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Cubic equation of state models for liquid excess heat capacity calculations. II. Applicability of the PRSV-SR and PRSV-HVOS models to complex binary mixtures
Binary liquid excess heat capacities C-p(E) for various kinds of complex binary systems measured by Conti and coworkers are well represented by the PRSV EOS modified van der Waals one fluid mixing rule proposed by Schwartzentruber and Renon (SR) and the Orbey-Sandler modification of the Huron-Vidal mixing rules (HVOS). The HVOS mixing rule is used with the NRTL excess free energy model. The binary parameters of both models (PRSV-SR and PRSV-HVOS) were assumed to be linear functions of temperature. Only for the system ethanol-cyclohexane the correlation obtained by the PRSV-SR model is not satisfactory.
Keywords:
excess heat capacity / cubic equation of state / mixing rule / polar compound / binary mixture
Source:
Journal of the Serbian Chemical Society, 1998, 63, 4, 251-256
TY - JOUR
AU - Kijevčanin, Mirjana
AU - Đorđević, Bojan D.
AU - Adamović, MM
AU - Šerbanović, Slobodan P.
PY - 1998
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/167
AB - Binary liquid excess heat capacities C-p(E) for various kinds of complex binary systems measured by Conti and coworkers are well represented by the PRSV EOS modified van der Waals one fluid mixing rule proposed by Schwartzentruber and Renon (SR) and the Orbey-Sandler modification of the Huron-Vidal mixing rules (HVOS). The HVOS mixing rule is used with the NRTL excess free energy model. The binary parameters of both models (PRSV-SR and PRSV-HVOS) were assumed to be linear functions of temperature. Only for the system ethanol-cyclohexane the correlation obtained by the PRSV-SR model is not satisfactory.
PB - Serbian Chemical Society, Belgrade
T2 - Journal of the Serbian Chemical Society
T1 - Cubic equation of state models for liquid excess heat capacity calculations. II. Applicability of the PRSV-SR and PRSV-HVOS models to complex binary mixtures
EP - 256
IS - 4
SP - 251
VL - 63
UR - https://hdl.handle.net/21.15107/rcub_technorep_167
ER -
@article{
author = "Kijevčanin, Mirjana and Đorđević, Bojan D. and Adamović, MM and Šerbanović, Slobodan P.",
year = "1998",
abstract = "Binary liquid excess heat capacities C-p(E) for various kinds of complex binary systems measured by Conti and coworkers are well represented by the PRSV EOS modified van der Waals one fluid mixing rule proposed by Schwartzentruber and Renon (SR) and the Orbey-Sandler modification of the Huron-Vidal mixing rules (HVOS). The HVOS mixing rule is used with the NRTL excess free energy model. The binary parameters of both models (PRSV-SR and PRSV-HVOS) were assumed to be linear functions of temperature. Only for the system ethanol-cyclohexane the correlation obtained by the PRSV-SR model is not satisfactory.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Cubic equation of state models for liquid excess heat capacity calculations. II. Applicability of the PRSV-SR and PRSV-HVOS models to complex binary mixtures",
pages = "256-251",
number = "4",
volume = "63",
url = "https://hdl.handle.net/21.15107/rcub_technorep_167"
}
Kijevčanin, M., Đorđević, B. D., Adamović, M.,& Šerbanović, S. P.. (1998). Cubic equation of state models for liquid excess heat capacity calculations. II. Applicability of the PRSV-SR and PRSV-HVOS models to complex binary mixtures. in Journal of the Serbian Chemical Society
Serbian Chemical Society, Belgrade., 63(4), 251-256.
https://hdl.handle.net/21.15107/rcub_technorep_167
Kijevčanin M, Đorđević BD, Adamović M, Šerbanović SP. Cubic equation of state models for liquid excess heat capacity calculations. II. Applicability of the PRSV-SR and PRSV-HVOS models to complex binary mixtures. in Journal of the Serbian Chemical Society. 1998;63(4):251-256.
https://hdl.handle.net/21.15107/rcub_technorep_167 .
Kijevčanin, Mirjana, Đorđević, Bojan D., Adamović, MM, Šerbanović, Slobodan P., "Cubic equation of state models for liquid excess heat capacity calculations. II. Applicability of the PRSV-SR and PRSV-HVOS models to complex binary mixtures" in Journal of the Serbian Chemical Society, 63, no. 4 (1998):251-256,
https://hdl.handle.net/21.15107/rcub_technorep_167 .
