Приказ основних података о документу
Influence of monomer and crosslinker molar ratio on the swelling behaviour of thermosensitive hydrogels
Uticaj molarnog odnosa monomera i umreživača na karakteristike bubrenja termoosetljivih hidrogelova
dc.creator | Ilić-Stojanović, Snežana | |
dc.creator | Nikolić, Ljubiša B. | |
dc.creator | Nikolić, Vesna | |
dc.creator | Stanković, Mihajlo | |
dc.creator | Stamenković, Jakov | |
dc.creator | Mladenović-Ranisavljević, Ivana | |
dc.creator | Petrović, Slobodan | |
dc.date.accessioned | 2021-03-10T11:46:40Z | |
dc.date.available | 2021-03-10T11:46:40Z | |
dc.date.issued | 2012 | |
dc.identifier.issn | 1451-9372 | |
dc.identifier.uri | http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2069 | |
dc.description.abstract | The synthesis of the poly(N-isopropylacrylamide-co-2-hydroxypropyl-methacrylate) hydrogel along with the analysis of the residual monomers content and influence of monomer and crosslinker molar ratios on the swelling behaviour was investigated. Synthesis of thermosensitive hydrogel based on N-isopropylacrylamide was carried out with the molar ratios of 5, 10, 15 and 20 mol% of monomer 2-hydroxypropyl-methacrylate, in the presence of ethylene glycol dimethacrylate as a crosslinker (1, 1.5, 2 and 3 mol%) and 2,2'-azobis(2-methylpropionitrile) as an initiator in acetone. The quantities of residual monomers in the synthesized copolymers were determined by HPLC method, ranging from 0.19 to 0.49% for N-isopropylacrylamide and from 0.13 to 0.63% for 2- -hydroxypropyl-methacrylate, counting the amount of xerogel. The hydrogels swelling ratio depending on time at 20 and 40°C was examined. It was found that the hydrogel with 5 mol% 2-hydroxypropyl-methacrylate and 1 mol% ethylene glycol dimethacrylate had the highest degree of swelling (( = 29.59) at 20°C, and that the hydrogel with 20 mol% 2-hydroxypropyl-methacrylate and 3 mol% ethylene glycol dimethacrylate had the lowest swelling degree ((=2.17) at 40°C. | en |
dc.description.abstract | Predmet ovog rada je sinteza kopolimernog hidrogela poli(N-izopropilakrilamid-ko-2-hidroksipropilmetakrilata), analiza sadržaja rezidualnih monomera i ispitivanje uticaja molskog odnosa monomera i umreživača na karakteristike bubrenja. Sinteza termoosetljivog hidrogela na bazi N-izopropilakrilamida izvršena je sa molarnim udelom 5, 10, 15 i 20 mol% monomera 2-hidroksipropilmetakrilata, u prisustvu umreživača etilenglikoldimetakrilata (u koncentraciji: 1, 1,5 , 2 i 3 mol%) i inicijatora 2,2'-azobis(2-metilpropionitrila) u acetonu. Sadržaj zaostalih monomera u sintetizovanim kopolimerima analiziran je pomoću HPLC metode. Vrednosti se nalaze u granicama od 0,19 do 0,49% za N-izopropilakrilamid i od 0,13 do 0,63% za 2-hidroksipropilmetakrilat računajući na količinu kserogela. Ispitan je stepen bubrenja dobijenih hidrogelova u zavisnosti od temperature. Najveći stepen bubrenja (( = 29,59) pri konstantnoj temperaturi od 20°C dostigao je uzorak hidrogela sa 5 mol% 2-hidroksipropilmetakrilata i 1 mol% umreživača EGDM-a, a najmanji (( = 2.17) pri temperaturi od 40°C dostigao je uzorak hidrogela sa 20 mol% 2-hidroksipropilmetakrilata i 3 mol% umreživača EGDM-a. PR Projekat Ministarstva nauke Republike Srbije, br. TR 34012. | sr |
dc.publisher | Association of the Chemical Engineers of Serbia | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Technological Development (TD or TR)/34012/RS// | |
dc.rights | openAccess | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.source | Chemical Industry & Chemical Engineering Quarterly | |
dc.subject | thermosensitive hydrogel | en |
dc.subject | residual monomers | en |
dc.subject | swelling | en |
dc.subject | N-isopropylacrylamide | en |
dc.subject | 2-hydroxypropyl-methacrylate | en |
dc.subject | termoosetljivi hidrogelovi | sr |
dc.subject | bubrenje | sr |
dc.subject | rezidualni monomeri | sr |
dc.subject | N-izopropilakrilamid | sr |
dc.subject | 2-hidroksipropilmetakrilat | sr |
dc.title | Influence of monomer and crosslinker molar ratio on the swelling behaviour of thermosensitive hydrogels | en |
dc.title | Uticaj molarnog odnosa monomera i umreživača na karakteristike bubrenja termoosetljivih hidrogelova | sr |
dc.type | article | |
dc.rights.license | BY-NC-ND | |
dc.citation.epage | 9 | |
dc.citation.issue | 1 | |
dc.citation.other | 18(1): 1-9 | |
dc.citation.rank | M23 | |
dc.citation.spage | 1 | |
dc.citation.volume | 18 | |
dc.identifier.doi | 10.2298/CICEQ110711040I | |
dc.identifier.fulltext | http://TechnoRep.tmf.bg.ac.rs/bitstream/id/8931/1451-93721100040I.pdf | |
dc.identifier.scopus | 2-s2.0-84859353741 | |
dc.identifier.wos | 000305925200001 | |
dc.type.version | publishedVersion |