'The osmotic coefficients of the mixed electrolyte solution {yK(2)SO(4) + (1 - y)Mg(NO3)(2)}(aq) have been measured by the isopiestic method, at the temperature T = 298.15 K. The activity coefficients of K2SO4 and Mg(NO3)(2) were calculated by Scatchard's neutral-electrolyte method and by Fitter and Kim's treatment for mixed electrolyte solutions. The results are used for calculation of the excess Gibbs energy as a function of ionic strength and ionic-strength fraction of K2SO4, and also as a test of Zdanovskii's rule of linearity.
Keywords:
osmotic coefficients / activity coefficients
Source:
Journal of Chemical Thermodynamics, 1998, 30, 7, 847-853
TY - JOUR
AU - Todorović, M.
AU - Ninković, Rozalija
AU - Miladinović, Jelena
PY - 1998
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/215
AB - 'The osmotic coefficients of the mixed electrolyte solution {yK(2)SO(4) + (1 - y)Mg(NO3)(2)}(aq) have been measured by the isopiestic method, at the temperature T = 298.15 K. The activity coefficients of K2SO4 and Mg(NO3)(2) were calculated by Scatchard's neutral-electrolyte method and by Fitter and Kim's treatment for mixed electrolyte solutions. The results are used for calculation of the excess Gibbs energy as a function of ionic strength and ionic-strength fraction of K2SO4, and also as a test of Zdanovskii's rule of linearity.
PB - Academic Press Ltd, London
T2 - Journal of Chemical Thermodynamics
T1 - Osmotic and activity coefficients of {yK(2)SO(4)+(1-y)Mg(NO3)(2)}(aq) at the temperature T = 298.15 K
EP - 853
IS - 7
SP - 847
VL - 30
DO - 10.1006/jcht.1998.0351
ER -
@article{
author = "Todorović, M. and Ninković, Rozalija and Miladinović, Jelena",
year = "1998",
abstract = "'The osmotic coefficients of the mixed electrolyte solution {yK(2)SO(4) + (1 - y)Mg(NO3)(2)}(aq) have been measured by the isopiestic method, at the temperature T = 298.15 K. The activity coefficients of K2SO4 and Mg(NO3)(2) were calculated by Scatchard's neutral-electrolyte method and by Fitter and Kim's treatment for mixed electrolyte solutions. The results are used for calculation of the excess Gibbs energy as a function of ionic strength and ionic-strength fraction of K2SO4, and also as a test of Zdanovskii's rule of linearity.",
publisher = "Academic Press Ltd, London",
journal = "Journal of Chemical Thermodynamics",
title = "Osmotic and activity coefficients of {yK(2)SO(4)+(1-y)Mg(NO3)(2)}(aq) at the temperature T = 298.15 K",
pages = "853-847",
number = "7",
volume = "30",
doi = "10.1006/jcht.1998.0351"
}
Todorović, M., Ninković, R.,& Miladinović, J.. (1998). Osmotic and activity coefficients of {yK(2)SO(4)+(1-y)Mg(NO3)(2)}(aq) at the temperature T = 298.15 K. in Journal of Chemical Thermodynamics
Academic Press Ltd, London., 30(7), 847-853.
https://doi.org/10.1006/jcht.1998.0351
Todorović M, Ninković R, Miladinović J. Osmotic and activity coefficients of {yK(2)SO(4)+(1-y)Mg(NO3)(2)}(aq) at the temperature T = 298.15 K. in Journal of Chemical Thermodynamics. 1998;30(7):847-853.
doi:10.1006/jcht.1998.0351 .
Todorović, M., Ninković, Rozalija, Miladinović, Jelena, "Osmotic and activity coefficients of {yK(2)SO(4)+(1-y)Mg(NO3)(2)}(aq) at the temperature T = 298.15 K" in Journal of Chemical Thermodynamics, 30, no. 7 (1998):847-853,
https://doi.org/10.1006/jcht.1998.0351 . .
