Crystallization behaviour of Li2O·Nb2O5·SiO2 glass containing TiO2

2011
Аутори
Matijašević, Srđan D.Živanović, Vladimir D.
Tošić, Mihajlo B.
Grujić, Snežana

Stojanović, Jovica
Nikolić, Jelena D.
Ždrale, Sonja V.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
This paper deals with the crystallization of glass 30Li2O·15Nb2O5·50SiO2·5TiO2 (mol%). The crystallization behavior was studied under isothermal and non-isothermal conditions. XRD and SEM methods were employed for determination of phase composition and microstructure of crystallized glass. It was detected that this glass crystallizes by the surface crystallization mechanism. SEM micrographs of the crystallized samples revealed that the crystals grow in the form of dendrites. The glass-ceramics with complex phase composition was obtained. Three crystalline phases were detected where LiNbO3 has grown as primary phase and a secondary ones Li2Si2O5 and SiO2 appeared. The calculated average crystallite sizes are: 27 nm for LiNbO3 , 115 nm for Li2Si2O5 and 45 nm for SiO2 . From the experimental data an activation energy of crystals growth, calculated using the Kissinger relation, is Ea = 275 ±10 KJ / mol.
Кључне речи:
lithium niobate / glass-ceramics / crystallization / crystal growthИзвор:
Processing and Application of Ceramics, 2011, 5, 4, 223-227Издавач:
- University of Novi Sad
Финансирање / пројекти:
- Развој стакала са контролисаним отпуштањем јона за примену у пољопривреди и медицини (RS-34001)
- Феномени и процеси синтезе нових стакластих и наноструктурних стакло-керамичких материјала (RS-172004)
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Matijašević, Srđan D. AU - Živanović, Vladimir D. AU - Tošić, Mihajlo B. AU - Grujić, Snežana AU - Stojanović, Jovica AU - Nikolić, Jelena D. AU - Ždrale, Sonja V. PY - 2011 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1821 AB - This paper deals with the crystallization of glass 30Li2O·15Nb2O5·50SiO2·5TiO2 (mol%). The crystallization behavior was studied under isothermal and non-isothermal conditions. XRD and SEM methods were employed for determination of phase composition and microstructure of crystallized glass. It was detected that this glass crystallizes by the surface crystallization mechanism. SEM micrographs of the crystallized samples revealed that the crystals grow in the form of dendrites. The glass-ceramics with complex phase composition was obtained. Three crystalline phases were detected where LiNbO3 has grown as primary phase and a secondary ones Li2Si2O5 and SiO2 appeared. The calculated average crystallite sizes are: 27 nm for LiNbO3 , 115 nm for Li2Si2O5 and 45 nm for SiO2 . From the experimental data an activation energy of crystals growth, calculated using the Kissinger relation, is Ea = 275 ±10 KJ / mol. PB - University of Novi Sad T2 - Processing and Application of Ceramics T1 - Crystallization behaviour of Li2O·Nb2O5·SiO2 glass containing TiO2 EP - 227 IS - 4 SP - 223 VL - 5 UR - https://hdl.handle.net/21.15107/rcub_technorep_1821 ER -
@article{ author = "Matijašević, Srđan D. and Živanović, Vladimir D. and Tošić, Mihajlo B. and Grujić, Snežana and Stojanović, Jovica and Nikolić, Jelena D. and Ždrale, Sonja V.", year = "2011", abstract = "This paper deals with the crystallization of glass 30Li2O·15Nb2O5·50SiO2·5TiO2 (mol%). The crystallization behavior was studied under isothermal and non-isothermal conditions. XRD and SEM methods were employed for determination of phase composition and microstructure of crystallized glass. It was detected that this glass crystallizes by the surface crystallization mechanism. SEM micrographs of the crystallized samples revealed that the crystals grow in the form of dendrites. The glass-ceramics with complex phase composition was obtained. Three crystalline phases were detected where LiNbO3 has grown as primary phase and a secondary ones Li2Si2O5 and SiO2 appeared. The calculated average crystallite sizes are: 27 nm for LiNbO3 , 115 nm for Li2Si2O5 and 45 nm for SiO2 . From the experimental data an activation energy of crystals growth, calculated using the Kissinger relation, is Ea = 275 ±10 KJ / mol.", publisher = "University of Novi Sad", journal = "Processing and Application of Ceramics", title = "Crystallization behaviour of Li2O·Nb2O5·SiO2 glass containing TiO2", pages = "227-223", number = "4", volume = "5", url = "https://hdl.handle.net/21.15107/rcub_technorep_1821" }
Matijašević, S. D., Živanović, V. D., Tošić, M. B., Grujić, S., Stojanović, J., Nikolić, J. D.,& Ždrale, S. V.. (2011). Crystallization behaviour of Li2O·Nb2O5·SiO2 glass containing TiO2. in Processing and Application of Ceramics University of Novi Sad., 5(4), 223-227. https://hdl.handle.net/21.15107/rcub_technorep_1821
Matijašević SD, Živanović VD, Tošić MB, Grujić S, Stojanović J, Nikolić JD, Ždrale SV. Crystallization behaviour of Li2O·Nb2O5·SiO2 glass containing TiO2. in Processing and Application of Ceramics. 2011;5(4):223-227. https://hdl.handle.net/21.15107/rcub_technorep_1821 .
Matijašević, Srđan D., Živanović, Vladimir D., Tošić, Mihajlo B., Grujić, Snežana, Stojanović, Jovica, Nikolić, Jelena D., Ždrale, Sonja V., "Crystallization behaviour of Li2O·Nb2O5·SiO2 glass containing TiO2" in Processing and Application of Ceramics, 5, no. 4 (2011):223-227, https://hdl.handle.net/21.15107/rcub_technorep_1821 .