This paper reports the results of the study of hydrogen bonding complexes between secondary amides and various aromatic hydrocarbons. The possibility of using chemometric methods was investigated in order to characterize N-H...π hydrogen bonded complexes. Hierarchical clustering and Principal Component Analysis (PCA) have been applied on infrared spectroscopic and Taft parameters of 43 N-substituted amide complexes with different aromatic hydrocarbons. The results obtained in this study are in good agreement with conclusions of other spectroscopic and thermodynamic analysis.
U ovom radu hemometrijski su okarakterisani vodonično vezani kompleksi sekundarnih amida i aromatičnih ugljovodonika. Metodama klaster analize i analizom glavne komponente utvrđene su razlike među N-H...π kompleksima na osnovu baznosti proton akceptora. Dobijeni rezultati se u dobroj meri slažu sa rezultatima spektroskopskih i termodinamičkih istraživanja.
Keywords:
hydrogen bonding / secondary amides / aromatic hydrocarbons / principal component / vodonična veza / sekundarni amidi / aromatični ugljovodonici / glavne komponente
TY - JOUR
AU - Jović, Branislav
AU - Nikolić, Aleksandar
AU - Petrović, Slobodan
PY - 2012
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2079
AB - This paper reports the results of the study of hydrogen bonding complexes between secondary amides and various aromatic hydrocarbons. The possibility of using chemometric methods was investigated in order to characterize N-H...π hydrogen bonded complexes. Hierarchical clustering and Principal Component Analysis (PCA) have been applied on infrared spectroscopic and Taft parameters of 43 N-substituted amide complexes with different aromatic hydrocarbons. The results obtained in this study are in good agreement with conclusions of other spectroscopic and thermodynamic analysis.
AB - U ovom radu hemometrijski su okarakterisani vodonično vezani kompleksi sekundarnih amida i aromatičnih ugljovodonika. Metodama klaster analize i analizom glavne komponente utvrđene su razlike među N-H...π kompleksima na osnovu baznosti proton akceptora. Dobijeni rezultati se u dobroj meri slažu sa rezultatima spektroskopskih i termodinamičkih istraživanja.
PB - Association of Chemical Engineers of Serbia
T2 - Hemijska industrija
T1 - Chemometric characterization of the hydrogen bonding complexes of secondary amides and aromatic hydrocarbons
T1 - Hemometrijska karakterizacija vodonično-vezanih kompleksa sekundarnih amida i aromatičnih ugljovodonika
EP - 7
IS - 1
SP - 1
VL - 66
DO - 10.2298/HEMIND110624058J
ER -
@article{
author = "Jović, Branislav and Nikolić, Aleksandar and Petrović, Slobodan",
year = "2012",
abstract = "This paper reports the results of the study of hydrogen bonding complexes between secondary amides and various aromatic hydrocarbons. The possibility of using chemometric methods was investigated in order to characterize N-H...π hydrogen bonded complexes. Hierarchical clustering and Principal Component Analysis (PCA) have been applied on infrared spectroscopic and Taft parameters of 43 N-substituted amide complexes with different aromatic hydrocarbons. The results obtained in this study are in good agreement with conclusions of other spectroscopic and thermodynamic analysis., U ovom radu hemometrijski su okarakterisani vodonično vezani kompleksi sekundarnih amida i aromatičnih ugljovodonika. Metodama klaster analize i analizom glavne komponente utvrđene su razlike među N-H...π kompleksima na osnovu baznosti proton akceptora. Dobijeni rezultati se u dobroj meri slažu sa rezultatima spektroskopskih i termodinamičkih istraživanja.",
publisher = "Association of Chemical Engineers of Serbia",
journal = "Hemijska industrija",
title = "Chemometric characterization of the hydrogen bonding complexes of secondary amides and aromatic hydrocarbons, Hemometrijska karakterizacija vodonično-vezanih kompleksa sekundarnih amida i aromatičnih ugljovodonika",
pages = "7-1",
number = "1",
volume = "66",
doi = "10.2298/HEMIND110624058J"
}
Jović, B., Nikolić, A.,& Petrović, S.. (2012). Chemometric characterization of the hydrogen bonding complexes of secondary amides and aromatic hydrocarbons. in Hemijska industrija
Association of Chemical Engineers of Serbia., 66(1), 1-7.
https://doi.org/10.2298/HEMIND110624058J
Jović B, Nikolić A, Petrović S. Chemometric characterization of the hydrogen bonding complexes of secondary amides and aromatic hydrocarbons. in Hemijska industrija. 2012;66(1):1-7.
doi:10.2298/HEMIND110624058J .
Jović, Branislav, Nikolić, Aleksandar, Petrović, Slobodan, "Chemometric characterization of the hydrogen bonding complexes of secondary amides and aromatic hydrocarbons" in Hemijska industrija, 66, no. 1 (2012):1-7,
https://doi.org/10.2298/HEMIND110624058J . .
