Adsorption thermodynamics of organics on nickel- and copper-hexacyanoferrates
Apstrakt
Adsorption of various organics on Ni- and Cu-hexacyanoferrates was investigated by gas-solid chromatography (inverse gas chromatography). Adsorption was studied in the temperature region from 80 to 95 degrees C at zero surface coverage. Thermodynamic data of adsorption (standard free energy change, standard state enthalpies, and the entropy changes) were calculated using the surface partition coefficients. Thermodynamic parameters are discussed in terms of surface properties of used adsorbents and physicochemical properties of organic compounds.
Ključne reči:
insoluble hexacyanoferrates / Adsorption / organic molecules / gas chromatographyIzvor:
Materials Science Forum, 1998, 282-2, 183-188Izdavač:
- Trans Tech Publications Ltd, Durnten-Zurich
DOI: 10.4028/www.scientific.net/MSF.282-283.183
ISSN: 0255-5476
WoS: 000075079900025
[ Google Scholar ]Institucija/grupa
Tehnološko-metalurški fakultetTY - JOUR AU - Onjia, Antonije AU - Milonjić, Slobodan K. AU - Todorović, M. AU - Loos-Nesković, C AU - Fedoroff, A AU - Jones, DJ PY - 1998 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/178 AB - Adsorption of various organics on Ni- and Cu-hexacyanoferrates was investigated by gas-solid chromatography (inverse gas chromatography). Adsorption was studied in the temperature region from 80 to 95 degrees C at zero surface coverage. Thermodynamic data of adsorption (standard free energy change, standard state enthalpies, and the entropy changes) were calculated using the surface partition coefficients. Thermodynamic parameters are discussed in terms of surface properties of used adsorbents and physicochemical properties of organic compounds. PB - Trans Tech Publications Ltd, Durnten-Zurich T2 - Materials Science Forum T1 - Adsorption thermodynamics of organics on nickel- and copper-hexacyanoferrates EP - 188 SP - 183 VL - 282-2 DO - 10.4028/www.scientific.net/MSF.282-283.183 ER -
@article{ author = "Onjia, Antonije and Milonjić, Slobodan K. and Todorović, M. and Loos-Nesković, C and Fedoroff, A and Jones, DJ", year = "1998", abstract = "Adsorption of various organics on Ni- and Cu-hexacyanoferrates was investigated by gas-solid chromatography (inverse gas chromatography). Adsorption was studied in the temperature region from 80 to 95 degrees C at zero surface coverage. Thermodynamic data of adsorption (standard free energy change, standard state enthalpies, and the entropy changes) were calculated using the surface partition coefficients. Thermodynamic parameters are discussed in terms of surface properties of used adsorbents and physicochemical properties of organic compounds.", publisher = "Trans Tech Publications Ltd, Durnten-Zurich", journal = "Materials Science Forum", title = "Adsorption thermodynamics of organics on nickel- and copper-hexacyanoferrates", pages = "188-183", volume = "282-2", doi = "10.4028/www.scientific.net/MSF.282-283.183" }
Onjia, A., Milonjić, S. K., Todorović, M., Loos-Nesković, C., Fedoroff, A.,& Jones, D.. (1998). Adsorption thermodynamics of organics on nickel- and copper-hexacyanoferrates. in Materials Science Forum Trans Tech Publications Ltd, Durnten-Zurich., 282-2, 183-188. https://doi.org/10.4028/www.scientific.net/MSF.282-283.183
Onjia A, Milonjić SK, Todorović M, Loos-Nesković C, Fedoroff A, Jones D. Adsorption thermodynamics of organics on nickel- and copper-hexacyanoferrates. in Materials Science Forum. 1998;282-2:183-188. doi:10.4028/www.scientific.net/MSF.282-283.183 .
Onjia, Antonije, Milonjić, Slobodan K., Todorović, M., Loos-Nesković, C, Fedoroff, A, Jones, DJ, "Adsorption thermodynamics of organics on nickel- and copper-hexacyanoferrates" in Materials Science Forum, 282-2 (1998):183-188, https://doi.org/10.4028/www.scientific.net/MSF.282-283.183 . .