catena-Poly[[[(di-2-pyridylamine-kappa N-2(2),N-2 ')copper(II)]-mu-benzene-1,3-dicarboxylato-kappa O-3(1),O-1 ':O-3] monohydrate], a zigzag coordination polymer with strong pi-pi interactions
Само за регистроване кориснике
2011
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The novel title coordination polymer, {[Cu(C8H4O4)-(C10H9N3)]center dot H2O}(n), synthesized by the slow-diffusion method, takes the form of one-dimensional zigzag chains built up of Cu-II cations linked by benzene-1,3-dicarboxylate (ipht) anions. An exceptional characteristic of this structure is that it belongs to a small group of metal-organic polymers where ipht is coordinated as a bridging tridentate ligand with monodentate and chelate coordination of individual carboxylate groups. The Cu-II cation has a highly distorted square-pyramidal geometry formed by three O atoms from two ipht anions and two N atoms from a di-2-pyridylamine (dipya) ligand. The zigzag chains, which run along the b axis, further construct a three-dimensional metal-organic framework via strong face-to-face pi-pi interactions and hydrogen bonds. A solvent water molecule is linked to the different carboxylate groups via hydrogen bonds. Thermogravimetric and differential scanning calorimetric analyses confirm the... strong hydrogen bonding.
Извор:
Acta Crystallographica Section C-Crystal Structure Communications, 2011, 67, M230-M233Издавач:
- Wiley-Blackwell, Hoboken
Финансирање / пројекти:
- 0-3D наноструктуре за примену у електроници и обновљивим изворима енергије: синтеза, карактеризација и процесирање (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45007)
DOI: 10.1107/S0108270111022451
ISSN: 0108-2701
PubMed: 21727619
WoS: 000292468900008
Scopus: 2-s2.0-79959960186
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Rogan, Jelena AU - Poleti, Dejan AU - Karanović, Ljiljana PY - 2011 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1914 AB - The novel title coordination polymer, {[Cu(C8H4O4)-(C10H9N3)]center dot H2O}(n), synthesized by the slow-diffusion method, takes the form of one-dimensional zigzag chains built up of Cu-II cations linked by benzene-1,3-dicarboxylate (ipht) anions. An exceptional characteristic of this structure is that it belongs to a small group of metal-organic polymers where ipht is coordinated as a bridging tridentate ligand with monodentate and chelate coordination of individual carboxylate groups. The Cu-II cation has a highly distorted square-pyramidal geometry formed by three O atoms from two ipht anions and two N atoms from a di-2-pyridylamine (dipya) ligand. The zigzag chains, which run along the b axis, further construct a three-dimensional metal-organic framework via strong face-to-face pi-pi interactions and hydrogen bonds. A solvent water molecule is linked to the different carboxylate groups via hydrogen bonds. Thermogravimetric and differential scanning calorimetric analyses confirm the strong hydrogen bonding. PB - Wiley-Blackwell, Hoboken T2 - Acta Crystallographica Section C-Crystal Structure Communications T1 - catena-Poly[[[(di-2-pyridylamine-kappa N-2(2),N-2 ')copper(II)]-mu-benzene-1,3-dicarboxylato-kappa O-3(1),O-1 ':O-3] monohydrate], a zigzag coordination polymer with strong pi-pi interactions EP - M233 SP - M230 VL - 67 DO - 10.1107/S0108270111022451 ER -
@article{ author = "Rogan, Jelena and Poleti, Dejan and Karanović, Ljiljana", year = "2011", abstract = "The novel title coordination polymer, {[Cu(C8H4O4)-(C10H9N3)]center dot H2O}(n), synthesized by the slow-diffusion method, takes the form of one-dimensional zigzag chains built up of Cu-II cations linked by benzene-1,3-dicarboxylate (ipht) anions. An exceptional characteristic of this structure is that it belongs to a small group of metal-organic polymers where ipht is coordinated as a bridging tridentate ligand with monodentate and chelate coordination of individual carboxylate groups. The Cu-II cation has a highly distorted square-pyramidal geometry formed by three O atoms from two ipht anions and two N atoms from a di-2-pyridylamine (dipya) ligand. The zigzag chains, which run along the b axis, further construct a three-dimensional metal-organic framework via strong face-to-face pi-pi interactions and hydrogen bonds. A solvent water molecule is linked to the different carboxylate groups via hydrogen bonds. Thermogravimetric and differential scanning calorimetric analyses confirm the strong hydrogen bonding.", publisher = "Wiley-Blackwell, Hoboken", journal = "Acta Crystallographica Section C-Crystal Structure Communications", title = "catena-Poly[[[(di-2-pyridylamine-kappa N-2(2),N-2 ')copper(II)]-mu-benzene-1,3-dicarboxylato-kappa O-3(1),O-1 ':O-3] monohydrate], a zigzag coordination polymer with strong pi-pi interactions", pages = "M233-M230", volume = "67", doi = "10.1107/S0108270111022451" }
Rogan, J., Poleti, D.,& Karanović, L.. (2011). catena-Poly[[[(di-2-pyridylamine-kappa N-2(2),N-2 ')copper(II)]-mu-benzene-1,3-dicarboxylato-kappa O-3(1),O-1 ':O-3] monohydrate], a zigzag coordination polymer with strong pi-pi interactions. in Acta Crystallographica Section C-Crystal Structure Communications Wiley-Blackwell, Hoboken., 67, M230-M233. https://doi.org/10.1107/S0108270111022451
Rogan J, Poleti D, Karanović L. catena-Poly[[[(di-2-pyridylamine-kappa N-2(2),N-2 ')copper(II)]-mu-benzene-1,3-dicarboxylato-kappa O-3(1),O-1 ':O-3] monohydrate], a zigzag coordination polymer with strong pi-pi interactions. in Acta Crystallographica Section C-Crystal Structure Communications. 2011;67:M230-M233. doi:10.1107/S0108270111022451 .
Rogan, Jelena, Poleti, Dejan, Karanović, Ljiljana, "catena-Poly[[[(di-2-pyridylamine-kappa N-2(2),N-2 ')copper(II)]-mu-benzene-1,3-dicarboxylato-kappa O-3(1),O-1 ':O-3] monohydrate], a zigzag coordination polymer with strong pi-pi interactions" in Acta Crystallographica Section C-Crystal Structure Communications, 67 (2011):M230-M233, https://doi.org/10.1107/S0108270111022451 . .