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Tio2/zro2 thin films synthesized by pld in low pressure n-, c- and/or o-containing gases: structural, optical and photocatalytic properties

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Authors
Linnik, Oksana
Petrik, Irina
Smirnova, Natalia
Kandyba, Viktor
Korduban, Oleksandr
Eremenko, Anna
Socol, Gabriel
Stefan, Nicolaie
Ristoscu, Carmen
Mihailescu, Ion N.
Sutan, Claudiu
Malinovschi, Viorel
Đokić, Veljko
Janaković, Đordje
Article (Published version)
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Abstract
Doped TiO2/ZrO2 films were obtained by Pulsed Laser Deposition method under different synthesis conditions. The onset of absorption spectra was red shifted for the films obtained in N-2 containing gas mixtures, while a broad absorption in visible was observed in the case of films deposited in CH4 atmosphere. The presence of O-Ti-N bonds revealed by XPS corresponded to the highest photocatalytic performance. XPS spectra of the samples obtained in N-2/CH4 gas mixtures evidenced a more effective incorporation of nitrogen in the structure due to oxygen deficiency. Nevertheless, no atomic carbon presence in the TiO2/ZrO2 structures has been detected.
Keywords:
TiO2/ZrO2 thin films / N- and C-doping / photocatalytic activity / toxic Cr(VI) ions reduction
Source:
Digest Journal of Nanomaterials and Biostructures, 2012, 7, 3, 1343-1352
Publisher:
  • Inst Materials Physics, Bucharest
Funding / projects:
  • Academy of Sciences of Ukraine
  • Romanian Academy
  • UEFISCDI [304/2011]
  • Synthesis, processing and applications of nanostructured multifunctional materials with defined properties (RS-45019)

ISSN: 1842-3582

PubMed:

WoS: 000312709300054

Scopus: 2-s2.0-84866537295
[ Google Scholar ]
10
9
Handle
https://hdl.handle.net/21.15107/rcub_technorep_2007
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2007
Collections
  • Radovi istraživača (Inovacioni centar) / Researchers’ publications (Innovation Centre)
Institution/Community
Inovacioni centar
TY  - JOUR
AU  - Linnik, Oksana
AU  - Petrik, Irina
AU  - Smirnova, Natalia
AU  - Kandyba, Viktor
AU  - Korduban, Oleksandr
AU  - Eremenko, Anna
AU  - Socol, Gabriel
AU  - Stefan, Nicolaie
AU  - Ristoscu, Carmen
AU  - Mihailescu, Ion N.
AU  - Sutan, Claudiu
AU  - Malinovschi, Viorel
AU  - Đokić, Veljko
AU  - Janaković, Đordje
PY  - 2012
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2007
AB  - Doped TiO2/ZrO2 films were obtained by Pulsed Laser Deposition method under different synthesis conditions. The onset of absorption spectra was red shifted for the films obtained in N-2 containing gas mixtures, while a broad absorption in visible was observed in the case of films deposited in CH4 atmosphere. The presence of O-Ti-N bonds revealed by XPS corresponded to the highest photocatalytic performance. XPS spectra of the samples obtained in N-2/CH4 gas mixtures evidenced a more effective incorporation of nitrogen in the structure due to oxygen deficiency. Nevertheless, no atomic carbon presence in the TiO2/ZrO2 structures has been detected.
PB  - Inst Materials Physics, Bucharest
T2  - Digest Journal of Nanomaterials and Biostructures
T1  - Tio2/zro2 thin films synthesized by pld in low pressure n-, c- and/or o-containing gases: structural, optical and photocatalytic properties
EP  - 1352
IS  - 3
SP  - 1343
VL  - 7
UR  - https://hdl.handle.net/21.15107/rcub_technorep_2007
ER  - 
@article{
author = "Linnik, Oksana and Petrik, Irina and Smirnova, Natalia and Kandyba, Viktor and Korduban, Oleksandr and Eremenko, Anna and Socol, Gabriel and Stefan, Nicolaie and Ristoscu, Carmen and Mihailescu, Ion N. and Sutan, Claudiu and Malinovschi, Viorel and Đokić, Veljko and Janaković, Đordje",
year = "2012",
abstract = "Doped TiO2/ZrO2 films were obtained by Pulsed Laser Deposition method under different synthesis conditions. The onset of absorption spectra was red shifted for the films obtained in N-2 containing gas mixtures, while a broad absorption in visible was observed in the case of films deposited in CH4 atmosphere. The presence of O-Ti-N bonds revealed by XPS corresponded to the highest photocatalytic performance. XPS spectra of the samples obtained in N-2/CH4 gas mixtures evidenced a more effective incorporation of nitrogen in the structure due to oxygen deficiency. Nevertheless, no atomic carbon presence in the TiO2/ZrO2 structures has been detected.",
publisher = "Inst Materials Physics, Bucharest",
journal = "Digest Journal of Nanomaterials and Biostructures",
title = "Tio2/zro2 thin films synthesized by pld in low pressure n-, c- and/or o-containing gases: structural, optical and photocatalytic properties",
pages = "1352-1343",
number = "3",
volume = "7",
url = "https://hdl.handle.net/21.15107/rcub_technorep_2007"
}
Linnik, O., Petrik, I., Smirnova, N., Kandyba, V., Korduban, O., Eremenko, A., Socol, G., Stefan, N., Ristoscu, C., Mihailescu, I. N., Sutan, C., Malinovschi, V., Đokić, V.,& Janaković, Đ.. (2012). Tio2/zro2 thin films synthesized by pld in low pressure n-, c- and/or o-containing gases: structural, optical and photocatalytic properties. in Digest Journal of Nanomaterials and Biostructures
Inst Materials Physics, Bucharest., 7(3), 1343-1352.
https://hdl.handle.net/21.15107/rcub_technorep_2007
Linnik O, Petrik I, Smirnova N, Kandyba V, Korduban O, Eremenko A, Socol G, Stefan N, Ristoscu C, Mihailescu IN, Sutan C, Malinovschi V, Đokić V, Janaković Đ. Tio2/zro2 thin films synthesized by pld in low pressure n-, c- and/or o-containing gases: structural, optical and photocatalytic properties. in Digest Journal of Nanomaterials and Biostructures. 2012;7(3):1343-1352.
https://hdl.handle.net/21.15107/rcub_technorep_2007 .
Linnik, Oksana, Petrik, Irina, Smirnova, Natalia, Kandyba, Viktor, Korduban, Oleksandr, Eremenko, Anna, Socol, Gabriel, Stefan, Nicolaie, Ristoscu, Carmen, Mihailescu, Ion N., Sutan, Claudiu, Malinovschi, Viorel, Đokić, Veljko, Janaković, Đordje, "Tio2/zro2 thin films synthesized by pld in low pressure n-, c- and/or o-containing gases: structural, optical and photocatalytic properties" in Digest Journal of Nanomaterials and Biostructures, 7, no. 3 (2012):1343-1352,
https://hdl.handle.net/21.15107/rcub_technorep_2007 .

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