The aim of this study was to present the quantitative determination of midecamycin at a gold electrode in 0.05 M NaHCO3 using cyclic linear sweep voltammetry. It was found that the value of the oxidative peak of pure midecamycin at 0.85 V vs. SCE at a scan rate of 50 mV s(-1) is a linear function of the concentration in the range 0.1693-0.3289 mg cm(-3). The value of its reductive peak at 0.3 V vs. SCE is a linear function of the concentration in the range 0.11396-0.3802 mg cm(-3). HPLC analysis of the bulk of electrolyte confirmed the data obtained by analysis of the current peak values concerning the correlation with each investigated concentration of midecamycin. By MS spectrometry no degradation products were found in electrolyte during its quantitative determination.
TY - JOUR
AU - Drljević-Đurić, Katica
AU - Avramov-Ivić, Milka
AU - Petrović, Slobodan
AU - Mijin, Dušan
AU - Jadranin, Milka
PY - 2011
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1871
AB - The aim of this study was to present the quantitative determination of midecamycin at a gold electrode in 0.05 M NaHCO3 using cyclic linear sweep voltammetry. It was found that the value of the oxidative peak of pure midecamycin at 0.85 V vs. SCE at a scan rate of 50 mV s(-1) is a linear function of the concentration in the range 0.1693-0.3289 mg cm(-3). The value of its reductive peak at 0.3 V vs. SCE is a linear function of the concentration in the range 0.11396-0.3802 mg cm(-3). HPLC analysis of the bulk of electrolyte confirmed the data obtained by analysis of the current peak values concerning the correlation with each investigated concentration of midecamycin. By MS spectrometry no degradation products were found in electrolyte during its quantitative determination.
PB - Pleiades Publishing Inc, Moscow
T2 - Russian Journal of Electrochemistry
T1 - A Voltammetric Method for the Quantitative Determination of Midecamycin Compared to Its Simultaneous HPLC Determination
EP - 786
IS - 7
SP - 781
VL - 47
DO - 10.1134/S1023193511070056
ER -
@article{
author = "Drljević-Đurić, Katica and Avramov-Ivić, Milka and Petrović, Slobodan and Mijin, Dušan and Jadranin, Milka",
year = "2011",
abstract = "The aim of this study was to present the quantitative determination of midecamycin at a gold electrode in 0.05 M NaHCO3 using cyclic linear sweep voltammetry. It was found that the value of the oxidative peak of pure midecamycin at 0.85 V vs. SCE at a scan rate of 50 mV s(-1) is a linear function of the concentration in the range 0.1693-0.3289 mg cm(-3). The value of its reductive peak at 0.3 V vs. SCE is a linear function of the concentration in the range 0.11396-0.3802 mg cm(-3). HPLC analysis of the bulk of electrolyte confirmed the data obtained by analysis of the current peak values concerning the correlation with each investigated concentration of midecamycin. By MS spectrometry no degradation products were found in electrolyte during its quantitative determination.",
publisher = "Pleiades Publishing Inc, Moscow",
journal = "Russian Journal of Electrochemistry",
title = "A Voltammetric Method for the Quantitative Determination of Midecamycin Compared to Its Simultaneous HPLC Determination",
pages = "786-781",
number = "7",
volume = "47",
doi = "10.1134/S1023193511070056"
}
Drljević-Đurić, K., Avramov-Ivić, M., Petrović, S., Mijin, D.,& Jadranin, M.. (2011). A Voltammetric Method for the Quantitative Determination of Midecamycin Compared to Its Simultaneous HPLC Determination. in Russian Journal of Electrochemistry
Pleiades Publishing Inc, Moscow., 47(7), 781-786.
https://doi.org/10.1134/S1023193511070056
Drljević-Đurić K, Avramov-Ivić M, Petrović S, Mijin D, Jadranin M. A Voltammetric Method for the Quantitative Determination of Midecamycin Compared to Its Simultaneous HPLC Determination. in Russian Journal of Electrochemistry. 2011;47(7):781-786.
doi:10.1134/S1023193511070056 .
Drljević-Đurić, Katica, Avramov-Ivić, Milka, Petrović, Slobodan, Mijin, Dušan, Jadranin, Milka, "A Voltammetric Method for the Quantitative Determination of Midecamycin Compared to Its Simultaneous HPLC Determination" in Russian Journal of Electrochemistry, 47, no. 7 (2011):781-786,
https://doi.org/10.1134/S1023193511070056 . .
