The mechanism of compact Ag-film formation by electrolysis from nitrate solution with addition of small amounts of phosphate ions is elucidated. It is shown that the phosphate ions exert their effect by lowering the exchange current density. Consequently, the radii of nucleation exclusion zones also diminishes, thus producing conditions stimulating electrodeposition of continuous thin Ag-film.
Keywords:
electrodeposition / nitrate solution / phosphate ion addition / silver
Source:
Journal of Applied Electrochemistry, 1998, 28, 8, 797-801
TY - JOUR
AU - Popov, Konstantin I.
AU - Pavlović, MG
AU - Grgur, Branimir
AU - Dimitrov, AT
AU - Jordanov, SH
PY - 1998
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/217
AB - The mechanism of compact Ag-film formation by electrolysis from nitrate solution with addition of small amounts of phosphate ions is elucidated. It is shown that the phosphate ions exert their effect by lowering the exchange current density. Consequently, the radii of nucleation exclusion zones also diminishes, thus producing conditions stimulating electrodeposition of continuous thin Ag-film.
PB - Springer, Dordrecht
T2 - Journal of Applied Electrochemistry
T1 - Electrodeposition of silver from nitrate solution: Part II. Mechanism of the effect of phosphate ions
EP - 801
IS - 8
SP - 797
VL - 28
DO - 10.1023/A:1003450604118
ER -
@article{
author = "Popov, Konstantin I. and Pavlović, MG and Grgur, Branimir and Dimitrov, AT and Jordanov, SH",
year = "1998",
abstract = "The mechanism of compact Ag-film formation by electrolysis from nitrate solution with addition of small amounts of phosphate ions is elucidated. It is shown that the phosphate ions exert their effect by lowering the exchange current density. Consequently, the radii of nucleation exclusion zones also diminishes, thus producing conditions stimulating electrodeposition of continuous thin Ag-film.",
publisher = "Springer, Dordrecht",
journal = "Journal of Applied Electrochemistry",
title = "Electrodeposition of silver from nitrate solution: Part II. Mechanism of the effect of phosphate ions",
pages = "801-797",
number = "8",
volume = "28",
doi = "10.1023/A:1003450604118"
}
Popov, K. I., Pavlović, M., Grgur, B., Dimitrov, A.,& Jordanov, S.. (1998). Electrodeposition of silver from nitrate solution: Part II. Mechanism of the effect of phosphate ions. in Journal of Applied Electrochemistry
Springer, Dordrecht., 28(8), 797-801.
https://doi.org/10.1023/A:1003450604118
Popov KI, Pavlović M, Grgur B, Dimitrov A, Jordanov S. Electrodeposition of silver from nitrate solution: Part II. Mechanism of the effect of phosphate ions. in Journal of Applied Electrochemistry. 1998;28(8):797-801.
doi:10.1023/A:1003450604118 .
Popov, Konstantin I., Pavlović, MG, Grgur, Branimir, Dimitrov, AT, Jordanov, SH, "Electrodeposition of silver from nitrate solution: Part II. Mechanism of the effect of phosphate ions" in Journal of Applied Electrochemistry, 28, no. 8 (1998):797-801,
https://doi.org/10.1023/A:1003450604118 . .
