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Catalysis of oxygen reduction on Au modified by Pd nanoislands in perchloric acid solution
(Pergamon-Elsevier Science Ltd, Oxford, 2012)
Oxygen reduction reaction (ORR) was studied on polycrystalline gold, Au(poly), modified by nanosized palladium islands in 0.1 M HClO4 solution using rotating disc electrode technique. Paladium was spontaneously deposited ...
HCOOH oxidation on thin Pd layers on Au: Self-poisoning by the subsequent reaction of the reaction product
(Pergamon-Elsevier Science Ltd, Oxford, 2013)
The oxidation of HCOOH has been investigated on thin Pd layers ranging from 1 to 17 ML equivalents electrodeposited on polycrystalline Au substrate (Pd"Au). The results are compared to those on Pd black. Potentiodynamic ...
The origin of high activity of Pt-Au surfaces in the formic acid oxidation
(Pergamon-Elsevier Science Ltd, Oxford, 2009)
We have investigated the oxidation of HCOOH on Au-modified Pt (Au"Pt) and Pt-modified Au (Pt")/Au) electrodes to establish the role of the ensemble and the electronic effect in the catalysis of this reaction. The surfaces ...