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The mechanism and kinetics of the tungsten (vi)-oxide reduction in the vertical tube reactor

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Authors
Kamberović, Željko
Raić, Karlo
Filipović, Mirjana
Andić, Zoran
Korać, Marija
Article (Published version)
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Abstract
Presented study shows the analysis of the process of reduction of WO 3 powder with hydrogen in the vertical tube reactor, representing a new approach in comparison to the conventional methods in the horizontal tube reactor. SEM analysis of the synthetisized tungsten powder shows the existence of particles, approximately 1,mu m in size, both individual ones and those within the porous agglomerates with a spongy structure. In order to study the mechanism and kinetics of the reduction process, the reduction degree and retention time of particles of WO3 powder in the reaction zone were calculated using a developed mathematical model, based on the application of Stokes' law. Kinetic parameters and activation energies were determined at the corresponding temperature intervals. Kinetic analysis showed that the process of WO3 reduction with hydrogen in the vertical tube reactor in the temperature interval from 700 to 900 degrees C occurs in the kinetic zone. Activation energy for the temperatu...re interval from 700 to 800 degrees C is E-a1=7.5 +/- 0.1 kJ/mol, whereas for the temperature interval from 800 to 900 degrees C, activation energy is E-a2=14.6 +/- 0.1 kJ/mol. A model was proposed describing the mechanism of the reduction process in the vertical tube reactor according to which particles of tungsten powder I pm in size arise from the stretching and cracking of coarse particles in the reduction zone, as well as from the appropriate temperature shock outside this zone.

Keywords:
tungsten (VI)-oxide / reduction / vertical tube reactor / kinetics
Source:
Metalurgia International, 2012, 17, 4, 8-13
Publisher:
  • Editura Stiintifica Fmr, Bucharest
Funding / projects:
  • Innovative synergy of by-products, waste minimization and clean technologies in metallurgy (RS-34033)

ISSN: 1582-2214

WoS: 000300590900002

[ Google Scholar ]
Handle
https://hdl.handle.net/21.15107/rcub_technorep_2229
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2229
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Kamberović, Željko
AU  - Raić, Karlo
AU  - Filipović, Mirjana
AU  - Andić, Zoran
AU  - Korać, Marija
PY  - 2012
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2229
AB  - Presented study shows the analysis of the process of reduction of WO 3 powder with hydrogen in the vertical tube reactor, representing a new approach in comparison to the conventional methods in the horizontal tube reactor. SEM analysis of the synthetisized tungsten powder shows the existence of particles, approximately 1,mu m in size, both individual ones and those within the porous agglomerates with a spongy structure. In order to study the mechanism and kinetics of the reduction process, the reduction degree and retention time of particles of WO3 powder in the reaction zone were calculated using a developed mathematical model, based on the application of Stokes' law. Kinetic parameters and activation energies were determined at the corresponding temperature intervals. Kinetic analysis showed that the process of WO3 reduction with hydrogen in the vertical tube reactor in the temperature interval from 700 to 900 degrees C occurs in the kinetic zone. Activation energy for the temperature interval from 700 to 800 degrees C is E-a1=7.5 +/- 0.1 kJ/mol, whereas for the temperature interval from 800 to 900 degrees C, activation energy is E-a2=14.6 +/- 0.1 kJ/mol. A model was proposed describing the mechanism of the reduction process in the vertical tube reactor according to which particles of tungsten powder I pm in size arise from the stretching and cracking of coarse particles in the reduction zone, as well as from the appropriate temperature shock outside this zone.
PB  - Editura Stiintifica Fmr, Bucharest
T2  - Metalurgia International
T1  - The mechanism and kinetics of the tungsten (vi)-oxide reduction in the vertical tube reactor
EP  - 13
IS  - 4
SP  - 8
VL  - 17
UR  - https://hdl.handle.net/21.15107/rcub_technorep_2229
ER  - 
@article{
author = "Kamberović, Željko and Raić, Karlo and Filipović, Mirjana and Andić, Zoran and Korać, Marija",
year = "2012",
abstract = "Presented study shows the analysis of the process of reduction of WO 3 powder with hydrogen in the vertical tube reactor, representing a new approach in comparison to the conventional methods in the horizontal tube reactor. SEM analysis of the synthetisized tungsten powder shows the existence of particles, approximately 1,mu m in size, both individual ones and those within the porous agglomerates with a spongy structure. In order to study the mechanism and kinetics of the reduction process, the reduction degree and retention time of particles of WO3 powder in the reaction zone were calculated using a developed mathematical model, based on the application of Stokes' law. Kinetic parameters and activation energies were determined at the corresponding temperature intervals. Kinetic analysis showed that the process of WO3 reduction with hydrogen in the vertical tube reactor in the temperature interval from 700 to 900 degrees C occurs in the kinetic zone. Activation energy for the temperature interval from 700 to 800 degrees C is E-a1=7.5 +/- 0.1 kJ/mol, whereas for the temperature interval from 800 to 900 degrees C, activation energy is E-a2=14.6 +/- 0.1 kJ/mol. A model was proposed describing the mechanism of the reduction process in the vertical tube reactor according to which particles of tungsten powder I pm in size arise from the stretching and cracking of coarse particles in the reduction zone, as well as from the appropriate temperature shock outside this zone.",
publisher = "Editura Stiintifica Fmr, Bucharest",
journal = "Metalurgia International",
title = "The mechanism and kinetics of the tungsten (vi)-oxide reduction in the vertical tube reactor",
pages = "13-8",
number = "4",
volume = "17",
url = "https://hdl.handle.net/21.15107/rcub_technorep_2229"
}
Kamberović, Ž., Raić, K., Filipović, M., Andić, Z.,& Korać, M.. (2012). The mechanism and kinetics of the tungsten (vi)-oxide reduction in the vertical tube reactor. in Metalurgia International
Editura Stiintifica Fmr, Bucharest., 17(4), 8-13.
https://hdl.handle.net/21.15107/rcub_technorep_2229
Kamberović Ž, Raić K, Filipović M, Andić Z, Korać M. The mechanism and kinetics of the tungsten (vi)-oxide reduction in the vertical tube reactor. in Metalurgia International. 2012;17(4):8-13.
https://hdl.handle.net/21.15107/rcub_technorep_2229 .
Kamberović, Željko, Raić, Karlo, Filipović, Mirjana, Andić, Zoran, Korać, Marija, "The mechanism and kinetics of the tungsten (vi)-oxide reduction in the vertical tube reactor" in Metalurgia International, 17, no. 4 (2012):8-13,
https://hdl.handle.net/21.15107/rcub_technorep_2229 .

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