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Kinetic analysis of hydrogen evolution at Ni-Mo alloy electrodes
(Elsevier Science Ltd, 2000)
The hydrogen evolution reaction (HER) on Ni, Mo and MoNi intermetallic compound was investigated with ac impedance and dc polarization measurements in 1.0 mol dm-3 NaOH solution at 25 °C. The rate constants of the forward ...
HCOOH oxidation on thin Pd layers on Au: Self-poisoning by the subsequent reaction of the reaction product
(Pergamon-Elsevier Science Ltd, Oxford, 2013)
The oxidation of HCOOH has been investigated on thin Pd layers ranging from 1 to 17 ML equivalents electrodeposited on polycrystalline Au substrate (Pd"Au). The results are compared to those on Pd black. Potentiodynamic ...
Synthesis and characterization of MoOx-Pt/C and TiOx-Pt/C nano-catalysts for oxygen reduction
(Pergamon-Elsevier Science Ltd, Oxford, 2009)
The oxygen reduction reaction (ORR) was studied at carbon supported MoOx-Pt/C and TiOx-Pt nanocatalysts in 0.5 mol dm(-3) HClO4 solution, at 25 degrees C. The MoOx-Pt/C and TiOx-Pt/C catalysts were prepared by the polyole ...
Hydrogen evolution in acid solution at Pd electrodeposited onto Ti2AlC
(Pergamon-Elsevier Science Ltd, Oxford, 2017)
The hydrogen evolution reaction (HER) was studied in 0.5 M H2SO4 at 25 degrees C on Pd electrodeposited onto Ti2AlC substrate, as an excellent substrate due to its high conductivity and high stability in concentrated ...
Methanol oxidation on an ink type electrode using Pt supported on high area carbons
(Pergamon-Elsevier Science Ltd, Oxford, 2001)
Methanol oxidation was investigated on the following Pt catalysts: bare Pt electrode, Pt covered by nafion (R) film, and pt catalysts supported on high area carbons in the form of an ink. The reaction was carried out using ...
Coupling electrokinetic with a cork-based permeable reactive barrier to prevent groundwater pollution: A case study on hexavalent chromium-contaminated soil
(Elsevier Ltd., 2022)
This work proposes an eco-efficient treatment technology for the remediation of a kaolinite-based clay soil artificially contaminated with hexavalent chromium (50 mg Cr(VI) kg–1 soil), combining electrokinetics (EK) with ...
Ti substrate coated with composite Cr–MoO2 coatings as highly selective cathode materials in hypochlorite production
(Elsevier, 2013)
The aim of this work was to investigate the possibility of preparation of the composite Cr–MoO2 coatings onto steel and titanium substrates as cathode materials with high selective properties which imply the suppression ...
Oxygen reduction on iron-IV. The reduction of hydrogen peroxide as the intermediate in oxygen reduction reaction in alkaline solutions
(Pergamon-Elsevier Science Ltd, Oxford, 1991)
The kinetics of hydrogen peroxide reduction were studied on iron in borate buffered and unbuffered solutions of pH ranging from 8.6 to 13.8, with and without the presence of chloride ions. A rotating disk electrode was ...
The origin of high activity of Pt-Au surfaces in the formic acid oxidation
(Pergamon-Elsevier Science Ltd, Oxford, 2009)
We have investigated the oxidation of HCOOH on Au-modified Pt (Au"Pt) and Pt-modified Au (Pt")/Au) electrodes to establish the role of the ensemble and the electronic effect in the catalysis of this reaction. The surfaces ...
The effect of the electrode surface roughness at low level of coarseness on the polarization characteristics of electrochemical processes
(Pergamon-Elsevier Science Ltd, Oxford, 2010)
In this study, it is considered: (a) the effect of the exchange current density to the limiting diffusion current density ratio (J(0)/J(L)) at low level of surface coarseness on the polarization characteristics of the ...