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Effects of additives on nickel (ii)-chloride hydrogen reduction for production of nanocomposite catalysts

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Authors
Kamberović, Željko
Sokić, Miroslav
Matković, Vladislav
Anđić, Zoran
Korać, Marija
Nikolić, Vesna
Article (Published version)
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Abstract
Catalysts based on nickel, as active component, exhibit suitable properties in various heterogeneous catalysis processes; however, they quickly deactivate due to deposits formation during exploitation and sintering at elevated temperatures. Considering that catalysts with several catalytic components possess enhanced catalytic properties, in present study the influence of temperature, time and additives (PdCl2, FeCl2 and CuCl2) on the reduction degree of nickel(II)-chloride by hydrogen have been investigated. The objectives of the study were selection of an appropriate catalytic activity modifier and development of a new synthesis method for nanocomposite catalysts production, which are characterized by enhanced properties compared to the commercial Ni/Al2O3 catalysts. Obtained experimental results clearly indicate that the best effect was achieved with addition of 0.1 wt. % PdCl2, whereby NiCl2, reduction degree was 58.16% at 653 K and Pd significantly increased the reduction rate. Ac...cording to the obtained results., new technological synthesis method of nanocomposite Ni-Pd/Al2O3 catalysis was proposed, where Ni and Pd. as catalytically active components, are homogeneously dispersed in monolithic Al2O3 based ceramic foam.

Keywords:
nickel(II)-chloride / active additives / hydrogen reduction / catalysts
Source:
Metalurgia International, 2012, 17, 5, 37-41
Publisher:
  • Editura Stiintifica Fmr, Bucharest
Funding / projects:
  • Innovative synergy of by-products, waste minimization and clean technologies in metallurgy (RS-34033)
  • Developing technological processes for nonstandard copper concentrates processing with the aim to decrease pollutants emission (RS-34023)

ISSN: 1582-2214

PubMed:

WoS: 000302202400006

Scopus: 2-s2.0-84859418597
[ Google Scholar ]
2
1
Handle
https://hdl.handle.net/21.15107/rcub_technorep_1996
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1996
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
  • Radovi istraživača (Inovacioni centar) / Researchers’ publications (Innovation Centre)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Kamberović, Željko
AU  - Sokić, Miroslav
AU  - Matković, Vladislav
AU  - Anđić, Zoran
AU  - Korać, Marija
AU  - Nikolić, Vesna
PY  - 2012
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1996
AB  - Catalysts based on nickel, as active component, exhibit suitable properties in various heterogeneous catalysis processes; however, they quickly deactivate due to deposits formation during exploitation and sintering at elevated temperatures. Considering that catalysts with several catalytic components possess enhanced catalytic properties, in present study the influence of temperature, time and additives (PdCl2, FeCl2 and CuCl2) on the reduction degree of nickel(II)-chloride by hydrogen have been investigated. The objectives of the study were selection of an appropriate catalytic activity modifier and development of a new synthesis method for nanocomposite catalysts production, which are characterized by enhanced properties compared to the commercial Ni/Al2O3 catalysts. Obtained experimental results clearly indicate that the best effect was achieved with addition of 0.1 wt. % PdCl2, whereby NiCl2, reduction degree was 58.16% at 653 K and Pd significantly increased the reduction rate. According to the obtained results., new technological synthesis method of nanocomposite Ni-Pd/Al2O3 catalysis was proposed, where Ni and Pd. as catalytically active components, are homogeneously dispersed in monolithic Al2O3 based ceramic foam.
PB  - Editura Stiintifica Fmr, Bucharest
T2  - Metalurgia International
T1  - Effects of additives on nickel (ii)-chloride hydrogen reduction for production of nanocomposite catalysts
EP  - 41
IS  - 5
SP  - 37
VL  - 17
UR  - https://hdl.handle.net/21.15107/rcub_technorep_1996
ER  - 
@article{
author = "Kamberović, Željko and Sokić, Miroslav and Matković, Vladislav and Anđić, Zoran and Korać, Marija and Nikolić, Vesna",
year = "2012",
abstract = "Catalysts based on nickel, as active component, exhibit suitable properties in various heterogeneous catalysis processes; however, they quickly deactivate due to deposits formation during exploitation and sintering at elevated temperatures. Considering that catalysts with several catalytic components possess enhanced catalytic properties, in present study the influence of temperature, time and additives (PdCl2, FeCl2 and CuCl2) on the reduction degree of nickel(II)-chloride by hydrogen have been investigated. The objectives of the study were selection of an appropriate catalytic activity modifier and development of a new synthesis method for nanocomposite catalysts production, which are characterized by enhanced properties compared to the commercial Ni/Al2O3 catalysts. Obtained experimental results clearly indicate that the best effect was achieved with addition of 0.1 wt. % PdCl2, whereby NiCl2, reduction degree was 58.16% at 653 K and Pd significantly increased the reduction rate. According to the obtained results., new technological synthesis method of nanocomposite Ni-Pd/Al2O3 catalysis was proposed, where Ni and Pd. as catalytically active components, are homogeneously dispersed in monolithic Al2O3 based ceramic foam.",
publisher = "Editura Stiintifica Fmr, Bucharest",
journal = "Metalurgia International",
title = "Effects of additives on nickel (ii)-chloride hydrogen reduction for production of nanocomposite catalysts",
pages = "41-37",
number = "5",
volume = "17",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1996"
}
Kamberović, Ž., Sokić, M., Matković, V., Anđić, Z., Korać, M.,& Nikolić, V.. (2012). Effects of additives on nickel (ii)-chloride hydrogen reduction for production of nanocomposite catalysts. in Metalurgia International
Editura Stiintifica Fmr, Bucharest., 17(5), 37-41.
https://hdl.handle.net/21.15107/rcub_technorep_1996
Kamberović Ž, Sokić M, Matković V, Anđić Z, Korać M, Nikolić V. Effects of additives on nickel (ii)-chloride hydrogen reduction for production of nanocomposite catalysts. in Metalurgia International. 2012;17(5):37-41.
https://hdl.handle.net/21.15107/rcub_technorep_1996 .
Kamberović, Željko, Sokić, Miroslav, Matković, Vladislav, Anđić, Zoran, Korać, Marija, Nikolić, Vesna, "Effects of additives on nickel (ii)-chloride hydrogen reduction for production of nanocomposite catalysts" in Metalurgia International, 17, no. 5 (2012):37-41,
https://hdl.handle.net/21.15107/rcub_technorep_1996 .

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