Zn-Ni alloys were electrodeposited from a berate-citrate and TEPA bath in potentiostatic and galvanostatic regimes. Potential of electrodeposition or current density were varied and chemical composition and phase structure were determined. It was found that both chemical composition and phase structure of alloys electrodeposited at the same potential or current density but in the two electrolytes were different. Differences were found even when one and the same chemical composition was achieved. Hydrogen evolution kinetics at the Zn-Ni alloys deposited from the two baths was investigated in alkaline solution (1 M NaOH). Substantial differences in the reaction rates at the alloys with the same chemical but different phase composition were found.
Keywords:
Ni-Zn alloy / alloy electrodeposition / phase structure / her
TY - JOUR
AU - Stevanović, Jasmina
AU - Gojković, Snežana
AU - Despić, A
AU - Obradović, M
AU - Nakić, V
PY - 1998
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/219
AB - Zn-Ni alloys were electrodeposited from a berate-citrate and TEPA bath in potentiostatic and galvanostatic regimes. Potential of electrodeposition or current density were varied and chemical composition and phase structure were determined. It was found that both chemical composition and phase structure of alloys electrodeposited at the same potential or current density but in the two electrolytes were different. Differences were found even when one and the same chemical composition was achieved. Hydrogen evolution kinetics at the Zn-Ni alloys deposited from the two baths was investigated in alkaline solution (1 M NaOH). Substantial differences in the reaction rates at the alloys with the same chemical but different phase composition were found.
PB - Pergamon-Elsevier Science Ltd, Oxford
T2 - Electrochimica Acta
T1 - Hydrogen evolution at Zn-Ni alloys
EP - 711
IS - 7
SP - 705
VL - 43
DO - 10.1016/S0013-4686(97)00142-4
ER -
@article{
author = "Stevanović, Jasmina and Gojković, Snežana and Despić, A and Obradović, M and Nakić, V",
year = "1998",
abstract = "Zn-Ni alloys were electrodeposited from a berate-citrate and TEPA bath in potentiostatic and galvanostatic regimes. Potential of electrodeposition or current density were varied and chemical composition and phase structure were determined. It was found that both chemical composition and phase structure of alloys electrodeposited at the same potential or current density but in the two electrolytes were different. Differences were found even when one and the same chemical composition was achieved. Hydrogen evolution kinetics at the Zn-Ni alloys deposited from the two baths was investigated in alkaline solution (1 M NaOH). Substantial differences in the reaction rates at the alloys with the same chemical but different phase composition were found.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Electrochimica Acta",
title = "Hydrogen evolution at Zn-Ni alloys",
pages = "711-705",
number = "7",
volume = "43",
doi = "10.1016/S0013-4686(97)00142-4"
}
Stevanović, J., Gojković, S., Despić, A., Obradović, M.,& Nakić, V.. (1998). Hydrogen evolution at Zn-Ni alloys. in Electrochimica Acta
Pergamon-Elsevier Science Ltd, Oxford., 43(7), 705-711.
https://doi.org/10.1016/S0013-4686(97)00142-4
Stevanović J, Gojković S, Despić A, Obradović M, Nakić V. Hydrogen evolution at Zn-Ni alloys. in Electrochimica Acta. 1998;43(7):705-711.
doi:10.1016/S0013-4686(97)00142-4 .
Stevanović, Jasmina, Gojković, Snežana, Despić, A, Obradović, M, Nakić, V, "Hydrogen evolution at Zn-Ni alloys" in Electrochimica Acta, 43, no. 7 (1998):705-711,
https://doi.org/10.1016/S0013-4686(97)00142-4 . .
