Structure investigation of fluorinated aluminophosphate ULM-3 Al templated by 3-methylaminopropylamine
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2010
Authors
Zabukovec-Logar, NatašaMali, Gregor
Rajić, Nevenka
Jevtić, Sanja
Rangus, Mojca
Golobić, Amalija
Kaučič, Venčeslav
Article (Published version)
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A single-crystal X-ray diffraction analysis of an open-framework aluminophosphate ULM-3 Al prepared by 3-methylaminopropylamine (MAPA) as structure-directing agent revealed an orthorhombic Pcab symmetry (a=9.9949(4)angstrom, b=15.8229(7)angstrom, c=18.1963(5)angstrom, R=0.0648, Z=8, unit cell formula (Al24P24O96F16 center dot C32H112N16]). which differs from the Pbc2(1) symmetry of the structural analogue prepared in the presence of 1,4-diaminobutane. The Al-27, P-31, F-19, C-13 and H-1 NMR investigations, which were performed to study in detail MAPA arrangement inside the framework as well as the interactions of MAPA with the aluminophosphate host, confirmed the crystal symmetry and the proposed hydrogen bonding scheme between the template and the framework.
Keywords:
Aluminophosphate / Microporous material / ULM-3 / 3-Methylaminopropylamine / Single-crystal structure analysis / Fluoride mediumSource:
Journal of Solid State Chemistry, 2010, 183, 5, 1055-1062Publisher:
- Academic Press Inc Elsevier Science, San Diego
Funding / projects:
- Slovenian Ministry of Education. Science and Sport [P1-0021-0104]
- 42055
DOI: 10.1016/j.jssc.2010.02.020
ISSN: 0022-4596
WoS: 000277675500010
Scopus: 2-s2.0-77953229697
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Zabukovec-Logar, Nataša AU - Mali, Gregor AU - Rajić, Nevenka AU - Jevtić, Sanja AU - Rangus, Mojca AU - Golobić, Amalija AU - Kaučič, Venčeslav PY - 2010 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1699 AB - A single-crystal X-ray diffraction analysis of an open-framework aluminophosphate ULM-3 Al prepared by 3-methylaminopropylamine (MAPA) as structure-directing agent revealed an orthorhombic Pcab symmetry (a=9.9949(4)angstrom, b=15.8229(7)angstrom, c=18.1963(5)angstrom, R=0.0648, Z=8, unit cell formula (Al24P24O96F16 center dot C32H112N16]). which differs from the Pbc2(1) symmetry of the structural analogue prepared in the presence of 1,4-diaminobutane. The Al-27, P-31, F-19, C-13 and H-1 NMR investigations, which were performed to study in detail MAPA arrangement inside the framework as well as the interactions of MAPA with the aluminophosphate host, confirmed the crystal symmetry and the proposed hydrogen bonding scheme between the template and the framework. PB - Academic Press Inc Elsevier Science, San Diego T2 - Journal of Solid State Chemistry T1 - Structure investigation of fluorinated aluminophosphate ULM-3 Al templated by 3-methylaminopropylamine EP - 1062 IS - 5 SP - 1055 VL - 183 DO - 10.1016/j.jssc.2010.02.020 ER -
@article{ author = "Zabukovec-Logar, Nataša and Mali, Gregor and Rajić, Nevenka and Jevtić, Sanja and Rangus, Mojca and Golobić, Amalija and Kaučič, Venčeslav", year = "2010", abstract = "A single-crystal X-ray diffraction analysis of an open-framework aluminophosphate ULM-3 Al prepared by 3-methylaminopropylamine (MAPA) as structure-directing agent revealed an orthorhombic Pcab symmetry (a=9.9949(4)angstrom, b=15.8229(7)angstrom, c=18.1963(5)angstrom, R=0.0648, Z=8, unit cell formula (Al24P24O96F16 center dot C32H112N16]). which differs from the Pbc2(1) symmetry of the structural analogue prepared in the presence of 1,4-diaminobutane. The Al-27, P-31, F-19, C-13 and H-1 NMR investigations, which were performed to study in detail MAPA arrangement inside the framework as well as the interactions of MAPA with the aluminophosphate host, confirmed the crystal symmetry and the proposed hydrogen bonding scheme between the template and the framework.", publisher = "Academic Press Inc Elsevier Science, San Diego", journal = "Journal of Solid State Chemistry", title = "Structure investigation of fluorinated aluminophosphate ULM-3 Al templated by 3-methylaminopropylamine", pages = "1062-1055", number = "5", volume = "183", doi = "10.1016/j.jssc.2010.02.020" }
Zabukovec-Logar, N., Mali, G., Rajić, N., Jevtić, S., Rangus, M., Golobić, A.,& Kaučič, V.. (2010). Structure investigation of fluorinated aluminophosphate ULM-3 Al templated by 3-methylaminopropylamine. in Journal of Solid State Chemistry Academic Press Inc Elsevier Science, San Diego., 183(5), 1055-1062. https://doi.org/10.1016/j.jssc.2010.02.020
Zabukovec-Logar N, Mali G, Rajić N, Jevtić S, Rangus M, Golobić A, Kaučič V. Structure investigation of fluorinated aluminophosphate ULM-3 Al templated by 3-methylaminopropylamine. in Journal of Solid State Chemistry. 2010;183(5):1055-1062. doi:10.1016/j.jssc.2010.02.020 .
Zabukovec-Logar, Nataša, Mali, Gregor, Rajić, Nevenka, Jevtić, Sanja, Rangus, Mojca, Golobić, Amalija, Kaučič, Venčeslav, "Structure investigation of fluorinated aluminophosphate ULM-3 Al templated by 3-methylaminopropylamine" in Journal of Solid State Chemistry, 183, no. 5 (2010):1055-1062, https://doi.org/10.1016/j.jssc.2010.02.020 . .