1-Butanol + hexylamine plus n-heptane at temperature range (288.15-323.15 K): Experimental density data, excess molar volumes determination and modeling with cubic EOS
Само за регистроване кориснике
2010
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Densities rho of the ternary system 1-butanol + hexylamine + n-heptane and binaries: 1-butanol + hexylamine and hexylamine + n-heptane within the temperature range (288.15-323.15K) and atmospheric pressure are reported. Excess molar volumes V-E were calculated from the density data and fitted by the Redlich-Kister and Nagata and Tamura equations. The results are analyzed in terms of the molecular interactions between the components of mixtures. Several empirical relationships (Radojkovic, Kohler, Jacob-Fitzner, Colinet,Tsao-Smith,Toop, Scatchard and Rastogi) were applied for prediction of V-E data of the ternary system from the corresponding binary data. For the correlation of binary V-E, the Peng-Robinson-Stryjek-Vera cubic equation of state (PRSV CEOS) coupled with the van der Waals (vcIW1) and CEOS/G(E) mixing rule introduced by Twu et al. (TCBT) were chosen. Prediction of V-E of ternary system was performed by the same vdW1 and TCBT models. For the correlation of the V-E of ternary... data only TCBT mixing rules were used.
Кључне речи:
Experimental determination / Densities / Excess molar volumes / Ternary system / Cubic EOSИзвор:
Fluid Phase Equilibria, 2010, 298, 1, 117-130Издавач:
- Elsevier Science Bv, Amsterdam
Финансирање / пројекти:
- Ministry of Science and Environmental Protection, Serbia
- Примена хемијске термодинамике у феноменима преноса вишефазних вишекомпонентних система (RS-MESTD-MPN2006-2010-142064)
DOI: 10.1016/j.fluid.2010.07.011
ISSN: 0378-3812
WoS: 000283023700016
Scopus: 2-s2.0-84755160731
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Radović, Ivona AU - Kijevčanin, Mirjana AU - Šerbanović, Slobodan P. AU - Đorđević, Bojan D. PY - 2010 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1728 AB - Densities rho of the ternary system 1-butanol + hexylamine + n-heptane and binaries: 1-butanol + hexylamine and hexylamine + n-heptane within the temperature range (288.15-323.15K) and atmospheric pressure are reported. Excess molar volumes V-E were calculated from the density data and fitted by the Redlich-Kister and Nagata and Tamura equations. The results are analyzed in terms of the molecular interactions between the components of mixtures. Several empirical relationships (Radojkovic, Kohler, Jacob-Fitzner, Colinet,Tsao-Smith,Toop, Scatchard and Rastogi) were applied for prediction of V-E data of the ternary system from the corresponding binary data. For the correlation of binary V-E, the Peng-Robinson-Stryjek-Vera cubic equation of state (PRSV CEOS) coupled with the van der Waals (vcIW1) and CEOS/G(E) mixing rule introduced by Twu et al. (TCBT) were chosen. Prediction of V-E of ternary system was performed by the same vdW1 and TCBT models. For the correlation of the V-E of ternary data only TCBT mixing rules were used. PB - Elsevier Science Bv, Amsterdam T2 - Fluid Phase Equilibria T1 - 1-Butanol + hexylamine plus n-heptane at temperature range (288.15-323.15 K): Experimental density data, excess molar volumes determination and modeling with cubic EOS EP - 130 IS - 1 SP - 117 VL - 298 DO - 10.1016/j.fluid.2010.07.011 ER -
@article{ author = "Radović, Ivona and Kijevčanin, Mirjana and Šerbanović, Slobodan P. and Đorđević, Bojan D.", year = "2010", abstract = "Densities rho of the ternary system 1-butanol + hexylamine + n-heptane and binaries: 1-butanol + hexylamine and hexylamine + n-heptane within the temperature range (288.15-323.15K) and atmospheric pressure are reported. Excess molar volumes V-E were calculated from the density data and fitted by the Redlich-Kister and Nagata and Tamura equations. The results are analyzed in terms of the molecular interactions between the components of mixtures. Several empirical relationships (Radojkovic, Kohler, Jacob-Fitzner, Colinet,Tsao-Smith,Toop, Scatchard and Rastogi) were applied for prediction of V-E data of the ternary system from the corresponding binary data. For the correlation of binary V-E, the Peng-Robinson-Stryjek-Vera cubic equation of state (PRSV CEOS) coupled with the van der Waals (vcIW1) and CEOS/G(E) mixing rule introduced by Twu et al. (TCBT) were chosen. Prediction of V-E of ternary system was performed by the same vdW1 and TCBT models. For the correlation of the V-E of ternary data only TCBT mixing rules were used.", publisher = "Elsevier Science Bv, Amsterdam", journal = "Fluid Phase Equilibria", title = "1-Butanol + hexylamine plus n-heptane at temperature range (288.15-323.15 K): Experimental density data, excess molar volumes determination and modeling with cubic EOS", pages = "130-117", number = "1", volume = "298", doi = "10.1016/j.fluid.2010.07.011" }
Radović, I., Kijevčanin, M., Šerbanović, S. P.,& Đorđević, B. D.. (2010). 1-Butanol + hexylamine plus n-heptane at temperature range (288.15-323.15 K): Experimental density data, excess molar volumes determination and modeling with cubic EOS. in Fluid Phase Equilibria Elsevier Science Bv, Amsterdam., 298(1), 117-130. https://doi.org/10.1016/j.fluid.2010.07.011
Radović I, Kijevčanin M, Šerbanović SP, Đorđević BD. 1-Butanol + hexylamine plus n-heptane at temperature range (288.15-323.15 K): Experimental density data, excess molar volumes determination and modeling with cubic EOS. in Fluid Phase Equilibria. 2010;298(1):117-130. doi:10.1016/j.fluid.2010.07.011 .
Radović, Ivona, Kijevčanin, Mirjana, Šerbanović, Slobodan P., Đorđević, Bojan D., "1-Butanol + hexylamine plus n-heptane at temperature range (288.15-323.15 K): Experimental density data, excess molar volumes determination and modeling with cubic EOS" in Fluid Phase Equilibria, 298, no. 1 (2010):117-130, https://doi.org/10.1016/j.fluid.2010.07.011 . .