Microgel-based surface modifying system for stimuli-responsive functional finishing of cotton
Само за регистроване кориснике
2010
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
An innovative strategy for functional finishing of textile materials is based on the incorporation of a thin layer of surface modifying systems (SMS) in the form of stimuli-sensitive microgels or hydrogels. Since the copolymerization of poly(N-isopropylacrylamide) with an ionizable polymer, such as chitosan, results in a microgel that is responsive to both temperature and pH, the microparticulate hydrogel of poly-NiPAAm-chitosan copolymer (PNCS) was synthesized using surfactant-free emulsion method. The microparticle size in dry (collapsed) state is estimated at 200 nm by SEM and TEM, and effect of temperature and pH on microparticles was investigated by DLS and UV-vis spectrophotometry. The incorporation of PNCS microparticles to cotton material was done by a simple pad-dry-cure procedure from aqueous microparticle dispersion that contained 1,2,3,4-butanetetracarboxylic acid (BTCA) as a crosslinking agent. This application method provided sufficient integrity to coating by maintaining... the responsiveness of surface modifying system. The stimuli-responsiveness of modified cotton fabric has been confirmed in terms of regulating its water uptake in dependence of pH and temperature.
Кључне речи:
Cotton / Chitosan / Poly-NiPAAm / BTCA / Microparticle / HydrogelИзвор:
Carbohydrate Polymers, 2010, 82, 4, 1306-1314Издавач:
- Elsevier Sci Ltd, Oxford
Финансирање / пројекти:
- Ells Sixth Framework Programme [MEXT-CT-2006-042641]
DOI: 10.1016/j.carbpol.2010.07.011
ISSN: 0144-8617
WoS: 000283042100039
Scopus: 2-s2.0-77956489213
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Kulkarni, Amit AU - Tourrette, Audrey AU - Warmoeskerken, M. M. C. G. AU - Jocić, Dragan PY - 2010 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1727 AB - An innovative strategy for functional finishing of textile materials is based on the incorporation of a thin layer of surface modifying systems (SMS) in the form of stimuli-sensitive microgels or hydrogels. Since the copolymerization of poly(N-isopropylacrylamide) with an ionizable polymer, such as chitosan, results in a microgel that is responsive to both temperature and pH, the microparticulate hydrogel of poly-NiPAAm-chitosan copolymer (PNCS) was synthesized using surfactant-free emulsion method. The microparticle size in dry (collapsed) state is estimated at 200 nm by SEM and TEM, and effect of temperature and pH on microparticles was investigated by DLS and UV-vis spectrophotometry. The incorporation of PNCS microparticles to cotton material was done by a simple pad-dry-cure procedure from aqueous microparticle dispersion that contained 1,2,3,4-butanetetracarboxylic acid (BTCA) as a crosslinking agent. This application method provided sufficient integrity to coating by maintaining the responsiveness of surface modifying system. The stimuli-responsiveness of modified cotton fabric has been confirmed in terms of regulating its water uptake in dependence of pH and temperature. PB - Elsevier Sci Ltd, Oxford T2 - Carbohydrate Polymers T1 - Microgel-based surface modifying system for stimuli-responsive functional finishing of cotton EP - 1314 IS - 4 SP - 1306 VL - 82 DO - 10.1016/j.carbpol.2010.07.011 ER -
@article{ author = "Kulkarni, Amit and Tourrette, Audrey and Warmoeskerken, M. M. C. G. and Jocić, Dragan", year = "2010", abstract = "An innovative strategy for functional finishing of textile materials is based on the incorporation of a thin layer of surface modifying systems (SMS) in the form of stimuli-sensitive microgels or hydrogels. Since the copolymerization of poly(N-isopropylacrylamide) with an ionizable polymer, such as chitosan, results in a microgel that is responsive to both temperature and pH, the microparticulate hydrogel of poly-NiPAAm-chitosan copolymer (PNCS) was synthesized using surfactant-free emulsion method. The microparticle size in dry (collapsed) state is estimated at 200 nm by SEM and TEM, and effect of temperature and pH on microparticles was investigated by DLS and UV-vis spectrophotometry. The incorporation of PNCS microparticles to cotton material was done by a simple pad-dry-cure procedure from aqueous microparticle dispersion that contained 1,2,3,4-butanetetracarboxylic acid (BTCA) as a crosslinking agent. This application method provided sufficient integrity to coating by maintaining the responsiveness of surface modifying system. The stimuli-responsiveness of modified cotton fabric has been confirmed in terms of regulating its water uptake in dependence of pH and temperature.", publisher = "Elsevier Sci Ltd, Oxford", journal = "Carbohydrate Polymers", title = "Microgel-based surface modifying system for stimuli-responsive functional finishing of cotton", pages = "1314-1306", number = "4", volume = "82", doi = "10.1016/j.carbpol.2010.07.011" }
Kulkarni, A., Tourrette, A., Warmoeskerken, M. M. C. G.,& Jocić, D.. (2010). Microgel-based surface modifying system for stimuli-responsive functional finishing of cotton. in Carbohydrate Polymers Elsevier Sci Ltd, Oxford., 82(4), 1306-1314. https://doi.org/10.1016/j.carbpol.2010.07.011
Kulkarni A, Tourrette A, Warmoeskerken MMCG, Jocić D. Microgel-based surface modifying system for stimuli-responsive functional finishing of cotton. in Carbohydrate Polymers. 2010;82(4):1306-1314. doi:10.1016/j.carbpol.2010.07.011 .
Kulkarni, Amit, Tourrette, Audrey, Warmoeskerken, M. M. C. G., Jocić, Dragan, "Microgel-based surface modifying system for stimuli-responsive functional finishing of cotton" in Carbohydrate Polymers, 82, no. 4 (2010):1306-1314, https://doi.org/10.1016/j.carbpol.2010.07.011 . .