Aluminium was incorporated into polycrystalline zinc electrode surface by underpotential deposition from equimolar AlCl3+NaCl melt at 473, 523 and 573 K. The process was studied by linear sweep voltammetry and potentiostatic deposition/galvanostatic striping. The deposits were characterised by glancing incidence X-ray diffraction (GIXRD), Auger (AES) and electron probe micro-analyzer (EPMA). The electrochemical measurements showed evidence of Zn - Al alloys being formed. The constant-potential regions measured during the low-current striping correspond to the coexistence of two pairs of metastable intermetallic phases. However, the observed alloys could not be identified. The growth kinetics of the compounds is described.
TY - JOUR
AU - Jovicević, Niko
AU - Cvetković, Vesna S.
AU - Kamberović, Željko
AU - Jovicević, Jovan N.
PY - 2012
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1999
AB - Aluminium was incorporated into polycrystalline zinc electrode surface by underpotential deposition from equimolar AlCl3+NaCl melt at 473, 523 and 573 K. The process was studied by linear sweep voltammetry and potentiostatic deposition/galvanostatic striping. The deposits were characterised by glancing incidence X-ray diffraction (GIXRD), Auger (AES) and electron probe micro-analyzer (EPMA). The electrochemical measurements showed evidence of Zn - Al alloys being formed. The constant-potential regions measured during the low-current striping correspond to the coexistence of two pairs of metastable intermetallic phases. However, the observed alloys could not be identified. The growth kinetics of the compounds is described.
PB - Electrochemical Science Group, Beograd
T2 - International Journal of Electrochemical Science
T1 - Al-Zn Alloy Formation by Aluminium Underpotential Deposition from AlCl3+NaCl Melts on Zinc Substrate
EP - 10393
IS - 11
SP - 10380
VL - 7
UR - https://hdl.handle.net/21.15107/rcub_technorep_1999
ER -
@article{
author = "Jovicević, Niko and Cvetković, Vesna S. and Kamberović, Željko and Jovicević, Jovan N.",
year = "2012",
abstract = "Aluminium was incorporated into polycrystalline zinc electrode surface by underpotential deposition from equimolar AlCl3+NaCl melt at 473, 523 and 573 K. The process was studied by linear sweep voltammetry and potentiostatic deposition/galvanostatic striping. The deposits were characterised by glancing incidence X-ray diffraction (GIXRD), Auger (AES) and electron probe micro-analyzer (EPMA). The electrochemical measurements showed evidence of Zn - Al alloys being formed. The constant-potential regions measured during the low-current striping correspond to the coexistence of two pairs of metastable intermetallic phases. However, the observed alloys could not be identified. The growth kinetics of the compounds is described.",
publisher = "Electrochemical Science Group, Beograd",
journal = "International Journal of Electrochemical Science",
title = "Al-Zn Alloy Formation by Aluminium Underpotential Deposition from AlCl3+NaCl Melts on Zinc Substrate",
pages = "10393-10380",
number = "11",
volume = "7",
url = "https://hdl.handle.net/21.15107/rcub_technorep_1999"
}
Jovicević, N., Cvetković, V. S., Kamberović, Ž.,& Jovicević, J. N.. (2012). Al-Zn Alloy Formation by Aluminium Underpotential Deposition from AlCl3+NaCl Melts on Zinc Substrate. in International Journal of Electrochemical Science
Electrochemical Science Group, Beograd., 7(11), 10380-10393.
https://hdl.handle.net/21.15107/rcub_technorep_1999
Jovicević N, Cvetković VS, Kamberović Ž, Jovicević JN. Al-Zn Alloy Formation by Aluminium Underpotential Deposition from AlCl3+NaCl Melts on Zinc Substrate. in International Journal of Electrochemical Science. 2012;7(11):10380-10393.
https://hdl.handle.net/21.15107/rcub_technorep_1999 .
Jovicević, Niko, Cvetković, Vesna S., Kamberović, Željko, Jovicević, Jovan N., "Al-Zn Alloy Formation by Aluminium Underpotential Deposition from AlCl3+NaCl Melts on Zinc Substrate" in International Journal of Electrochemical Science, 7, no. 11 (2012):10380-10393,
https://hdl.handle.net/21.15107/rcub_technorep_1999 .
