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Kinetics measurements and in situ Raman spectroscopy of formation of hydrogen-tetrabutylammonium bromide semi-hydrates
dc.creator | Trueba, Alondra Torres | |
dc.creator | Radović, Ivona | |
dc.creator | Zevenbergen, John F. | |
dc.creator | Kroon, Maaike C. | |
dc.creator | Peters, Cor J. | |
dc.date.accessioned | 2021-03-10T11:58:01Z | |
dc.date.available | 2021-03-10T11:58:01Z | |
dc.date.issued | 2012 | |
dc.identifier.issn | 0360-3199 | |
dc.identifier.uri | http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2250 | |
dc.description.abstract | The kinetics of formation of H-2-TBAB semi-clathrate hydrates was studied in this work in order to elucidate their potential for H-2 storage. The influence of pressure (5-16 MPa), TBAB concentration (2.6 mol% and 3.7 mol%) and formation method (T-cycle method and T-constant method) on the hydrate nucleation, hydrate growth and H-2 storage capacity was determined. The results showed that kinetics is favored at higher pressures and solute concentrations. Additionally, the hydrate phase formation and dissociation was study for a solution of 2.6 mol% of TBAB in situ by using the Raman spectroscopy technique. The inclusion of H-2 in the semi-hydrate phase was confirmed. The results showed the importance of H-2 mass transfer on the storage capacity of the H-2-TBAB semi-hydrates. | en |
dc.publisher | Pergamon-Elsevier Science Ltd, Oxford | |
dc.relation | ACTS [H2 2007] | |
dc.rights | restrictedAccess | |
dc.source | International Journal of Hydrogen Energy | |
dc.subject | Kinetic measurements | en |
dc.subject | In situ Raman spectroscopy | en |
dc.subject | Hydrogen | en |
dc.subject | Tetrabutylammonium bromide | en |
dc.subject | Semi-hydrates | en |
dc.title | Kinetics measurements and in situ Raman spectroscopy of formation of hydrogen-tetrabutylammonium bromide semi-hydrates | en |
dc.type | article | |
dc.rights.license | ARR | |
dc.citation.epage | 5797 | |
dc.citation.issue | 7 | |
dc.citation.other | 37(7): 5790-5797 | |
dc.citation.rank | M21 | |
dc.citation.spage | 5790 | |
dc.citation.volume | 37 | |
dc.identifier.doi | 10.1016/j.ijhydene.2011.12.053 | |
dc.identifier.scopus | 2-s2.0-84858281237 | |
dc.identifier.wos | 000303284000036 | |
dc.type.version | publishedVersion |