochemistry from Biol Nice : International Society of Electrochemistry., s05-P-054. https://hdl.handle.net/21.15107/rcub_technorep_1570
Jugović B, Gvozdenović M, Stevanović J, Trišović T, Grgur B. Electrochemical characterization of electrochemically polymerized polyaniline in citrate containing electrolyte. in The 61st Annual Meeting of the International Society of Electrochemistry: Electrochemistry from Biol. 2010;:s05-P-054. https://hdl.handle.net/21.15107/rcub_technorep_1570 .
Jugović, Branimir, Gvozdenović, Milica, Stevanović, Jasmina, Trišović, Tomislav, Grgur, Branimir, "Electrochemical characterization of electrochemically polymerized polyaniline in citrate containing electrolyte" in The 61st Annual Meeting of the International Society of Electrochemistry: Electrochemistry from Biol (2010):s05-P-054, https://hdl.handle.net/21.15107/rcub_technorep_1570 .