TechnoRep - Faculty of Technology and Metallurgy Repository
University of Belgrade - Faculty of Technology and Metallurgy
    • English
    • Српски
    • Српски (Serbia)
  • English 
    • English
    • Serbian (Cyrillic)
    • Serbian (Latin)
  • Login
View Item 
  •   TechnoRep
  • Tehnološko-metalurški fakultet
  • Radovi istraživača / Researchers’ publications (TMF)
  • View Item
  •   TechnoRep
  • Tehnološko-metalurški fakultet
  • Radovi istraživača / Researchers’ publications (TMF)
  • View Item
JavaScript is disabled for your browser. Some features of this site may not work without it.

Crystallization behaviour of Li2O·Nb2O5·SiO2 glass containing TiO2

Thumbnail
2011
1818.pdf (669.4Kb)
Authors
Matijašević, Srđan D.
Živanović, Vladimir D.
Tošić, Mihajlo B.
Grujić, Snežana
Stojanović, Jovica
Nikolić, Jelena D.
Ždrale, Sonja V.
Article (Published version)
Metadata
Show full item record
Abstract
This paper deals with the crystallization of glass 30Li2O·15Nb2O5·50SiO2·5TiO2 (mol%). The crystallization behavior was studied under isothermal and non-isothermal conditions. XRD and SEM methods were employed for determination of phase composition and microstructure of crystallized glass. It was detected that this glass crystallizes by the surface crystallization mechanism. SEM micrographs of the crystallized samples revealed that the crystals grow in the form of dendrites. The glass-ceramics with complex phase composition was obtained. Three crystalline phases were detected where LiNbO3 has grown as primary phase and a secondary ones Li2Si2O5 and SiO2 appeared. The calculated average crystallite sizes are: 27 nm for LiNbO3 , 115 nm for Li2Si2O5 and 45 nm for SiO2 . From the experimental data an activation energy of crystals growth, calculated using the Kissinger relation, is Ea = 275 ±10 KJ / mol.
Keywords:
lithium niobate / glass-ceramics / crystallization / crystal growth
Source:
Processing and Application of Ceramics, 2011, 5, 4, 223-227
Publisher:
  • University of Novi Sad
Funding / projects:
  • The development of glasses with controlled ions release for application in agriculture and medicine (RS-34001)
  • Phenomena and processes of the synthesis of new glassy and nano-structured glass-ceramics materials (RS-172004)

ISSN: 1820-6131

[ Google Scholar ]
Handle
https://hdl.handle.net/21.15107/rcub_technorep_1821
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1821
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Matijašević, Srđan D.
AU  - Živanović, Vladimir D.
AU  - Tošić, Mihajlo B.
AU  - Grujić, Snežana
AU  - Stojanović, Jovica
AU  - Nikolić, Jelena D.
AU  - Ždrale, Sonja V.
PY  - 2011
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1821
AB  - This paper deals with the crystallization of glass 30Li2O·15Nb2O5·50SiO2·5TiO2 (mol%). The crystallization behavior was studied under isothermal and non-isothermal conditions. XRD and SEM methods were employed for determination of phase composition and microstructure of crystallized glass. It was detected that this glass crystallizes by the surface crystallization mechanism. SEM micrographs of the crystallized samples revealed that the crystals grow in the form of dendrites. The glass-ceramics with complex phase composition was obtained. Three crystalline phases were detected where LiNbO3 has grown as primary phase and a secondary ones Li2Si2O5 and SiO2 appeared. The calculated average crystallite sizes are: 27 nm for LiNbO3 , 115 nm for Li2Si2O5 and 45 nm for SiO2 . From the experimental data an activation energy of crystals growth, calculated using the Kissinger relation, is Ea = 275 ±10 KJ / mol.
PB  - University of Novi Sad
T2  - Processing and Application of Ceramics
T1  - Crystallization behaviour of Li2O·Nb2O5·SiO2 glass containing TiO2
EP  - 227
IS  - 4
SP  - 223
VL  - 5
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1821
ER  - 
@article{
author = "Matijašević, Srđan D. and Živanović, Vladimir D. and Tošić, Mihajlo B. and Grujić, Snežana and Stojanović, Jovica and Nikolić, Jelena D. and Ždrale, Sonja V.",
year = "2011",
abstract = "This paper deals with the crystallization of glass 30Li2O·15Nb2O5·50SiO2·5TiO2 (mol%). The crystallization behavior was studied under isothermal and non-isothermal conditions. XRD and SEM methods were employed for determination of phase composition and microstructure of crystallized glass. It was detected that this glass crystallizes by the surface crystallization mechanism. SEM micrographs of the crystallized samples revealed that the crystals grow in the form of dendrites. The glass-ceramics with complex phase composition was obtained. Three crystalline phases were detected where LiNbO3 has grown as primary phase and a secondary ones Li2Si2O5 and SiO2 appeared. The calculated average crystallite sizes are: 27 nm for LiNbO3 , 115 nm for Li2Si2O5 and 45 nm for SiO2 . From the experimental data an activation energy of crystals growth, calculated using the Kissinger relation, is Ea = 275 ±10 KJ / mol.",
publisher = "University of Novi Sad",
journal = "Processing and Application of Ceramics",
title = "Crystallization behaviour of Li2O·Nb2O5·SiO2 glass containing TiO2",
pages = "227-223",
number = "4",
volume = "5",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1821"
}
Matijašević, S. D., Živanović, V. D., Tošić, M. B., Grujić, S., Stojanović, J., Nikolić, J. D.,& Ždrale, S. V.. (2011). Crystallization behaviour of Li2O·Nb2O5·SiO2 glass containing TiO2. in Processing and Application of Ceramics
University of Novi Sad., 5(4), 223-227.
https://hdl.handle.net/21.15107/rcub_technorep_1821
Matijašević SD, Živanović VD, Tošić MB, Grujić S, Stojanović J, Nikolić JD, Ždrale SV. Crystallization behaviour of Li2O·Nb2O5·SiO2 glass containing TiO2. in Processing and Application of Ceramics. 2011;5(4):223-227.
https://hdl.handle.net/21.15107/rcub_technorep_1821 .
Matijašević, Srđan D., Živanović, Vladimir D., Tošić, Mihajlo B., Grujić, Snežana, Stojanović, Jovica, Nikolić, Jelena D., Ždrale, Sonja V., "Crystallization behaviour of Li2O·Nb2O5·SiO2 glass containing TiO2" in Processing and Application of Ceramics, 5, no. 4 (2011):223-227,
https://hdl.handle.net/21.15107/rcub_technorep_1821 .

DSpace software copyright © 2002-2015  DuraSpace
About TechnoRep | Send Feedback

OpenAIRERCUB
 

 

All of DSpaceInstitutions/communitiesAuthorsTitlesSubjectsThis institutionAuthorsTitlesSubjects

Statistics

View Usage Statistics

DSpace software copyright © 2002-2015  DuraSpace
About TechnoRep | Send Feedback

OpenAIRERCUB