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Electrochemical behavior of polyaniline in chloride/citrate electrolyte

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2011
1764.pdf (3.402Mb)
Authors
Jugović, Branimir
Gvozdenović, Milica
Trišović, Tomislav
Stevanović, Jasmina
Grgur, Branimir
Conference object (Published version)
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Abstract
Polyaniline electrode, was obtained by electrochemical polymerization at constant current density of 2.0 mA cm-2 from aqueous solution of 1.0 mol dm-3 HCl containing 0.25 mol dm-3 aniline. Electrochemical characterization of the polyaniline electrode in chloride and chloride/citrate electrolyte, for different anodic potential limits, was performed using cyclic voltammetry and galvanostatic measurements. It was observed that for anodic potential 0.32 V, higher electrode capacity in chloride/citrate was obtained. For anodic potential limit of 0.50 V, faster decrease of the electrode capacity in chloride/citrate electrolyte was also observed. It was suggested that influence of both chloride and citrate anions has to be taken into account.
Keywords:
polyaniline / chloride and citrate electrolyte / polymers / electrochemical techniques / electrochemical properties
Source:
Proceedings of the 38th International Conference of Slovak Society of Chemical Engineering, 2011, 963-967
Publisher:
  • Tatranské Matliare : Slovak Society of Chemical Engineering
Funding / projects:
  • Electrochemical synthesis and characterization of nanostructured functional materials for application in new technologies (RS-172046)

ISBN: 978-80-227-3503-2

[ Google Scholar ]
Handle
https://hdl.handle.net/21.15107/rcub_technorep_1767
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1767
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
Institution/Community
Tehnološko-metalurški fakultet
TY  - CONF
AU  - Jugović, Branimir
AU  - Gvozdenović, Milica
AU  - Trišović, Tomislav
AU  - Stevanović, Jasmina
AU  - Grgur, Branimir
PY  - 2011
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1767
AB  - Polyaniline electrode, was obtained by electrochemical polymerization at constant current density of 2.0 mA cm-2 from aqueous solution of 1.0 mol dm-3 HCl containing 0.25 mol dm-3 aniline. Electrochemical characterization of the polyaniline electrode in chloride and chloride/citrate electrolyte, for different anodic potential limits, was performed using cyclic voltammetry and galvanostatic measurements. It was observed that for anodic potential 0.32 V, higher electrode capacity in chloride/citrate was obtained. For anodic potential limit of 0.50 V, faster decrease of the electrode capacity in chloride/citrate electrolyte was also observed. It was suggested that influence of both chloride and citrate anions has to be taken into account.
PB  - Tatranské Matliare : Slovak Society of Chemical Engineering
C3  - Proceedings of the 38th International Conference of Slovak Society of Chemical Engineering
T1  - Electrochemical behavior of polyaniline in chloride/citrate electrolyte
EP  - 967
SP  - 963
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1767
ER  - 
@conference{
author = "Jugović, Branimir and Gvozdenović, Milica and Trišović, Tomislav and Stevanović, Jasmina and Grgur, Branimir",
year = "2011",
abstract = "Polyaniline electrode, was obtained by electrochemical polymerization at constant current density of 2.0 mA cm-2 from aqueous solution of 1.0 mol dm-3 HCl containing 0.25 mol dm-3 aniline. Electrochemical characterization of the polyaniline electrode in chloride and chloride/citrate electrolyte, for different anodic potential limits, was performed using cyclic voltammetry and galvanostatic measurements. It was observed that for anodic potential 0.32 V, higher electrode capacity in chloride/citrate was obtained. For anodic potential limit of 0.50 V, faster decrease of the electrode capacity in chloride/citrate electrolyte was also observed. It was suggested that influence of both chloride and citrate anions has to be taken into account.",
publisher = "Tatranské Matliare : Slovak Society of Chemical Engineering",
journal = "Proceedings of the 38th International Conference of Slovak Society of Chemical Engineering",
title = "Electrochemical behavior of polyaniline in chloride/citrate electrolyte",
pages = "967-963",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1767"
}
Jugović, B., Gvozdenović, M., Trišović, T., Stevanović, J.,& Grgur, B.. (2011). Electrochemical behavior of polyaniline in chloride/citrate electrolyte. in Proceedings of the 38th International Conference of Slovak Society of Chemical Engineering
Tatranské Matliare : Slovak Society of Chemical Engineering., 963-967.
https://hdl.handle.net/21.15107/rcub_technorep_1767
Jugović B, Gvozdenović M, Trišović T, Stevanović J, Grgur B. Electrochemical behavior of polyaniline in chloride/citrate electrolyte. in Proceedings of the 38th International Conference of Slovak Society of Chemical Engineering. 2011;:963-967.
https://hdl.handle.net/21.15107/rcub_technorep_1767 .
Jugović, Branimir, Gvozdenović, Milica, Trišović, Tomislav, Stevanović, Jasmina, Grgur, Branimir, "Electrochemical behavior of polyaniline in chloride/citrate electrolyte" in Proceedings of the 38th International Conference of Slovak Society of Chemical Engineering (2011):963-967,
https://hdl.handle.net/21.15107/rcub_technorep_1767 .

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